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Field exposure of FeCrAl model alloys in a waste‐fired boiler at 600°C: The influence of Cr and Si on the corrosion behaviour
Open accessAbstract
The aim of this study was to examine the performance of FeCrAl model alloys in a waste‐fired boiler and investigate the influence of chromium and silicon content on the corrosion behaviour. The investigation was executed by utilising an air‐cooled probe, giving a material temperature of 600°C throughout a 672 hr exposure. The material loss measurements were performed by utilizing an ultrasonic thickness gauge in combination with scanning electron microscopy analysis. It was found that increasing the chromium content significantly reduced the overall material loss of the FeCrAl model alloys but further accelerated the corrosion attack on the windward side. Simultaneously, the increased chromium content caused embrittlement of the material. Minor additions of silicon drastically reduced the material loss of the FeCrAl model alloys, whereas the sample ring with no silicon present was completely deteriorated. The trends observed in this field study correlated well with what has been observed in previous laboratory studies. A state‐of‐the‐art alloy in the present environment, Inconel 625, was simultaneously exposed and showed similar performance to the silicon‐containing FeCrAl model alloys with ≥10 wt% Cr.
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The primary corrosion protection of FeCrAl alloys ((Al,Cr)2O3) acts similar to the Cr-rich type of oxide scale at intermediately high temperatures, e.g. 600°C.
“The results from this study also indicate that the primary corrosion protection of FeCrAl alloys ((Al,Cr) 2 O 3 ) act similar to the Cr-rich type of oxide scale at intermediately high temperatures, e.g.600 • C, in good agreement with recent investigations [35,40].”
From Beyond breakaway corrosion – Influence of chromium, nickel and aluminum on corrosion of iron-based alloys at 600 °C (2020) · cites this paper as [35]
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Persdotter, A., Eklund, J., Liske, J., & Jonsson, T. (2020) · Corrosion Science · doi:10.1016/j.corsci.2020.108961 · Cited by 44
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Metadata
- Authors
- Eklund, J., Paz, M. D., Jönsson, B., Liske, J., Svensson, J., & Jonsson, T.
- Affiliations
- Chalmers University of Technology (SE)
- Department of Chemistry and Chemical Engineering, Divisionof Energy and Materials Chalmers University of Technology Gothenburg Sweden
- Kanthal (Sweden) (SE)
- Corresponding author
- Eklund, Johan
- Venue
- Materials and Corrosion
- Publisher
- Wiley
- Published
- 2019-04-23
- Volume
- 70
- Issue
- 8
- Pages
- 1476-1485
- ISSN
- 0043-2822 (ISSN-L)
- 0947-5117
- 1521-4176
- OpenAlex
- W2940854212
- Cited by
- 18
- References
- 4
- Citations by year
- 2026: 2 · 2024: 5 · 2023: 8 · 2022: 2 · 2020: 1
- FWCI
- 0.55
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Materials and Corrosion (publishedVersion, cc-by)
- Chalmers Research (Chalmers University of Technology) (submittedVersion)
- Funders
- Chalmers Tekniska Högskola
- Energimyndigheten
- Topics
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Physical Sciences › Materials Science › Metals and Alloys › Hydrogen embrittlement and corrosion behaviors in metals
- Keywords
- high-temperature corrosion, chromium content, silicon addition, material loss, embrittlement, Inconel 625, field exposure
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