Green and Sustainable Solvents of the Future: Deep Eutectic Solvents

Deep Eutectic Solvents (DESs) and Their Applications

Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378 · see citing works

Green Chemistry: Principles and Practice

Anastas, P., & Eghbali, N. (2010) · Chem. Soc. Rev. · doi:10.1039/b918763b · Cited by 5,256 · see citing works

Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids

Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340 · see citing works

Deep eutectic solvents: A review of fundamentals and applications

Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422 · see citing works

Environmental chemistry and ecotoxicology of hazardous heavy metals: environmental persistence, toxicity, and bioaccumulation

Ali, H., Khan, E., & Ilahi, I. (2019) · Journal of Chemistry · doi:10.1155/2019/6730305 · Cited by 3,238 · see citing works

Natural deep eutectic solvents as new potential media for green technology

Dai, Y., van Spronsen, J., Witkamp, G.-J., Verpoorte, R., & Choi, Y. H. (2013) · Analytica Chimica Acta · doi:10.1016/j.aca.2012.12.019 · Cited by 2,694 · see citing works

Natural Deep Eutectic Solvents – Solvents for the 21st Century

Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500096j · Cited by 2,458 · see citing works

Tools and techniques for solvent selection: green solvent selection guides

Byrne, F. P., Jin, S., Paggiola, G., Petchey, T. H. M., Clark, J. H., Farmer, T. J., Hunt, A. J., McElroy, C. R., & Sherwood, J. R. (2016) · Sustainable Chemical Processes · doi:10.1186/s40508-016-0051-z · Cited by 1,424 · see citing works

Insoluble drug delivery strategies: review of recent advances and business prospects

Kalepu, S., & Nekkanti, V. (2015) · Acta Pharmaceutica Sinica B · doi:10.1016/j.apsb.2015.07.003 · Cited by 1,410 · see citing works

Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?

Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368 · see citing works

Natural deep eutectic solvents: Properties, applications, and perspectives

Liu, Y., Friesen, J. B., McAlpine, J. B., Lankin, D. C., Chen, S.-N., & Pauli, G. F. (2018) · Journal of Natural Products · doi:10.1021/acs.jnatprod.7b00945 · Cited by 1,304 · see citing works

Green chemistry oriented organic synthesis in water

Simon, M., & Li, C. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15222j · Cited by 1,177 · see citing works

Hydrophobic deep eutectic solvents as water-immiscible extractants

van Osch, D. J. G. P., Zubeir, L. F., van den Bruinhorst, A., Rocha, M. A. A., & Kroon, M. C. (2015) · Green Chemistry · doi:10.1039/c5gc01451d · Cited by 987 · see citing works

Insights into the synthesis and properties of deep eutectic solvents based on cholinium chloride and carboxylic acids

Florindo, C., Oliveira, F. S., Rebelo, L. P. N., Fernandes, A. M., & Marrucho, I. M. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500439w · Cited by 977 · see citing works

Are deep eutectic solvents benign or toxic?

Hayyan, M., Hashim, M. A., Hayyan, A., Al-Saadi, M. A., AlNashef, I. M., Mirghani, M. E. S., & Saheed, O. K. (2013) · Chemosphere · doi:10.1016/j.chemosphere.2012.11.004 · Cited by 675 · see citing works

Chemical pollution: A growing peril and potential catastrophic risk to humanity

Naidu, R., Biswas, B., Willett, I. R., Cribb, J., Singh, B. K., Nathanail, C. P., Coulon, F., Semple, K. T., Jones, K. C., Barclay, A., et al. (2021) · Environment International · doi:10.1016/j.envint.2021.106616 · Cited by 655 · see citing works

Toxic effects of pesticide mixtures at a molecular level: Their relevance to human health

Hernández, A. F., Carreño, T. P., Tsatsakis, A. M., Requena, M., Alarcón, R., & López‐Guarnido, O. (2012) · Toxicology · doi:10.1016/j.tox.2012.06.009 · Cited by 619 · see citing works

Biocompatible Deep Eutectic Solvents Based on Choline Chloride: Characterization and Application to the Extraction of Rutin from <i>Sophora japonica</i>

Zhao, B.-Y., Xu, P., Yang, F.-X., Wu, H., Zong, M.-H., & Lou, W.-Y. (2015) · ACS Sustainable Chemistry &amp; Engineering · doi:10.1021/acssuschemeng.5b00619 · Cited by 617 · see citing works

Deep eutectic solvents vs ionic liquids: similarities and differences

Płotka-Wasylka, J., de la Guardia, M., Andruch, V., & Vilková, M. (2020) · Microchemical Journal · doi:10.1016/j.microc.2020.105539 · Cited by 615 · see citing works

Deep eutectic solvents for the production and application of new materials

Tomé, L. I. N., Baião, V., da Silva, W., & Brett, C. (2018) · Applied Materials Today · doi:10.1016/j.apmt.2017.11.005 · Cited by 605 · see citing works

Biodegradable ionic liquids : Part II. Effect of the anion and toxicology

García, M. T., Gathergood, N., & Scammells, P. J. (2004) · Green Chemistry · doi:10.1039/b411922c · Cited by 576 · see citing works

Gas-Expanded Liquids

Jessop, P. G., & Subramaniam, B. (2007) · Chemical Reviews · doi:10.1021/cr040199o · Cited by 567 · see citing works

Phenolic Hydrogen Bond Donors in the Formation of Non-Ionic Deep Eutectic Solvents: The Quest for Type V DES

Abranches, D. O., Martins, M. A. R., Silva, L. P., Schaeffer, N., Pinho, S. P., & Coutinho, J. A. P. (2019) · Chemical Communications · doi:10.1039/c9cc04846d · Cited by 550 · see citing works

Natural Bioactive Compounds from Winery By-Products as Health Promoters: A Review

Teixeira, A., Baenas, N., Domínguez‐Perles, R., Barros, A., Rosa, E. A. S., Moreno, D. A., & García‐Viguera, C. (2014) · International Journal of Molecular Sciences · doi:10.3390/ijms150915638 · Cited by 544 · see citing works

Recent developments in deep eutectic solvents in chemical sciences

Tang, B., & Row, K. H. (2013) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-013-1050-3 · Cited by 538 · see citing works

Freeze-Drying of Aqueous Solutions of Deep Eutectic Solvents: A Suitable Approach to Deep Eutectic Suspensions of Self-Assembled Structures

Gutiérrez, M. C., Ferrer, M. L., Mateo, C. R., & del Monte, F. (2009) · Langmuir · doi:10.1021/la900552b · Cited by 524 · see citing works

On the Chemical Stabilities of Ionic Liquids

Sowmiah, S., Srinivasadesikan, V., Tseng, M., & Chu, Y. (2009) · Molecules · doi:10.3390/molecules14093780 · Cited by 513 · see citing works

Extraction desulfurization process of fuels with ammonium-based deep eutectic solvents

Li, C., Li, D., Zou, S., Li, Z., Yin, J., Wang, A., Cui, Y., ZhiLong, Y., & Zhao, Q. C. (2013) · Green Chemistry · doi:10.1039/c3gc41067f · Cited by 481 · see citing works

Assessing the toxicity and biodegradability of deep eutectic solvents

Wen, Q., Chen, J.-X., Tang, Y.-L., Wang, J., & Yang, Z. (2015) · Chemosphere · doi:10.1016/j.chemosphere.2015.02.061 · Cited by 480 · see citing works

Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environments

Florindo, C., Branco, L. C., & Marrucho, I. M. (2017) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2017.04.002 · Cited by 436 · see citing works

Ionic Liquids Toxicity—Benefits and Threats

Flieger, J., & Flieger, M. (2020) · International Journal of Molecular Sciences · doi:10.3390/ijms21176267 · Cited by 424 · see citing works

Natural deep eutectic solvents providing enhanced stability of natural colorants from safflower (Carthamus tinctorius)

Dai, Y., Verpoorte, R., & Choi, Y. H. (2014) · Food Chemistry · doi:10.1016/j.foodchem.2014.02.155 · Cited by 416 · see citing works

Solvents and sustainable chemistry

Welton, T. (2015) · Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rspa.2015.0502 · Cited by 412 · see citing works

Natural deep eutectic solvents as beneficial extractants for enhancement of plant extracts bioactivity

Radošević, K., Ćurko, N., Gaurina Srček, V., Cvjetko Bubalo, M., Tomašević, M., Kovačević Ganić, K., & Radojčić Redovniković, I. (2016) · LWT · doi:10.1016/j.lwt.2016.05.037 · Cited by 404 · see citing works

Revisiting the Physicochemical Properties and Applications of Deep Eutectic Solvents

Ijardar, S. P., Singh, V., & Gardas, R. L. (2022) · Molecules · doi:10.3390/molecules27041368 · Cited by 386 · see citing works

Transdermal delivery from eutectic systems: enhanced permeation of a model drug, ibuprofen

Stott, P. W. (1998) · Journal of Controlled Release · doi:10.1016/s0168-3659(97)00153-3 · Cited by 384 · see citing works

Fundamentals of Supercritical Fluids

Clifford, T. (1998) · doi:10.1093/oso/9780198501374.001.0001 · Cited by 379 · see citing works

A review of environmental occurrence, toxicity, biotransformation and biomonitoring of volatile organic compounds

Li, A. J., Pal, V. K., & Kannan, K. (2021) · Environmental Chemistry and Ecotoxicology · doi:10.1016/j.enceco.2021.01.001 · Cited by 378 · see citing works

Which is the best food emerging solvent: IL, DES or NADES?

Benvenutti, L., Zielinski, A. A. F., & Ferreira, S. R. S. (2019) · Trends in Food Science & Technology · doi:10.1016/j.tifs.2019.06.003 · Cited by 369 · see citing works

Review of the toxic effects of ionic liquids

Cho, C.-W., Pham, T. P. T., Zhao, Y., Stolte, S., & Yun, Y. (2021) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2021.147309 · Cited by 335 · see citing works

Solvent neurotoxicity

Dick, F. D. (2006) · Occupational and Environmental Medicine · doi:10.1136/oem.2005.022400 · Cited by 330 · see citing works

The perspectives of natural deep eutectic solvents in agri-food sector

Mišan, A., Nađpal, J., Stupar, A., Pojić, M., Mandić, A., Verpoorte, R., & Choi, Y. H. (2020) · Critical Reviews in Food Science and Nutrition · doi:10.1080/10408398.2019.1650717 · Cited by 316 · see citing works

The green solvent: a critical perspective

Winterton, N. (2021) · Clean Technologies and Environmental Policy · doi:10.1007/s10098-021-02188-8 · Cited by 307 · see citing works

Development of green betaine-based deep eutectic solvent aqueous two-phase system for the extraction of protein

Li, N., Wang, Y., Xu, K., Huang, Y., Wen, Q., & Ding, X. (2016) · Talanta · doi:10.1016/j.talanta.2016.01.042 · Cited by 304 · see citing works

Type V deep eutectic solvents: Design and applications

Abranches, D. O., & Coutinho, J. A. P. (2022) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2022.100612 · Cited by 286 · see citing works

Deep eutectic solvents: overcoming 21st century challenges

Florindo, C., Lima, F., Ribeiro, B. D., & Marrucho, I. M. (2019) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2018.12.003 · Cited by 284 · see citing works

Prospects of applying ionic liquids and deep eutectic solvents for renewable energy storage by means of redox flow batteries

Chakrabarti, B. K., Mjalli, F. S., AlNashef, I. M., Hashim, M. A., Hussain, M. A., Bahadori, L., & Low, C. T. J. (2013) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2013.10.004 · Cited by 281 · see citing works

The Curious Case of Hydrophobic Deep Eutectic Solvents: A Story on the Discovery, Design, and Applications

van Osch, D. J. G. P., Dietz, C. H. J. T., Warrag, S. E. E., & Kroon, M. C. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c00559 · Cited by 278 · see citing works

Eutectic Electrolytes as a Promising Platform for Next-Generation Electrochemical Energy Storage

Zhang, C., Zhang, L., & Yu, G. (2020) · Accounts of Chemical Research · doi:10.1021/acs.accounts.0c00360 · Cited by 277 · see citing works

A comparison between pure active pharmaceutical ingredients and therapeutic deep eutectic solvents: Solubility and permeability studies

Duarte, A. R. C., Ferreira, A. S. D., Barreiros, S. F., Cabrita, E. J., Reis, R. L., & Paiva, A. (2017) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2017.02.003 · Cited by 273 · see citing works

Emerging frontiers of deep eutectic solvents in drug discovery and drug delivery systems

Zainal-Abidin, M. H., Hayyan, M., Ngoh, G. C., Wong, W. F., & Looi, C. Y. (2019) · Journal of Controlled Release · doi:10.1016/j.jconrel.2019.09.019 · Cited by 253 · see citing works

A Comparative Study of Nickel Electrodeposition Using Deep Eutectic Solvents and Aqueous Solutions

Abbott, A. P., Ballantyne, A. D., Harris, R. C., Juma, J. A., Ryder, K. S., & Forrest, G. (2015) · Electrochimica Acta · doi:10.1016/j.electacta.2015.07.051 · Cited by 248 · see citing works

Tuberculosis: Current situation, challenges and overview of its control programs in India

Sandhu, G. (2011) · Journal of Global Infectious Diseases · doi:10.4103/0974-777x.81691 · Cited by 246 · see citing works

Chemicals in European residences – Part I: A review of emissions, concentrations and health effects of volatile organic compounds (VOCs)

Halios, C. H., Landeg-Cox, C., Lowther, S. D., Middleton, A., Marczylo, T. H., & Dimitroulopoulou, S. (2022) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2022.156201 · Cited by 229 · see citing works

Some aspects of green solvents

Häckl, K., & Kunz, W. (2018) · Comptes Rendus Chimie · doi:10.1016/j.crci.2018.03.010 · Cited by 219 · see citing works

The electrochemical stability of ionic liquids and deep eutectic solvents

Li, Q., Jiang, J., Li, G., Zhao, W., Zhao, X., & Mu, T. (2016) · Science China Chemistry · doi:10.1007/s11426-016-5566-3 · Cited by 210 · see citing works

Insights into the relationships between physicochemical properties, solvent performance, and applications of deep eutectic solvents

Zhang, M., Zhang, X., Liu, Y.-Y., Wu, K.-J., Zhu, Y.-M., Lu, H.-F., & Liang, B. (2021) · Environmental science and pollution research international · doi:10.1007/s11356-021-14485-2 · Cited by 192 · see citing works

Deep Eutectic Solvents

Marcus, Y. (2018) · Springer eBooks · doi:10.1007/978-3-030-00608-2 · Cited by 190 · see citing works

Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

Vidal, C., García‐Álvarez, J., Hernán‐Gómez, A., Kennedy, A. R., & Hevia, E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201400889 · Cited by 189 · see citing works

Deep Eutectic Solvents: Are They Safe?

Lomba, L., Ribate, M. P., Sangüesa, E., Concha, J., Garralaga, M. P., Errazquin, D., García, C. B., & Giner, B. (2021) · Applied Sciences · doi:10.3390/app112110061 · Cited by 186 · see citing works

Processing of Electric Arc Furnace Dust using Deep Eutectic Solvents

Abbott, A. P., Collins, J., Dalrymple, I. M., Harris, R. C., Mistry, R., Qiu, F., Scheirer, J. E., & Wise, W. R. (2009) · Australian Journal of Chemistry · doi:10.1071/ch08476 · Cited by 182 · see citing works

Greener Media in Chemical Synthesis and Processing

Ávalos, M., Babiano, R., Cintas, P., Jiménez, J. L., & Palacios, J. C. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504285 · Cited by 177 · see citing works

Theoretical and experimental study of choline chloride-carboxylic acid deep eutectic solvents and their hydrogen bonds

Gautam, R., Kumar, N., & Lynam, J. G. (2020) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2020.128849 · Cited by 177 · see citing works

Therapeutic Role of Deep Eutectic Solvents Based on Menthol and Saturated Fatty Acids on Wound Healing

Silva, J. M., Pereira, C. V., Mano, F., Silva, E., Castro, V. I. B., Sá-Nogueira, I., Reis, R., Paiva, A., Matias, A., & Duarte, A. (2019) · ACS Applied Bio Materials · doi:10.1021/acsabm.9b00598 · Cited by 173 · see citing works

Deep eutectic solvents as a green toolbox for synthesis

Yu, D., Xue, Z., & Mu, T. (2022) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2022.100809 · Cited by 169 · see citing works

Hydrophobic deep eutectic solvents for the extraction of organic and inorganic analytes from aqueous environments

Lee, J., Jung, D., & Park, K.-B. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.07.008 · Cited by 167 · see citing works

Formulation, structure, and applications of therapeutic and amino acid-based deep eutectic solvents: An overview

Rahman, M. S., Roy, R., Jadhav, B., Hossain, M. N., Halim, M. A., & Raynie, D. E. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.114745 · Cited by 164 · see citing works

Deep insights into the viscosity of deep eutectic solvents by an XGBoost-based model plus SHapley Additive exPlanation

Shi, D., Zhou, F., Mu, W., Cheng, L., Mu, T., Yu, G., & Li, R. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp03423a · Cited by 164 · see citing works

Effects of environmental contaminants on fertility and reproductive health

Ma, Y., He, X., Qi, K., Wang, T., Qi, Y., Cui, L., Wang, F., & Song, M. (2018) · Journal of Environmental Sciences · doi:10.1016/j.jes.2018.07.015 · Cited by 164 · see citing works

Chitosan films plasticized with choline-based deep eutectic solvents: UV shielding, antioxidant, and antibacterial properties

Yu, J., Xu, S., Gökşen, G., et al. (2022) · Food Hydrocolloids · doi:10.1016/j.foodhyd.2022.108196 · Cited by 164 · see citing works

Extraction desulfurization of fuels with ‘metal ions’ based deep eutectic solvents (MDESs)

Li, C., Zhang, J., Li, Z., Yin, J., Cui, Y., Liu, Y., & Yang, G. (2016) · Green Chemistry · doi:10.1039/c6gc00366d · Cited by 155 · see citing works

Deep Eutectic Solvents for Organocatalysis, Biotransformations, and Multistep Organocatalyst/Enzyme Combinations

Guajardo, N., Müller, C. R., Schrebler, R. A., Carlesi, C., & de Marı́a, P. D. (2015) · ChemCatChem · doi:10.1002/cctc.201501133 · Cited by 153 · see citing works

Review of deep eutectic systems from laboratory to industry, taking the application in the cosmetics industry as an example

Rente, D., Bubalo, M. C., Panić, M., Paiva, A., Caprin, B., Redovniković, I. R., & Duarte, A. R. C. (2022) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2022.135147 · Cited by 150 · see citing works

Exploiting Deep Eutectic Solvents and Organolithium Reagent Partnerships: Chemoselective Ultrafast Addition to Imines and Quinolines Under Aerobic Ambient Temperature Conditions

Vidal, C., García‐Álvarez, J., Hernán‐Gómez, A., Kennedy, A. R., & Hevia, E. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201609929 · Cited by 149 · see citing works

Adverse Impact of Textile Dyes on the Aquatic Environment as well as on Human Beings

Mehra, S., Singh, M., & Chadha, P. (2021) · Toxicology International · doi:10.18311/ti/2021/v28i2/26798 · Cited by 147 · see citing works

Bio-inspired choline chloride-based deep eutectic solvents as electrolytes for lithium-ion batteries

Millia, L., Dall’Asta, V., Ferrara, C., Berbenni, V., Quartarone, E., Perna, F. M., Capriati, V., & Mustarelli, P. (2018) · Solid State Ionics · doi:10.1016/j.ssi.2018.05.016 · Cited by 140 · see citing works

Interaction of inhalable volatile organic compounds and pulmonary surfactant: Potential hazards of VOCs exposure to lung

Zhao, Q., Li, Y., Chai, X., et al. (2019) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.01.104 · Cited by 135 · see citing works

Deep Eutectic Solvents

(2019) · Wiley eBooks · doi:10.1002/9783527818488 · Cited by 123 · see citing works

Liquid polymers as solvents for catalytic reductions

Heldebrant, D. J., Witt, H. N., Walsh, S. M., et al. (2006) · Green Chemistry · doi:10.1039/b605405f · Cited by 121 · see citing works

Investigation of the antimicrobial effect of natural deep eutectic solvents (NADES) as solvents in antimicrobial photodynamic therapy

Wikene, K. O., Valen, H. R., Bruzell, E. M., & Tønnesen, H. H. (2017) · Journal of Photochemistry and Photobiology B Biology · doi:10.1016/j.jphotobiol.2017.04.030 · Cited by 110 · see citing works

Ionicity of deep eutectic solvents by Walden plot and pulsed field gradient nuclear magnetic resonance (PFG-NMR)

Wang, Y., Chen, W., Zhao, Q., Jin, G., Xue, Z., Wang, Y., & Mu, T. (2020) · Physical Chemistry Chemical Physics · doi:10.1039/d0cp01431a · Cited by 106 · see citing works

Dye‐Sensitized Solar Cells that use an Aqueous Choline Chloride‐Based Deep Eutectic Solvent as Effective Electrolyte Solution

Boldrini, C. L., Manfredi, N., Perna, F. M., Trifiletti, V., Capriati, V., & Abbotto, A. (2016) · Energy Technology · doi:10.1002/ente.201600420 · Cited by 105 · see citing works

Choline Chloride Based Natural Deep Eutectic Solvents as Extraction Media for Extracting Phenolic Compounds from Chokeberry (Aronia melanocarpa)

Razboršek, M. I., Ivanović, M., Krajnc, P., & Kolar, M. (2020) · Molecules · doi:10.3390/molecules25071619 · Cited by 94 · see citing works

Neoteric deep eutectic solvents: history, recent developments, and catalytic applications

Shaibuna, M., Theresa, L. V., & Sreekumar, K. (2022) · Soft Matter · doi:10.1039/d1sm01797g · Cited by 82 · see citing works

Extractive desulfurization of fuel oils using deep eutectic solvents – A comprehensive review

Abro, R., Kiran, N., Ahmed, S., Muhammad, A., Jatoi, A. S., Mazari, S. A., Salma, U., & Plechkova, N. V. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.107369 · Cited by 80 · see citing works

Strategy To Form Eutectic Molecular Liquids Based on Noncovalent Interactions

Yu, D., & Mu, T. (2019) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.9b02891 · Cited by 78 · see citing works

Applications of Deep Eutectic Solvents Related to Health, Synthesis, and Extraction of Natural Based Chemicals

Lomba, L., García, C. B., Ribate, M. P., Giner, B., & Zuriaga, E. (2021) · Applied Sciences · doi:10.3390/app112110156 · Cited by 76 · see citing works

Natural deep eutectic solvents in phytonutrient extraction and other applications

Li, D. (2022) · Frontiers in Plant Science · doi:10.3389/fpls.2022.1004332 · Cited by 76 · see citing works

Properties of Therapeutic Deep Eutectic Solvents of l-Arginine and Ethambutol for Tuberculosis Treatment

Santos, F., Leitão, M. I. P. S., & Duarte, A. R. C. (2018) · Molecules · doi:10.3390/molecules24010055 · Cited by 74 · see citing works

An account on the deep eutectic solvents-based electrolytes for rechargeable batteries and supercapacitors

Puttaswamy, R., Mondal, C., Mondal, D., & Ghosh, D. (2022) · Sustainable materials and technologies · doi:10.1016/j.susmat.2022.e00477 · Cited by 72 · see citing works

Water Miscibility, Surface Tension, Density, and Dynamic Viscosity of Hydrophobic Deep Eutectic Solvents Composed of Capric Acid, Menthol, and Thymol

Deepika, Juneja, S., & Pandey, S. (2022) · Journal of Chemical &amp; Engineering Data · doi:10.1021/acs.jced.2c00495 · Cited by 70 · see citing works

One-pot sustainable synthesis of tertiary alcohols by combining ruthenium-catalysed isomerisation of allylic alcohols and chemoselective addition of polar organometallic reagents in deep eutectic solvents

Cicco, L., Rodríguez‐Álvarez, M. J., Perna, F. M., et al. (2017) · Green Chemistry · doi:10.1039/c7gc00458c · Cited by 69 · see citing works

Electropolishing of aluminium in a deep eutectic solvent

Китык, А. А., Protsenko, V. S., Danilov, F. I., et al. (2019) · Surface and Coatings Technology · doi:10.1016/j.surfcoat.2019.07.018 · Cited by 68 · see citing works

Pd-Catalyzed Thiophene–Aryl Coupling Reaction via C–H Bond Activation in Deep Eutectic Solvents

Punzi, A., Coppi, D. I., Matera, S., Capozzi, M. A. M., Operamolla, A., Ragni, R., Babudri, F., & Farinola, G. M. (2017) · Organic Letters · doi:10.1021/acs.orglett.7b02114 · Cited by 66 · see citing works

Electrochemical CO2 reduction to formate on indium catalysts prepared by electrodeposition in deep eutectic solvents

Bohlen, B., Wastl, D., Radomski, J., et al. (2019) · Electrochemistry Communications · doi:10.1016/j.elecom.2019.106597 · Cited by 65 · see citing works

Volatile Organic Compounds (VOCs) Emitted from Coated Furniture Units

Ülker, Ö. C., Ülker, Ö. C., & Hızıroǧlu, S. (2021) · Coatings · doi:10.3390/coatings11070806 · Cited by 63 · see citing works

Theoretical study of physicochemical properties of selected ammonium salt-based deep eutectic solvents

Benabid, S., Benguerba, Y., AlNashef, I. M., & Haddaoui, N. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.04.052 · Cited by 62 · see citing works

Electropolishing of nickel and cobalt in deep eutectic solvents

Karim, W. O., Abbott, A. P., Cihangir, S., et al. (2018) · Transactions of the IMF · doi:10.1080/00202967.2018.1470400 · Cited by 60 · see citing works

Inhaled deep eutectic solvent based-nanoemulsion of pirfenidone in idiopathic pulmonary fibrosis

Kang, J., Yang, M.-S., Kwon, T. K., Kim, D., & Park, C. (2022) · Journal of Controlled Release · doi:10.1016/j.jconrel.2022.10.045 · Cited by 53 · see citing works

Enhancement of the surface characteristics of Ti-based biomedical alloy by electropolishing in environmentally friendly deep eutectic solvent (Ethaline)

Китык, А. А., Protsenko, V. S., Danilov, F. I., et al. (2021) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2020.126125 · Cited by 51 · see citing works

Ionic liquid–based aqueous biphasic systems as sustainable extraction and separation techniques

Basaiahgari, A., & Gardas, R. L. (2020) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2020.100423 · Cited by 46 · see citing works

An alternative strategy for enhancing stability and antimicrobial activity of catechins by natural deep eutectic solvents

Zhou, P., Tang, D., Zou, J., & Wang, X. (2021) · LWT · doi:10.1016/j.lwt.2021.112558 · Cited by 46 · see citing works

Rapid Self-Healing Gel Electrolyte Based on Deep Eutectic Solvents for Solid-State Lithium Batteries

Li, Q., Zhang, Z., Li, Y., Li, H., Liu, Z., Liu, X., & Xu, Q. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c12445 · Cited by 46 · see citing works

Betaine-based deep eutectic solvents mediated synthesis of zinc oxide nanoparticles at low temperature

Mustafa, S. M., Barzinjy, A. A., Hamad, A. H., & Hamad, S. M. (2022) · Ceramics International · doi:10.1016/j.ceramint.2022.04.131 · Cited by 44 · see citing works

Acidity scales of deep eutectic solvents based on IR and NMR

Zhou, F., Shi, R., Wang, Y., Xue, Z., Zhang, B., & Mu, T. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp01816k · Cited by 43 · see citing works

An efficient extraction method for essential oil from angelica sinensis radix by natural deep eutectic solvents-assisted microwave hydrodistillation

Fan, Y., & Li, Q. (2022) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2022.100792 · Cited by 43 · see citing works

A natural deep eutectic solvent (NADES) as potential excipient in collagen-based products

Grønlien, K. G., Pedersen, M. E., & Tønnesen, H. H. (2020) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2020.04.026 · Cited by 38 · see citing works

The effect of organic additives in electrodeposition of Co from deep eutectic solvents

Juma, J. A. (2021) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2021.103036 · Cited by 38 · see citing works

Cholinium-Based Ionic Liquids as Efficient Media for Improving the Structural and Thermal Stability of Immunoglobulin G Antibodies

Dhiman, D., Bisht, M., Tavares, A. P. M., et al. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c07979 · Cited by 38 · see citing works

Selective terpene based therapeutic deep eutectic systems against colorectal cancer

Pereira, J., Castro, M. M., Santos, F., Duarte, A. R. C., Paiva, A., Oliveira, F., & Duarte, A. R. C. (2022) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2022.04.008 · Cited by 37 · see citing works

Development of quantitative structure-property relationship to predict the viscosity of deep eutectic solvent for CO2 capture using molecular descriptor

Kurnia, K. A., Zunita, M., Coutinho, J. A. P., Wenten, I. G., & Santoso, D. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.118239 · Cited by 36 · see citing works

“Inverted” Deep Eutectic Solvents Based on Host‐Guest Interactions

Yu, D., Mou, H., Fu, H., Lan, X., Wang, Y., & Mu, T. (2019) · Chemistry - An Asian Journal · doi:10.1002/asia.201901365 · Cited by 35 · see citing works

Application of Ionic Liquids in the Upstream oil Industry-A Review

Sulemana, N. T., & Ghosh, B. (2017) · International Journal of Petrochemistry and Research · doi:10.18689/ijpr-1000110 · Cited by 35 · see citing works

Coordination of Acidic Deep Eutectic Solvent–Chromium Trichloride Catalytic System for Efficient Synthesis of Fructose to 5-Hydroxymethylfurfual

Li, Q., Sun, K., Shao, Y., Zhang, S., Yan, Z., Zhang, L., Liu, Q., Wang, Y., & Hu, X. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.0c01218 · Cited by 35 · see citing works

Chemical synthesis using supercritical fluids

Campanelli, P., Manna, L., Banchero, M., et al. (2009) · PORTO@Iris · Cited by 34 · see citing works

Polyethylene glycol-water and polypropylene glycol-water solutionsas benign reaction solvents

Leininger, N. F., Clontz, R., Gainer, J. L., et al. (2003) · Chemical Engineering Communications · doi:10.1080/00986440302082 · Cited by 32 · see citing works

Electropolishing of two kinds of bronze in a deep eutectic solvent (Ethaline)

Китык, А. А., Danilov, F. I., Protsenko, V. S., et al. (2020) · Surface and Coatings Technology · doi:10.1016/j.surfcoat.2020.126060 · Cited by 32 · see citing works

Enhancing aqueous systems fermentability using hydrophobic eutectic solvents as extractans of inhibitory compounds

González, E. J., González‐Miquel, M., Díaz, I., Rodríguez, M., Fontela, C., Cañadas, R., & Sánchez, J. (2020) · Separation and Purification Technology · doi:10.1016/j.seppur.2020.117184 · Cited by 31 · see citing works

Effect of temperature and composition on density and dynamic viscosity of (lanthanide metal salts + urea) deep eutectic solvents

Khokhar, V., Dhingra, D., & Pandey, S. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.119396 · Cited by 30 · see citing works

Deep eutectic solvents regulation synthesis of multi-metal oxalate for electrocatalytic oxygen evolution reaction and supercapacitor applications

Yang, H., Cheng, Z., Wu, P., et al. (2022) · Electrochimica Acta · doi:10.1016/j.electacta.2022.140879 · Cited by 29 · see citing works

Occurrence, health risk, and removal efficiency assessment of volatile organic compounds in drinking water treatment plants (DWTPs): An investigation of seven major river basins across China

Zhang, K., Chang, S., Wang, E., et al. (2022) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2022.133762 · Cited by 29 · see citing works

Precursor- and Time-Dependent Morphological Evolution of ZnO Nanostructures for Comparative Photocatalytic Activity and Adsorption Dynamics with Methylene Blue Dye

Thakur, S., & Mandal, S. K. (2020) · ACS Omega · doi:10.1021/acsomega.0c01555 · Cited by 26 · see citing works

Ligand‐Free Suzuki–Miyaura Cross‐Coupling Reactions in Deep Eutectic Solvents: Synthesis of Benzodithiophene Derivatives and Study of their Optical and Electrochemical Performance

Pelliccioli, V., Dilauro, G., Grecchi, S., Arnaboldi, S., Graiff, C., Perna, F., Vitale, P., Licandro, E., Aliprandi, A., Cauteruccio, S., et al. (2020) · Annalen der Pharmacie · doi:10.1002/ejoc.202000889 · Cited by 26 · see citing works

Modeling the viscosity of binary eutectic systems at different compositions and temperatures

Peng, D., Alhadid, A., & Minceva, M. (2023) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2023.121258 · Cited by 26 · see citing works

Therapeutic Deep Eutectic Systems towards the Treatment of Tuberculosis and Colorectal Cancer: Opportunities and Challenges

Oliveira, F., Santos, F., & Duarte, A. R. C. (2021) · Molecules · doi:10.3390/molecules26227022 · Cited by 25 · see citing works

Physicochemical and acoustic characterization of binary mixtures of tetraalkylammonium bromide: PEG based DES and water

Sharma, R., Athira, K. K., Gardas, R. L., Malek, N. I., & Ijardar, S. P. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.120386 · Cited by 24 · see citing works

Hydroxyl‐Rich Deep Eutectic Solvents Assistant Synthesis of VPO and Its Application in Selective Oxidation of n‐Butane

Shi, Y., Dai, F., Zhang, T., et al. (2020) · ChemistrySelect · doi:10.1002/slct.202001090 · Cited by 24 · see citing works

Efficient, green extraction of two biflavonoids from Selaginella uncinata with deep eutectic solvents

Qin, G., Lei, J., Li, S., et al. (2022) · Microchemical Journal · doi:10.1016/j.microc.2022.108085 · Cited by 24 · see citing works

A novel and effective approach for viscosity prediction of binary and multicomponent liquid mixtures

Dey, R., & Biswas, P. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.06.012 · Cited by 23 · see citing works

Thermophysical characterization of deep eutectic solvents composed by D-sorbitol, xylitol or D(+)xylose as hydrogen bond donors

Dias, M. C. G. C., Farias, F. O., Gaioto, R. C., Kaspchak, E., da Costa, M. C., Igarashi‐Mafra, L., & Mafra, M. R. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.118801 · Cited by 21 · see citing works

Extraction of neonicotinoid pesticides from aquatic environmental matrices with sustainable terpenoids and eutectic solvents

Gutiérrez-Sánchez, P., Navarro, P., Álvarez-Torrellas, S., Garcı́a, J., & Larriba, M. (2022) · Separation and Purification Technology · doi:10.1016/j.seppur.2022.122148 · Cited by 21 · see citing works

Ionic liquid-nanoparticle based hybrid systems for energy conversion and energy storage applications

Singh, V., Amirchand, K. D., & Gardas, R. L. (2022) · Journal of the Taiwan Institute of Chemical Engineers · doi:10.1016/j.jtice.2022.104237 · Cited by 20 · see citing works

Insights into experimental and theoretical approach to physicochemical properties of aqueous PEGylated deep eutectic solvents at T=(293.15–323.15) K

Sharma, R., Jisha, K. J., Gardas, R. L., et al. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.120278 · Cited by 15 · see citing works

Thermophysical characterization of terpenoid based hydrophobic deep eutectic solvent and its Vapour-Liquid equilibrium studies with furfural

Sai, M. S. N., De, D., Gariya, D., & Satyavathi, B. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.120056 · Cited by 12 · see citing works

SOLVENTS USE IN VARIOUS INDUSTRIES

Wypych, G., Matsumoto, M., Isken, S., de Bont, J. A. M., Botzenhart, K., Hahn, T., Schweinsberg, F., Yamane, T., Hasenclever, K. D., Wakelyn, P. J., et al. (2019) · Elsevier eBooks · doi:10.1016/b978-1-927885-41-3.50003-6 · Cited by 10 · see citing works

Nonideal Behavior of Aqueous Deep Eutectic Solvents Based on Tetrabutylphosphonium Bromide and Ethylene Glycol/Glycerol

Al‐Ghamdi, A. A., Saini, D., Singh, M., & Malek, N. I. (2022) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.2c00372 · Cited by 8 · see citing works

Solvents

Bonventre, J. A. (2014) · Elsevier eBooks · doi:10.1016/b978-0-12-386454-3.01063-0 · Cited by 7 · see citing works

A global transform for the general formulation of liquid viscosities with significant linearizing benefits: a case study on ionic liquid mixtures

Hekayati, J., & Raeissi, S. (2021) · Physical Chemistry Chemical Physics · doi:10.1039/d1cp02033a · Cited by 5 · see citing works

Chiral Solvent Discovery: Exploring Chiral Eutectic Mixtures and Deep Eutectic SolventsPreprint

Hopkins, T. A., VandenElzen, L., Nelson, B. P., et al. (2022) · ChemRxiv · doi:10.26434/chemrxiv-2022-7c94s · Cited by 4 · see citing works

Atom Economy

Song, Q., & He, L. (2018) · Springer eBooks · doi:10.1007/978-1-4939-2493-6_1001-1 · Cited by 3 · see citing works

Deep eutectic solvents as a green alternative for trace element analysis in food and beverage samples: Recent advances and challenges

Luján, C. E., Lemos, A. A., Oviedo, M. N., Llaver, M., & Wuilloud, R. G. (2024) · Talanta · doi:10.1016/j.talanta.2023.125451 · Cited by 21 · see citing works

The Physicochemical Properties and Plausible Implication of Deep Eutectic Solvents in Analytical Techniques

Katrak, V. K., Patel, N. A., & Ijardar, S. P. (2026) · Critical Reviews in Analytical Chemistry · doi:10.1080/10408347.2025.2486209 · Cited by 16 · see citing works

Deep Eutectic Solvent-Based Dispersive Liquid–Liquid Microextraction Coupled with LC-MS/MS for the Analysis of Two Ochratoxins in Capsicum

Yang, H., Li, J., Mao, J., Xu, C., Song, J., & Xie, F. (2023) · Molecules · doi:10.3390/molecules28227634 · Cited by 13 · see citing works

Eco-Friendly Deep Eutectic Solvent-Based Extraction Technologies: A Comprehensive Review of Principles, Applications, and Comparative Insights

Alahmadi, S. M., & Abu-Dief, A. M. (2026) · Sustainable Chemistry · doi:10.3390/suschem7030033 · Cited by 1 · see citing works

On the reusability of samples in active learningPreprint

van Tulder, G., & Loog, M. (2022) · arXiv (Cornell University) · doi:10.48550/arxiv.2206.06276

Behaviors of Eutectic Crystals below Their Eutectic Points

Tino, Y., & Asahi, N. (1968) · Japanese Journal of Applied Physics · doi:10.1143/jjap.7.1005 · Cited by 3 · see citing works

NOAA fleet hazardous materials and hazardous waste management

Cunningham, W. R. (1988) · doi:10.1109/oceans.1988.794973

Understanding the impact of language features on reusability

Biddle, R., & Tempero, E. D. (2002) · doi:10.1109/icsr.1996.496113 · Cited by 21 · see citing works

A hazardous wastes overview

McIlvaine, R. W. (1988) · Waste Age; (United States) · Cited by 1 · see citing works