Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
Abstract
This article reports the development and characterization of a microfluidic reactor for the electrochemical reduction of carbon dioxide. The use of gas diffusion electrodes enables better control of the three-phase interface where the reactions take place. Furthermore, the versatility of the microfluidic reactor enables rapid evaluation of catalysts under different operating conditions. Several catalysts as well as the effects of electrolyte pH on reactor efficiency for reduction of to formic acid were tested. Operating at acidic pH resulted in a significant increase in performance: faradaic and energetic efficiencies of 89 and 45%, respectively, and current density of .
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Varela et al. demonstrated that while both Cl- and Br- can be used to suppress HER and improve the selectivity towards CO, I- can enhance hydrocarbon formation by donating more electronic charge to the Cu surface and facilitating charge transfer.
“Studying the effects of different halides, Varela et al. demonstrated that while both Cl -and Br -can be used to suppress HER and improve the selectivity towards CO, I - can enhance hydrocarbon formation by donating more electronic charge to the Cu surface and facilitating charge transfer.[217]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [217]
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- Authors
- Whipple, D. T., Finke, E. C., & Kenis, P. J. A.
- Affiliations
- University of Illinois Urbana-Champaign (US)
- ORCID
- Kenis, Paul J. A.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2010
- Volume
- 13
- Issue
- 9
- Pages
- B109
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2105840275
- Cited by
- 375
- References
- 29
- Citations by year
- 2026: 18 · 2025: 26 · 2024: 32 · 2023: 43 · 2022: 32 · 2021: 29 · 2020: 35 · 2019: 29 · 2018: 20 · 2017: 13 · 2016: 20 · 2015: 15 · 2014: 29 · 2013: 11 · 2012: 14
- FWCI
- 5.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochemical and Solid-State Letters (publishedVersion)
- Funders
- National Science Foundation
- University of Illinois at Urbana-Champaign
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- carbon dioxide reduction, microreactors, electrolyte pH, gas diffusion electrode, formic acid, electrocatalysts, three-phase interface, Faradaic efficiency, energy efficiency, current density
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