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A review on the recycling of spent lithium-ion batteries (LIBs) by the bioleaching approach
Open accessAbstract
This review discusses the latest trend in recovering valuable metals from spent lithium-ion batteries (LIBs) to meet the technological world's critical metal demands. Spent LIBs are a secondary source of valuable metals such as Li (5%-7%), Ni (5%-10%), Co (5%-25%), Mn (5-11%), and non-metal graphite. Recycling is essential for the battery industry to extract valuable critical metals from secondary sources to develop new and novel high-tech LIBs for various applications such as eco-friendly technologies, renewable energy, emission-free electric vehicles, and energy-saving lightings. LIB waste is currently undergoing high-temperature pyrometallurgical or hydrometallurgical processes to recover valuable metals, and these processes have proven to be successful and feasible. These methods, however, are not preferable due to the difficulties in controlling the process, secondary waste produced, high operational cost, and high risk of scaling up. Biotechnological approaches can be promising alternatives to pyrometallurgical and hydrometallurgical technologies in metal recovery from LIB waste. Microbiological metal dissolution or bioleaching has gained popularity for metal extraction from ores, concentrates, and recycled or residual materials in recent years. This technology is eco-friendly, safe to handle, and reduces operating costs and energy demands. The pre-treatment process (material preparation), microorganisms used in the bioleaching of LIBs, factors influencing the bioleaching process, methods of enhancing the leaching efficiency, regeneration of electrode materials, and future aspects have been discussed in detail.
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“This method is potentially environmentally friendly, as it reduces the reliance on harsh chemical reagents. However, its efficiency and scalability remain subjects of ongoing research [239].”
From Pathways to Greener Primary Lithium Extraction for a Really Sustainable Energy Transition: Environmental Challenges and Pioneering Innovations (2024) · cites this paper as [239]
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Fritze, M., & Hedrich, S. (2024) · Springer eBooks · doi:10.1007/978-3-031-67398-6_167 · Cited by 1
Influence of Microstructure Changes on the Stress Corrosion Properties of U-bend S275 Mild Steel
Parapurath, S., Jacob, L., Vahdati, N., & Günister, E. (2025) · Arabian Journal for Science and Engineering · doi:10.1007/s13369-025-10177-y · Cited by 1
Deviany, D., Achmad, F., Hardiana, D., Cannavaro, F. M., Sitara, S., Mufakhir, F. R., & Petrus, H. T. B. M. (2025) · AIP conference proceedings · doi:10.1063/5.0265042 · Cited by 1
Plant Growth Promoting Bacteria as Promising Candidates for Heavy Metal Detoxification
Kaur, R., Sharma, N., Kumar, D., Kour, S., Sharma, R., Ohri, P., & Bhardwaj, R. (2025) · BENTHAM SCIENCE PUBLISHERS eBooks · doi:10.2174/9798898811174125010009 · Cited by 1
Bioleaching of Heavy Metals from Electronic Waste
Mohanta, S., Parida, L., Sarkar, A., & Dassanayake, D. A. M. (2026) · Springer eBooks · doi:10.1007/978-3-031-90287-1_11 · Cited by 1
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Lithium Extraction From Commercial Lithium‐Ion Phosphate‐Based Black Masses by Bioleaching Process
Nadar, M. G. R., Roy, J. J., Cao, B., & Srinivasan, M. (2026) · Chemistry - An Asian Journal · doi:10.1002/asia.202500978 · Cited by 1
Self-citationYun, S. E., Son, U., Lee, J., Lee, S., Lee, H. J., Son, J., Hur, M., Oh, H. K., Ahn, J., & Hwang, G. (2026) · Minerals Engineering · doi:10.1016/j.mineng.2026.110261 · Cited by 1
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“In addition, the emerging deep eutectic solvents (DESs) method [17, 18] and bioleaching method [19, 20] have also demonstrated application potential.”
Sedikelo, G. K. M., Linganiso, L. Z., Chimwani, N., Yan, G., Linganiso, E. C., Liu, X., & Yao, Y. (2026) · Journal of Sustainable Metallurgy · doi:10.1007/s40831-026-01546-4 · Cited by 1
Progress and perspectives on recycling spent electrolytes in lithium-ion batteries: A review
Kumar, H., Mukherjee, S., Jha, R., Mishra, G., & Singh, K. K. (2026) · Waste Management & Research The Journal for a Sustainable Circular Economy · doi:10.1177/0734242x261449938 · Cited by 1
“…(Punt et al., 2022), solvent extraction (through chemical precipitation and electrolysis), filtration, and electro-chemical methods (Li et al., 2023, 2024a), bioprocessing (Roy et al., 2021; Sethurajan and Gaydardzhiev, 2021), and various combinations of these processes (Lv et al., 2024).”
Wang, L., Yang, Y., Li, M., Zhang, Y., Tang, J., Xia, W., Liu, L., & Ren, X. (2026) · Journal of Energy Storage · doi:10.1016/j.est.2026.123919 · Cited by 1
Bioleaching of metals from various waste resources
Iqbal, A., Iftekhar, S., Ashraf, A., & Asif, M. B. (2023) · Elsevier eBooks · doi:10.1016/b978-0-323-95327-6.00008-7 · Cited by 1
Biotechnological Applications in Spent Lithium-Ion Battery Processing
Abdollahi, H., Saneie, R., Rahmanian, A., Ebrahimi, E., Mohammadzadeh, A., & Shakiba, G. (2024) · Advances in Science, Technology & Innovation/Advances in science, technology & innovation · doi:10.1007/978-3-031-43625-3_5 · Cited by 1
Recovery Approaches for Spent Batteries: A Review
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Metadata
- Authors
- Roy, J. J., Cao, B., & Madhavi, S.
- Affiliations
- Nanyang Technological University (SG)
- Corresponding author
- Roy, Joseph Jegan
- Cao, Bin
- Venue
- Chemosphere
- Publisher
- Elsevier BV
- Published
- 2021-11
- Volume
- 282
- Pages
- 130944
- ISSN
- 0045-6535 (ISSN-L)
- OpenAlex
- W3164213697
- Cited by
- 346
- References
- 146
- Citations by year
- 2026: 54 · 2025: 87 · 2024: 84 · 2023: 73 · 2022: 38 · 2021: 10
- FWCI
- 4.32
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Chemosphere (publishedVersion)
- PubMed (publishedVersion)
- DR-NTU (Nanyang Technological University) (submittedVersion)
- Funders
- National Research Foundation of Singapore
- Government of Singapore Ministry of National Development
- National Environment Agency
- Topics
- Physical Sciences › Materials Science › Metals and Alloys › Extraction and Separation Processes
- Physical Sciences › Materials Science › Metals and Alloys › Metal Extraction and Bioleaching
- Physical Sciences › Environmental Science › Waste Management and Disposal › Recycling and Waste Management Techniques
- Keywords
- spent lithium-ion batteries, battery recycling, bioleaching, critical metal recovery, lithium recovery, nickel recovery, cobalt recovery, manganese recovery, graphite recovery
- MeSH terms
- Electrodes, Lithium, Metals, Electric Power Supplies, Recycling
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