Enhanced selectivity for the electrochemical reduction of CO2 to alcohols in aqueous solution with nanostructured Cu–Au alloy as catalyst
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As pH is increased, the selectivity of CO decreases in favor of formate formation on Ag catalysts.
“however, as the pH is increased, the selectivity of CO decreases in favor of formate formation. [47,131]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [131]
When generating CO on Ag catalysts in liquid phase electrolyzers, alkaline conditions have resulted in reduced overpotentials and HER.
“For example, when generating CO on Ag catalysts in liquid phase electrolyzers, alkaline conditions have resulted in reduced overpotentials [131,200] and HER, [201]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [131]
For catalysts producing CO (Au, Ag, etc.) or formate (Sn, Pb, etc.), elevated pressures do not greatly influence selectivity, but reduce cathodic overpotentials.
“For catalysts producing CO (Au, Ag, etc.) or formate (Sn, Pb, etc.), elevated pressures do not greatly influence selectivity, [139,143,202,220,221,[223][224][225][226] but reduce cathodic overpotentials.[131,143,221,224,225]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [131]
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- Authors
- Jia, F., Yu, X., & Zhang, L.
- Affiliations
- Central China Normal University (CN)
- Corresponding author
- Jia, Falong
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2014-04
- Volume
- 252
- Pages
- 85-89
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W1968787862
- Cited by
- 228
- References
- 15
- Citations by year
- 2026: 7 · 2025: 15 · 2024: 17 · 2023: 20 · 2022: 22 · 2021: 21 · 2020: 26 · 2019: 21 · 2018: 26 · 2017: 16 · 2016: 21 · 2015: 10 · 2014: 6
- FWCI
- 4.48
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Funders
- National Science Foundation of China (21073070, 21073069, 91023010)
- CCNU (CCNU11A02006)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, Cu-Au alloys, nanocatalysts, electrocatalysis, methanol, ethanol, electrodeposition, Faradaic efficiency, aqueous electrolyte solutions
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