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Copper‐Based Metal–Organic Porous Materials for CO2 Electrocatalytic Reduction to Alcohols
Abstract
The electrocatalytic reduction of CO 2 has been investigated using four Cu‐based metal–organic porous materials supported on gas diffusion electrodes, namely, (1) HKUST‐1 metal–organic framework (MOF), [Cu 3(μ 6‐C 9 H 3 O 6)2]n; (2) CuAdeAce MOF, [Cu 3(μ 3‐C 5 H 4 N 5)2]n; (3) CuDTA mesoporous metal–organic aerogel (MOA), [Cu(μ‐C 2 H 2 N 2 S 2)]n; and (4) CuZnDTA MOA, [Cu 0.6 Zn 0.4(μ‐C 2 H 2 N 2 S 2)]n. The electrodes show relatively high surface areas, accessibilities, and exposure of the Cu catalytic centers as well as favorable electrocatalytic CO 2 reduction performance, that is, they have a high efficiency for the production of methanol and ethanol in the liquid phase. The maximum cumulative Faradaic efficiencies for CO 2 conversion at HKUST‐1‐, CuAdeAce‐, CuDTA‐, and CuZnDTA‐based electrodes are 15.9, 1.2, 6, and 9.9 %, respectively, at a current density of 10 mA cm−2, an electrolyte‐flow/area ratio of 3 mL min cm−2, and a gas‐flow/area ratio of 20 mL min cm−2. We can correlate these observations with the structural features of the electrodes. Furthermore, HKUST‐1‐ and CuZnDTA‐based electrodes show stable electrocatalytic performance for 17 and 12 h, respectively.
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Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Hod, I., Deria, P., Bury, W., Mondloch, J. E., Kung, C.-W., So, M., Sampson, M. D., Peters, A. W., Kubiak, C. P., Farha, O. K., et al. (2015) · Nature Communications · doi:10.1038/ncomms9304 · Cited by 290
Metal–organic framework (MOF) aerogels with high micro- and macroporosity
Lohe, M. R., Rose, M., & Kaskel, S. (2009) · Chemical Communications · doi:10.1039/b910175f · Cited by 286
Jia, F., Yu, X., & Zhang, L. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.12.002 · Cited by 228
Wang, Q., Dong, H., & Yu, H. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.08.017 · Cited by 126
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Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Zhao, C., Dai, X., Yao, T., Chen, W., Wang, X., Wang, J., Yang, J., Wei, S., Wu, Y., & Li, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02736 · Cited by 1,365
Yang, H., Wu, Y., Li, G., Lin, Q., Hu, Q., Zhang, Q., Liu, J., & He, C. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b04907 · Cited by 788
Yaashikaa, P. R., Senthil Kumar, P., Varjani, S. J., & Saravanan, A. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.05.017 · Cited by 508
Wang, Y.-R., Huang, Q., He, C.-T., Chen, Y., Liu, J., Shen, F.-C., & Lan, Y.-Q. (2018) · Nature Communications · doi:10.1038/s41467-018-06938-z · Cited by 482
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts
Yang, D., Zhu, Q., Chen, C., Liu, H., Liu, Z., Zhao, Z., Zhang, X., Liu, S., & Han, B. (2019) · Nature Communications · doi:10.1038/s41467-019-08653-9 · Cited by 432
Zaera, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00905 · Cited by 425
Continuous-flow electroreduction of carbon dioxide
Endrődi, B., Bencsik, G., Darvas, F., Jones, R., Rajeshwar, K., & Janáky, C. (2017) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2017.05.005 · Cited by 386
Yan, T., Chen, X., Kumari, L., Lin, J., Li, M., Fan, Q., Chi, H., Meyer, T. J., Zhang, S., & Ma, X. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00514 · Cited by 328
Tang, T., Wang, Z., & Guan, J. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202111504 · Cited by 304
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Tailoring gas-phase CO 2 electroreduction selectivity to hydrocarbons at Cu nanoparticles
Merino-Garcia, I., Albo, J., & Irabien, A. (2018) · Nanotechnology · doi:10.1088/1361-6528/aa994e · Cited by 129
Self-citation
Metadata
- Authors
- Albo, J., Vallejo, D., Beobide, G., Castillo, O., Castaño, P., & Irabien, A.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2016-08-25
- Volume
- 10
- Issue
- 6
- Pages
- 1100-1109
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2508280130
- Cited by
- 410
- References
- 11
- FWCI
- 8.49
- Type
- journal article
- Language
- en
- Open access
- closed
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