Continuous multigram nanoparticle synthesis by high-power, high-repetition-rate ultrafast laser ablation in liquids
Abstract
Utilizing a novel laser system consisting of a 500 W, 10 MHz, 3 ps laser source which is fully synchronized with a polygon scanner reaching scanning speeds up to 500 m/s, we explore the possibilities to increase the productivity of nanoparticle synthesis by laser ablation in liquids. By exploiting the high scanning speed, laser-induced cavitation bubbles are spatially bypassed at high repetition rates and continuous multigram ablation rates up to 4 g/h are demonstrated for platinum, gold, silver, aluminum, copper, and titanium. Furthermore, the applicable, ablation-effective repetition rate is increased by two orders of magnitude. The ultrafast ablation mechanisms are investigated for different laser fluences, repetition rates, interpulse distances, and ablation times, while the resulting trends are successfully described by validating a model developed for ultrafast laser ablation in air to hold in liquids as well.
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Scale-up production of nanomaterials by pulsed laser synthesis to grams per hour has been demonstrated.
“Scale-up production to grams per hour has been demonstrated, making it appropriate for industrial applications20–22.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [22]
To achieve gram per hour productivity, approaches such as developing new types of chambers, bypassing the cavitation bubble, and reducing the liquid layer thickness have been sought.
“In order to achieve the gram per hour productivity, approaches such as developing new types of chambers, 74,[87][88][89] bypassing the cavitation bubble, 52,90 and reducing the liquid layer thickness, 88,91 have been sought.”
From Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production (2023) · cites this paper as [74]
Picosecond lasers are commonly employed when production upscaling is desired as an intermediate solution to decrease thermal interaction while avoiding strong nonlinear interactions.
“Then, as an intermediate solution to decrease thermal interaction while avoiding strong nonlinear interactions, ps lasers are commonly employed when production upscaling is desired.74”
From Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production (2023) · cites this paper as [74]
Fast scanning speed allows bypass of the cavitation bubble, reaching productivities as high as 4 g/h for PLAL of Pt.
“The fast scanning speed allows the bypass of the cavitation bubble, reaching productivities as high as 4 g h À1 for PLAL of Pt.”
From Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production (2023) · cites this paper as [74]
A direct comparison of PLAL with a galvanometric scanner (5 m/s) versus a polygon scanner (484 m/s) resulted in differences up to 16, 7, and 11 times for ablation of Au, Pt, and Au90Pt10 targets, respectively.
“A direct comparison of PLAL with a galvanometric scanner (5 m s À1 ) compared to the polygon scanner (484 m s À1 ) resulted in a difference up to 16, 7, and 11 times for the ablation of Au, Pt, and Au 90 Pt 10 targets, respectively (Fig. 9b).”
From Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production (2023) · cites this paper as [74]
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- Authors
- Streubel, R., Barcikowski, S., & Gökce, B.
- Affiliations
- University of Duisburg-Essen (DE)
- Corresponding author
- Streubel, René
- Barcikowski, Stephan
- Gökce, Bilal
- Venue
- Optics Letters
- Publisher
- Optica Publishing Group
- Published
- 2016-03-23
- Volume
- 41
- Issue
- 7
- Pages
- 1486
- ISSN
- 0146-9592 (ISSN-L)
- 1539-4794
- OpenAlex
- W2303828474
- Cited by
- 283
- References
- 30
- Citations by year
- 2026: 16 · 2025: 19 · 2024: 20 · 2023: 25 · 2022: 23 · 2021: 25 · 2020: 42 · 2019: 26 · 2018: 30 · 2017: 37 · 2016: 20
- FWCI
- 18.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Optics Letters (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Deutsche Forschungsgemeinschaft (DFG) (INST 20876/134-1 FUGG)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Engineering › Computational Mechanics › Laser Material Processing Techniques
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Keywords
- laser ablation in liquid, nanoparticle synthesis, ultrafast laser ablation, high repetition rate lasers, polygon scanner, cavitation bubbles, ablation rate, metal nanoparticles, platinum, gold, silver, aluminum, copper, titanium, ablation mechanism, laser fluence, ablation time, ablation model
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