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High-Temperature corrosion of P91/T91, 304L, Sanicro 28 and Inconel 625 exposed at 600 °C under continuous KCl deposition
Open accessAbstract
This study investigates the corrosion attack after breakaway oxidation on four commercial alloys (T91/P91, 304L, Sanicro 28 and Inconel 625) in the presence of KCl(g)/KCl(s) at 600 °C. The study suggests that an increase in corrosion resistant alloying elements (mainly nickel and chromium) results in the decrease of the thickness of the general oxide scale and not equally deep alloy grain boundary attack for the austenitic alloys. The corrosion attack in the presence of KCl is suggested to proceed by chromate formation and chlorine-induced acceleration of the diffusion of ions through the scale.
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The presence of Cl in the inner scale changes the diffusion properties of elements (e.g., oxygen) through the scale.
“The results indicate that the presence of Cl in the inner scale changes the diffusion properties of elements (e.g., oxygen) through the scale, which was also suggested in [16].”
From The Impact of HCl on Alkali-Induced Corrosion of Stainless Steels/FeCrAl Alloy at 600 °C: The Story After Breakaway (2024) · cites this paper as [16]
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Metadata
- Authors
- Phother-Simon, J., Hanif, I., Jonsson, T., & Liske, J.
- Affiliations
- Chalmers University of Technology (SE)
- Corresponding author
- Liske, J.
- Venue
- Fuel
- Publisher
- Elsevier BV
- Published
- 2024-02
- Volume
- 357
- Pages
- 130012
- ISSN
- 0016-2361 (ISSN-L)
- OpenAlex
- W4387637352
- Cited by
- 21
- References
- 42
- Citations by year
- 2026: 7 · 2025: 6 · 2024: 8
- FWCI
- 2.56
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Fuel (publishedVersion, cc-by)
- SSRN Electronic Journal (acceptedVersion)
- Chalmers Research (Chalmers University of Technology) (submittedVersion)
- Funders
- Energiforsk
- Chalmers Tekniska Högskola
- Ministerio de Economía y Competitividad
- Energimyndigheten
- Topics
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Materials Chemistry › Nuclear Materials and Properties
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Keywords
- high-temperature corrosion, potassium chloride, breakaway oxidation, P91 steel, T91 steel, 304L stainless steel, Sanicro 28, Inconel 625, oxide scale, grain boundary attack, chromate formation, chlorine diffusion, austenitic stainless steel
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