Liquid Air Energy Storage (LAES) as a large-scale storage technology for renewable energy integration – A review of investigation studies and near perspectives of LAES
Open accessAbstract
Electrical Energy Storage (EES) technologies have received considerable attention over the last decade because of the need to reduce greenhouse gas emission through the integration of renewable energy sources. Renewable sources have an intermittent power output to the electrical grid, thus EES represents a strategic solution in balancing electrical grids and enables the decarbonisation of the energy sector. Cryogenic Energy Storage (CES) is a novel method of EES falling within the thermo-mechanical category. It is based on storing liquid cryogenic fluids after their liquefaction from an initially gaseous state. A particular form of CES, Liquid Air Energy Storage (LAES), has gained growing attention respect to other cryogens. The current state of LAES is still at the development and demonstration stage since no commercial or pre-commercial plants have been built. This technology has been developed in different ways throughout its history (from 1977), and, to the best of our knowledge, no review paper has been published so far about the CES topic. Therefore, the present paper intends to provide a clear picture of the CES/LAES virtues in the literature as well as the challenges associated to the system to be commercially viable. For this purpose, this review includes: an investigation of the properties of cryogens and different CES processes as well as the main ways the system could be combined to other facilities to further enhance the energy efficiency, in particular the combination to a refrigerated warehouse with cold energy recovery from the cryogen evaporation.
AI snapshot
Written from the paper’s full text.
TL;DR
This review surveys Liquid Air Energy Storage (LAES) as a large-scale, location-independent cryogenic electricity storage option and compares liquefaction cycles, energy-extraction methods, and hybridization opportunities. It finds strong theoretical performance but persistent gaps in experimental validation and commercial viability.
Key findings
- LAES round-trip efficiency (RTE) varies widely by configuration: theoretical values are generally >70% for combustion-based recovery, while super-heating recovery is limited to 40–50%; ideal circumstances can exceed 80%.
- The only fully built LAES demonstrator cited had an RTE of 8% versus a theoretical 49%, attributed by the authors to small plant size; a proposed 100 MW/600 MWh “best built” configuration claimed 60% RTE.
- Cold-energy recovery can be substantial: Negro et al. (2018) reported the cold energy recovery sub-system efficiency can reach 88%, described as a key enabler for commercial viability.
- Hybridization options include integration with nuclear, solar thermal, cryogenic carbon capture, ORC, and refrigerated warehouses; Li et al. (2012) reported a solar-cryogen hybrid delivering 30% more power than the sum of individual systems.
Methods
- Critical literature review of LAES/CES, covering cryogen properties, liquefaction cycles (Linde-Hampson, Solvay, Claude, Heylandt), cryogenic energy extraction methods, and hybridization studies.
- Synthesizes thermodynamic and exergy analyses, RTE definitions, and reported performance from prior studies, patents, and pilot/demonstration plants.
- Compares super-heating (“S”) and combustion-based (“C”) recovery configurations, including cold/hot storage integration and industrial coupling such as refrigerated warehouses.
Limitations
- The paper states that LAES lacks experimental validation of simulated systems, and that high investment costs for machinery and demonstration-scale projects explain industrial reluctance.
- It notes environmental drawbacks of combustion-based recovery, including CO₂ and other emissions, and safety concerns from oxygen enrichment/stratification in liquid air storage.
- Evident from the provided text: Table 2, intended to compare main CEEMs, appears incomplete, so the review’s comparative RTE claims cannot be fully verified from the table as reproduced.
Model-written summary. Check it against the paper before relying on it.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
17 of 91 cited sources checked · 6 supported · 0 flagged · accuracy not yet measured
- Premisecitation
Liquid air does not require important storage volumes considering its significant energy density compared to that of PHS and CAES.
“Liquid air does not require important storage volumes considering significant energy density compared to that of PHS and CAES ( Chen et al., 2009 ).”
Quote in the paperSubstantial claim1 of 1 sources checked- cites Chen et al., 2009 source
Section 4.10.1 describes liquid air as a cryogenic storage medium and gives cryogenic energy storage a relatively high energy density of 100–200 Wh/kg. Section 5.6 places PHS among the lowest-density systems, supporting that comparison, but groups cryogenic storage and CAES together as medium-density systems. The paper does not establish that liquid air requires less storage volume than CAES. (LLM, conf=0.84)
Experimental — accuracy not yet measured
- Premisecitation
A packed bed filled with quartzite pebbles is integrated to store high-grade cold energy.
“Packed bed filled with quartzite pebbles is integrated in order to store high-grade cold energy.”
Quote in the paperSubstantial claim1 of 1 sources checked- cites Sciacovelli et al. (2017) source
The paper title (bibliographic entry, pp. 84–98) identifies a LAES system with packed-bed cold thermal storage, supporting that part of the claim. The available passages do not specify quartzite pebbles or describe the stored cold energy as high-grade; searches for those terms found no supporting passage. (LLM, conf=0.78)
Experimental — accuracy not yet measured
- Premisecitation
Heat from multiple compressor stages is recovered.
“Heat from multiple compressor stages is recovered, as it was the case in the work of Guizzi et al. (2015) .”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Guizzi et al. (2015) source
The passages labeled Abstract contain repository metadata rather than the paper’s text, and the PDF-file passages only describe available files. Searches for heat recovery from multiple compressor stages and interstage heat recovery returned no passage addressing the claim. (LLM, conf=0.75)
Experimental — accuracy not yet measured
- Premisecitation
As practical turbomachinery efficiencies were considered, this study has presented lower RTE than other theoretical values obtained in other works.
“As practical turbomachinery efficiencies were considered, this study has presented lower RTE than other theoretical values obtained in other works.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Negro et al., 2018 source
The Modelling Approach (section 4; page unavailable) says the model used state-of-the-art turbomachinery efficiencies, and Table 1 lists efficiencies below 100%. The Conclusion (section 7; page unavailable) gives a standalone RTE of 20–26%, but does not compare it with theoretical values from other works or attribute any difference to turbomachinery efficiency. (LLM, conf=0.85)
Experimental — accuracy not yet measured
- Premisecitation
From the parametric analysis, it was shown that three parameters can be controlled to enhance the RTE: discharge pressure, waste heat temperature at the expansion stage entrance and pressure in the storage tank.
“From the parametric analysis, it was shown that 3 parameters can be controlled to enhance the RTE: discharge pressure, waste heat temperature at the expansion stage entrance and pressure in the storage tank.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Negro et al., 2018 source
The System Wide Parametric Analysis and Results sections show that liquid-air storage pressure and discharge pressure affect RTE, although increasing discharge pressure helps only up to a point. The Results section reports higher RTE with 800 °C waste heat, but the listed parametric analysis does not vary waste-heat temperature or establish temperature at the expansion-stage entrance as a third controllable parameter. (LLM, conf=0.85)
Experimental — accuracy not yet measured
- Premisecitation
In February 2014, the UK government awarded Highview Ltd. an £8 million grant for a 5MW/15 MWh demonstration plant alongside Viridor's landfill gas generation plant at Pilsworth Landfill facility in Greater Manchester.
“In February 2014, the UK government awarded Highview Ltd. of a £8 million grant for the realization of a 5MW/15 MWh demonstration plant alongside Viridor's landfill gas generation plant at Pilsworth Landfill facility in Greater Manchester ( Highviewpower, 2017 ;Luo et al., 2015 ).”
Quote in the paperNot a substantial claim1 of 2 sources checked- cites Highviewpower, 2017
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites Luo et al., 2015 source
The passage on demonstration projects (page unavailable) says Highview Power Storage received £8 million from the UK government in February 2014 for a 5 MW/15 MWh LAES project alongside a landfill gas generation plant in the UK. It does not identify the plant as Viridor’s or locate it at Pilsworth Landfill in Greater Manchester. (LLM, conf=0.88)
Experimental — accuracy not yet measured
- Findingreasoning
According to Table 2, LAES with combustion methods have the highest RTE compared with the super-heating cycle, whether in independent or coupled cycle.
“According to Table 2 , LAES with combustion methods have the highest RTE comparing to super-heating cycle whether in independent or in coupled cycle.”
Quote in the paperNot a substantial claim - Findingreasoning
Almost all hybrid systems discussed include integration and recycle of the cold exergy released by the cryogen.
“Almost all hy-brid systems discussed include the integration and recycle of the cold exergy released by the cryogen, i.e. the capture of CO 2 , the condensing in an ORC or cooling the fluid in a Brayton cycle.”
Quote in the paperNot a substantial claim - Premisereasoning
JT expansion is responsible for a large loss of exergy due to the important pressure drop in an isenthalpic process.
“The JT expansion is responsible for a large loss of exergy due to the important pressure drop in an isenthalpic process.”
Quote in the paperNot a substantial claim - Premisecitation
Very low critical temperature and relatively low critical pressure of cryogens play a major role during liquefaction, since exergy lost during heat exchange is minimized when the fluid is cooled in supercritical conditions.
“The very low values of critical temperature and relatively low critical pressure of cryogens play a major role during liquefaction, since the exergy lost during the heat exchange process is minimized when the fluid is cooled in supercritical conditions ( Venkatarathnam, 2008 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Venkatarathnam, 2008 source
- Premisecitation
The exergy embodied by liquid nitrogen could be up to 750 kJ/kg.
“While, the exergy embodied by liquid nitrogen could be up to 750 kJ k g -1 .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisenone given
Air is non-flammable compared to hydrogen or methane cryogens.
“In a practical aspect, air is obviously a non-flammable fluid compared to hydrogen or methane cryogens.”
Quote in the paperNot a substantial claim - Premisecitation
When the isenthalpic expansion device is replaced by an isentropic expansion device, an increase in exergy efficiency of about 60% is achievable for a compression pressure of 200 bar.
“When the isenthalpic expansion device is replaced by an isentropic expansion device, an increase in the exergy efficiency of about 60% is achievable for a compression pressure of 200 bar ( Venkatarathnam, 2008 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Venkatarathnam, 2008 source
- Interpretationreasoning
LAES is considered a compact technology.
“Therefore, LAES is considered as a compacttechnology.”
Quote in the paperSubstantial claim - Premisecitation
Potential fire and explosion hazards increase when oxygen concentration in liquid or gaseous air increases.
“Since oxygen reacts violently with most materials ( EIGA, 2016 ), the potential fire and explosion hazards increase when oxygen concentration in liquid or gaseous air increases.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites EIGA, 2016
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Interpretationcitation
Exergy analysis is more adapted to quantify the potential of stored cryogen than energy analysis.
“So, exergy analysis is more adapted to quantify the potential of stored cryogen than energy analysis.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Interpretationreasoning
Reduction of refrigerated warehouses' electrical consumption by restituting some cold from evaporation at temperatures reaching -120 °C could greatly enhance the profitability of the whole combination.
“Refrigerated warehouses for chilled and frozen foods are large energy consumers, and therefore, the reduction of their electrical consumption by restituting some of the cold from the evaporation (at temperature reaching -120 °C) could greatly enhance the profitability of the whole combination.”
Quote in the paperNot a substantial claim - Premisecitation
Liquid air requires precautions because the oxygen fraction tends to separate and get locally enriched within the storage tank.
“However, there are some precautions when it comes to liquid air, because the oxygen fraction tends to separate and get locally enriched within the storage tank.”
Quote in the paperNot a substantial claim - Interpretationreasoning
As stored energy increases, the overall footprint increases more substantially than with LAES.
“Therefore, as stored energy increases, the overall footprint increases more substantially than with LAES.”
Quote in the paperSubstantial claim - Premisecitation
The exergy of liquid nitrogen is higher than the potential exergy of rock, which is around 455-499 kJ/kg when used for storing sensible heat.
“The latter figure is higher than the potential exergy of rock, which is around 455 -499 kJ k g -1 when used for storing sensible heat Li et al. (2010a) .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
The Claude cycle presents many advantages compared to the LH cycle.
“Claude cycle presents many advantages compared to LH cycle.”
Quote in the paperNot a substantial claim - Premisecitation
LAES is one of the few storage technologies which can offer large scale storage without geographical restrictions.
“Moreover, LAES is one of the few storage technologies which can offer large scale storage without geographical restrictions ( IRENA, 2017 ).”
Quote in the paperSubstantial claim0 of 1 sources checked- cites IRENA, 2017
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisereasoning
LAES gives the possibility for energy co-recovery, since cold from evaporation of liquid cryogen is not wasted.
“This technology gives the possibility for energy “co-recovery”, since cold from evaporation of liquid cryogen is not wasted.”
Quote in the paperNot a substantial claim - Interpretationnone given
The overall RTE had been greatly enhanced with the integration of hot and cold energy storage and recycle.
“Then, the overall RTE had been greatly enhanced with the integration of the hot and cold energy storage and recycle.”
Quote in the paperSubstantial claim - Premisecitation
The Highview LAES pilot was initially operative in 2011 at Scottish and Southern Energy's 80MW biomass plant in Slough, UK.
“It was initially operative in 2011 at Scottish and Southern Energy's 80MW biomass plant in Slough, UK.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Highviewpower, 2017
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Interpretationreasoning
The investment requirement explains the lack of experimental validation and industrial reluctance.
“This explains somehow the lack of experimental validation and industrials reluctance.”
Quote in the paperNot a substantial claim - Premisecitation
Carbon capture operation has lower complexity in oxy-fuel due to the higher CO2 density in the flue gas.
“Besides carbon capture operation has lower complexity in the oxy-fuel due to the higher CO2 density in the flue gas ( Buhre et al., 2005 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Buhre et al., 2005 source
- Interpretationreasoning
Combustion leads to high temperature at the turbine inlet before expansion, providing more work to be recovered from the expansion process.
“Besides, combustion leads to high temperature at the turbine inlet before expansion and this provides more work to be recovered from the expansion process.”
Quote in the paperSubstantial claim - Premisecitation
Wakana et al. (2005) designed a generation circuit that combined combustion with integration between liquefaction and generation units.
“In a second trial of this technology, Wakana et al. (2005) designed a generation circuit that combined combustion with the integration between liquefaction and generation units.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Wakana et al. (2005)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
Use of a Cryoturbine instead of a throttling device in a conventional setup improves considerably the efficiency of the liquefaction unit.
“It has been shown that the use of a Cryoturbine instead of a throttling device in a conventional setup improves considerably the efficiency of the liquefaction unit.”
Quote in the paperNot a substantial claim - Premisecitation
The CryoHub project investigates and extends the potential of large-scale LAES by recovering stored energy in two forms, cold and electrical energy.
“A recent innovative European project-( CryoHub, 2019 ) investigates and extends the potential of large-scale LAES by recovering the stored energy in two forms cold and electrical energy.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites CryoHub, 2019
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
In Vandor's patent, a LAES that relies on combustion of natural gas with liquid air is presented.
“In Vandor's patent ( Vandor, 2011 ), a LAES that relies on combustion of natural gas with liquid air is presented.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Vandor, 2011
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
Waste heat recovery has a large impact on increasing net power output.
“In fact, the waste heat recovery has a large impact on the increase of the net power output.”
Quote in the paperSubstantial claim - Premisecitation
The first LAES prototype was designed and demonstrated by Mitsubishi Heavy Industry in 1998.
“The first prototype was designed and demonstrated by Mitsubishi Heavy Industry in 1998 ( Kishimoto et al., 1998 ), with no information published about the design of the liquefaction unit.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
The round trip efficiency obtained for the Highview pilot was in the range of 8%.
“The round trip efficiency obtained was in the range of 8%.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Morgan et al. (2015) source
- Premisecitation
Highview Power Storage, working with the University of Birmingham, built the world's first fully integrated 350 kWh/2.5 MWh liquid air energy storage system.
“Working with the University of Birmingham (UK), Highview Power Storage has built the world's first fully integrated 350 kWh/2.5 MWh liquid air energy storage system Highview Power Storage designed and assembled this LAES pilot ( Highviewpower, 2017 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Highviewpower, 2017
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Interpretationreasoning
LAES would be more efficient when scaled-up.
“LAES would be more efficient when scaled-up.”
Quote in the paperSubstantial claim- Rests on an assumption: The only fully built LAES demonstrator has an RTE of 8% compared to a theoretical 49%.
- Interpretationreasoning
Tests and performance of deployed LAES systems did not match theoretical expectations because of technical limitations and real-world equipment efficiencies.
“Tests and performance of the deployed systems did not match theoretical expectations because of technical limitations and real world efficiencies of the equipment.”
Quote in the paperNot a substantial claim - Premisenone given
LAES architectures studied are almost focused on Solvay or Claude liquefier cycle with integration of a cryoturbine for the charging phase and super-heating for the discharging phase.
“Architectures studied of LAES are almost focused on Solvay or Claude liquefier cycle with the integration of Cryoturbine for charging phase and the super-heating process of energy extraction process for the discharging phase.”
Quote in the paperNot a substantial claim - Premisecitation
No information was published about the design of the liquefaction unit of the first LAES prototype.
“The first prototype was designed and demonstrated by Mitsubishi Heavy Industry in 1998 ( Kishimoto et al., 1998 ), with no information published about the design of the liquefaction unit.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- Premisecitation
Exergy and energy analysis results of Hamdy et al. (2019) show that the use of waste heat of 450 °C represents the highest exergetic efficiency of 55% compared to 44% with combustion.
“Contrary to the results found in literature, exergy and energy analysis results of this study show that the use of waste heat of 450 °C represents the highest exergetic efficiency of 55% comparing to 44% with combustion.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Hamdy et al., 2019 source
- Interpretationcitation
The higher RTE of combustion LAES can be explained by the high chemical exergy contained in the fuel, which provides an extra source of energy in addition to liquid air energy.
“This can be explained by the high chemical exergy ( Fyke et al., 1997 ) contained in the fuel and provided to the system as an extra source of energy in addition to liquid air energy.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites Fyke et al., 1997 source
- Interpretationreasoning
Despite the maturity of machinery used for LAES, the lack of experimental validation of theoretical performances is undeniable.
“Despite the maturity of machinery used for LAES (compressors, expanders, heat exchangers), the lack of experimental validation of theoretical performances is clearly undeniable.”
Quote in the paperSubstantial claim - Interpretationreasoning
Based on results of mentioned studies in this review, LAES represents an excellent candidate for the energy transition in terms of energy storage technology, regarding theoretical thermodynamic performances.
“Based on results of mentioned studies in this review, LAES represents an excellent candidate for the energy transition in terms of energy storage technology, regarding theoretical thermodynamic performances.”
Quote in the paperSubstantial claim - Interpretationreasoning
LAES economic viability for investors is not yet virtuous of millions of euros investments.
“LAES economic viability for investors is not yet virtuous of millions of euros investments.”
Quote in the paperSubstantial claim
- Classified as probably not a substantial claim. 74
- May combine two claims. 34
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationEES systems may provide peak shaving, load shifting and support the realization of smart grids.
“EES systems may also provide other useful services such as peak shaving, load shifting and supporting the realization of smart grids ( Luo et al., 2015 ).”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Luo et al., 2015 source
May combine two claims.
PremisecitationThe round trip efficiency for LAES is dependent on effective management of heat flux, but can reach values higher than 80% under ideal circumstances.
“The round trip efficiency for the case of LAES is dependent on the effective management of heat flux, but can reach values higher than 80% under ideal circumstances ( Luo et al., 2015 )”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Luo et al., 2015 source
The Liquid air Storage row in the comparison table lists a cycle-efficiency range of 55–80+%, which supports the possibility of exceeding 80%. Sections 3.2 and 3.10 describe LAES heat exchangers and thermal-energy conversion, but do not state that its round-trip efficiency depends on effective heat-flux management or specify ideal circumstances for the upper value. Page numbers are unavailable in our copy. (LLM, conf=0.78)
Experimental — accuracy not yet measured
Classified as probably not a substantial claim.
PremisecitationElectrical Energy Storage is viewed as one potential way to support integration of variable renewable energy sources.
“Consequently, the use of Electrical Energy Storage (EES) is viewed as one potential way to support integration of variable RES ( Luo et al., 2015 ).”
Quote in the paperSubstantial claim1 of 1 sources checked- cites Luo et al., 2015 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSimulation results gave ideally a round trip efficiency of 45% with some assumptions for a LAES providing daily air conditioning of an existing office building in Singapore.
“Results of simulation gave ideally a round trip efficiency of 45% with some assumptions.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Tafone et al. (2017) source
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThe cold recovered from evaporation could either be recycled in the liquefaction cycle or used to supply a refrigerated warehouse or food freezers.
“The cold recovered from the evaporation could either be recycled in the liquefaction cycle or used to supply refrigerated warehouse or food freezers.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Negro et al., 2018 source
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationSciacovelli focused on integrating packed bed storage in a dynamic RTE analysis and on the impact of this component on overall system performance.
“The author focused on the integration of the packed bed storage in a dynamic RTE analysis and the impact of this component on the system overall performances.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Sciacovelli et al. (2017) source
May combine two claims.
PremisecitationAlmost all recent studies on LAES obtained approximate results of exergy efficiency and the round trip efficiency varies in the range of 43-50%.
“Almost all recent studies ( Ameel et al., 2013 ;Guizzi et al., 2015 ;Hamdy et al., 2017 ;Sciacovelli et al., 2017 ) on the subject of LAES obtained approximate results of exergy efficiency and the round trip efficiency varies at a range of [43-50%].”
Quote in the paperNot a substantial claim1 of 3 sources checked- cites Ameel et al., 2013 source
- cites Guizzi et al., 2015 source
The indexed passages provide repository metadata and PDF listings, not the paper’s analysis or results (Abstract and “01 - Articolo su rivista”; no page numbers). Searches for exergy efficiency and a 43–50% round-trip efficiency range returned no substantive passage, so the available copy cannot verify the attributed figures. (LLM, conf=0.72)
Experimental — accuracy not yet measured - cites Hamdy et al., 2017 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSciacovelli et al. (2017) carried out a typical LAES system configuration based on super-heating process recovery.
“Sciacovelli et al. (2017) has carried out a typical configuration of the LAES system based on super-heating process recovery.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Sciacovelli et al. (2017) source
The available indexed passages identify the paper as a study of LAES with packed-bed cold thermal storage, but they do not describe its system configuration. Searches for super-heating recovery and the claimed typical configuration returned only bibliographic material, so our copy does not establish that specific attribution. (LLM, conf=0.72)
Experimental — accuracy not yet measured
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSensible heat is stored in a diathermic oil that acts as both heat transfer and storage medium.
“Sensible heat is stored in a diathermic oil that acts both as heat transfer and storage medium.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Sciacovelli et al. (2017) source
The available copy contains bibliographic information and keywords, including “Sensible storage” (Abstract/metadata; no page given), but no passage describing diathermic oil. Searches for “diathermic oil heat transfer storage medium” and “sensible heat hot thermal energy storage oil” found no passage addressing whether oil serves as both the heat-transfer and storage medium. (LLM, conf=0.77)
Experimental — accuracy not yet measured
Classified as probably not a substantial claim.
PremisecitationThe efficiency of the cold energy recovery sub-system can reach 88%.
“As main results of the study conducted by Negro et al. (2018) , the efficiency of the cold energy recovery sub-system can reach the value of 88%: « this will constitute a key technological enabler for any LAES technology to be commercially viable in the future ».”
Quote in the paperSubstantial claim1 of 1 sources checked- cites Negro et al. (2018) source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSciacovelli's proposed LAES system includes a modified Claude cycle with multiple expansion stages and a JT valve.
“The proposed system shown in Fig. 7 includes a modified Claude cycle which includes multiple expansion stages and a JT valve.”
Quote in the paperNot a substantial claim1 of 1 sources checked- cites Sciacovelli et al. (2017) source
The available passages identify Sciacovelli et al.’s 2017 LAES paper but do not describe the proposed system’s cycle or components. Searches for a modified Claude cycle, multiple expansion stages, and a JT valve found no relevant passage in our copy, so the attribution cannot be verified. (LLM, conf=0.70)
Experimental — accuracy not yet measured
May combine two claims.
FindingreasoningTheoretical RTE values are generally higher than 70%, while those of super-heating are limited to 40 to 50%.
“Values of theoretical RTE are generally higher than 70%, while those of super-heating are limited 40 to 50%.”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S4 (based).
Findingnone givenRecovery methods with combustion are proven to be more efficient in terms of RTE than with superheating.
“In CEEM section (3.2), recovery methods with combustion are proven to be more efficient in terms of RTE than with superheating.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
InterpretationreasoningDue to its instant availability and free use, air has the ultimate potential as a cryogen for an energy storing system.
“Finally, due to its instant availability and free use, air has the ultimate potential to the energy storing system as a cryogen.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe maximum safe oxygen concentration in a confined space is 23.5% by volume.
“In their report ( EIGA, 2016 ), the European Industrial Glasses Association claims that the maximum safe oxygen concentration in a confined space is 23.5% by volume.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites EIGA, 2016
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe Linde-Hampson liquefier is based on the Joule Thomson effect taking place in any throttling valve.
“The Linde-Hampson (LH) liquefier is based on the Joule Thomson (JT) effect taking place in any throttling valve ( Venkatarathnam, 2008 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Venkatarathnam, 2008 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationLiquid hydrogen has the highest exergy density, up to 11,912 kJ/kg.
“For example, calculation shows that liquid hydrogen has the highest exergy density using Eq. ( 1) , up to 11, 912 kJ/kg.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenFew air treatment operations are necessary before energy storage processing compared to hydrogen or nitrogen extraction.
“Furthermore, few air treatments operations are necessary before energy storage processing compared to hydrogen or nitrogen extraction for example.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationThe main drawbacks of pumped hydro storage and compressed air energy storage are dependence on geographical location, large land footprint and environmental concerns.
“So, the main drawbacks of these technologies are the dependence on geographical location and the large land footprint and therefore environmental concerns ( ENEA Consulting, 2012 ;IEC, 2011 ;IRENA, 2017 ).”
Quote in the paperSubstantial claim0 of 3 sources checked- cites ENEA Consulting, 2012
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites IEC, 2011
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites IRENA, 2017
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationNear-isentropic expansion makes the system potentially more efficient and additional work can be produced by the expansion device improving the overall efficiency.
“According to Sciever (2012) , the near-isentropic expansion makes the system potentially more efficient and additional work can be produced by the expansion device improving the overall efficiency.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Sciever, 2012
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
PremisecitationDespite the low exergy efficiency of Linde Hampson, many industrials refer to this system to produce liquid air, as many patents for LAES systems were based on the LH liquefier.
“Despite the low values of exergy efficiency of Linde Hampson, many industrials refer to this system to produce liquid air, as in many patents LAES systems were based on the LH liquefier ( Gatti et al., 2011 ;Sinatov and Afremov, 2015 ;Stiller et al., 2016 ;Vandor, 2011 ).”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites Gatti et al., 2011
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites Sinatov and Afremov, 2015
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites Stiller et al., 2016
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationIn the literature, mainly three major cycles were studied for the liquefaction of cryogens: Linde Hampson cycle, Solvay cycle and Claude cycle.
“In the literature, mainly 3 major cycles were studied for the liquefaction of cryogens, Linde Hampson cycle, Solvay cycle and Claude cycle ( Abdo et al., 2015 ;Ameel et al., 2013 ;Atrey, 1998 ;Chang, 2015 ;D'Arsonval, 1898 ;Guizzi et al., 2015 ;Hamdy et al., 2017 ;Li, 2011 ;Sciacovelli et al., 2017 ;Venkatarathnam, 2008 ).”
Quote in the paperNot a substantial claim0 of 3 sources checkedProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThe efficiency of the JT liquefaction cycle is 11% and is described as poor.
“Petit (1995) referred to the efficiency of 11% and describes the efficiency of JT liquefaction cycle as “poor”.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Petit, 1995 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe chemical exergy of liquid methane is 48 times higher than its thermo-physical exergy.
“Cryogens can also embody chemical exergy, for example the chemical exergy of liquid methane is 48 times higher than its thermo-physical exergy, on the other hand liquid nitrogen does not have any chemical exergy and all exergy is in the thermo-mechanical exergy potential Li et al. (2010a) .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisereasoningThe Solvay liquefier increases liquid yield considerably.
“The liquid yield increases considerably and this cycle is known as the Solvay liquefier.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationCES technology is at pre-commercial stage evaluated with Technology Readiness Level at maximum nine.
“The CES technology is at pre-commercial stage evaluated with Technology Readiness Level (TRL) at maximum nine ( Hamdy et al., 2019 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Hamdy et al., 2019 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationLiquid air can contain 50% nitrogen and 50% oxygen in some instances.
“Liquid air can even contain 50% of nitrogen and 50% of oxygen ( CLCF, 2013 ) in some instances.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites CLCF, 2013
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationWith the extended version of the Claude cycle, more cold is provided within the heat exchanger, hence more liquid is produced and the liquefier efficiency can be enhanced.
“With this extended version of Claude cycle, more cold is provided within the heat exchanger, henceforth more liquid is produced and so the liquefier efficiency can be enhanced.”
Quote in the paperNot a substantial claimMay combine two claims.
Interpretationnone givenLAES needs further development and is currently at industrial demonstration level.
“On the other hand, LAES needs further development and is currently at industrial demonstration level.”
Quote in the paperSubstantial claimMay combine two claims.
PremisecitationLiquid nitrogen does not have any chemical exergy and all its exergy is in the thermo-mechanical exergy potential.
“Cryogens can also embody chemical exergy, for example the chemical exergy of liquid methane is 48 times higher than its thermo-physical exergy, on the other hand liquid nitrogen does not have any chemical exergy and all exergy is in the thermo-mechanical exergy potential Li et al. (2010a) .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationCryogens can be an efficient energy carrier and storage media.
“Li (2011) made a thermodynamic assessment of the use of cryogen as a working fluid in an energy storage system and concluded that cryogens can be an efficient energy carrier and storage media.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li, 2011
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe idea of cryogenic energy storage was first proposed by E.M Smith at the University of New Castle in 1977.
“The idea of cryogenic energy storage was firstly proposed by E.M Smith, at university of New Castle in 1977 ( Smith, 1977 ), and tested by Mitsubishi in 1998 ( Kishimoto et al., 1998 ;Sciacovelli et al., 2017 ) using liquid air as cryogen.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Smith, 1977 source
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
InterpretationreasoningThe Linde Hampson principle has been regarded for a long time as a potential liquefier for industrial application and it is always the case nowadays mainly due to the cost benefit criterion.
“This means that the Linde Hampson principle has been regarded for a long time as potential liquefier for industrial application and it is always the case nowadays mainly due to the cost benefit criterion.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationCommercial companies got involved in LAES development beginning with Mitsubishi and Hitachi at the end of the nineties and more recently Highview Power Ltd.
“Consequently, some commercial companies got involved in the development of this technology beginning with Mitsubishi and Hitachi ( Kishimoto et al., 1998 ;Wakana et al., 2005 ) at the end of the nineties and more recently Highview Power Ltd.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
- cites Wakana et al., 2005
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
PremisecitationIn particular conditions, Li (2011) obtained an optimal round trip efficiency of 48% using a throttling valve, while this value increased to about 82% by using a Cryoturbine.
“For example, in particular conditions, Li (2011) obtained an optimal round trip efficiency of 48% using throttling valve while, this value increased to about 82% by using a Cryoturbine.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li, 2011
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
Premisenone givenThermo-mechanical exergy of liquid cryogens can be extracted after evaporation through turbines, while the remaining thermal exergy in the form of high-grade cold can be recovered through heat exchangers and storage medium.
“Thermo-mechanical exergy of liquid cryogens can be extracted after evaporation through turbines, while the remaining thermal exergy, in form of high-grade cold, can be recovered through heat exchangers and storage medium.”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSimulation results show that a solar-cryogen hybrid power system delivers power 30% greater than the sum of the power outputs of each system individually.
“Results of simulation in this study show that the system delivers power 30% greater than the sum of the power outputs of each system individually.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al. (2012)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
Premisenone givenCEEM and liquefaction system can be completely separated or thermally linked in the case of CES.
“CEEM and liquefaction system can be completely separated or thermally linked in the case of CES.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenThere was no full-scale pilot plant demonstrator for the Hitachi system.
“However there was no full scale pilot plant demonstrator.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationCarbon capture can be done by use of cryogenic cold energy.
“This can be done by use of cryogenic cold energy so as in Li et al. (2011) .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al. (2011)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe author calculated the thermal efficiency up to 77% as an efficiency of the generation cycle.
“The author calculated the thermal efficiency up to 77% (Eq.( 5)) as an efficiency of the generation cycle.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
Interpretationnone givenCombustion still rejects toxic particles such as CO, NO and O3, which require additional post-treatment processes and could lead to more complexity and expensiveness of the system.
“Nevertheless, combustion still rejects many others toxic particles like CO or NO, O 3 , etc. which require additional combustion post treatment processes and could lead to more complexity and expensiveness of the system.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationMitsubishi's generator is a combination of super-heating, combustion and direct expansion method with some modification.
“The generator is a combination of super-heating, combustion and direct expansion method with some modification, as showed by Fig 6 .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationCryogenic Carbon Capture is a viable approach to achieve the target CO2 emission level.
“Cryogenic Carbon Capture (CCC) is a viable approach to achieve the target of CO 2 emission level ( Safdarnejad et al., 2016 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Safdarnejad et al., 2016 source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationCarbon capture is a frequently proposed solution.
“Carbon capture is a frequent proposed solution ( Conlon, 2016 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Conlon, 2016
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationTo further increase the efficiency of LA discharge, waste heat from exhaust gas is recovered to superheat gaseous nitrogen at the turbine entrance.
“To further increase the efficiency of the LA discharge, waste heat from the exhaust gas is recovered to superheat the gaseous nitrogen at the turbine entrance ( Li et al., 2013 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2013
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationA self-developed cold storage was used for full integration of liquefaction and energy generation units.
“A self-developed cold storage ( Morgan and Dearman, 2013 ) was used for the full integration of liquefaction and energy generation units.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Morgan and Dearman, 2013
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenThe R&D activities were conducted by the Japanese company Hitachi, Ltd.
“The R&D activities were conducted by the Japanese company Hitachi, Ltd.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S1 (asserted), S3 (load-bearing).
PremisecitationThe round trip efficiency of the VPS cycle at a commercial scale is claimed to be greater than 95%.
“In a commercial document of the company that manufactures the system ( Liebowitz et al., 2013 ) the round trip efficiency of the VPS cycle at a commercial scale is claimed to be greater than 95%.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Liebowitz et al., 2013
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
InterpretationreasoningDearman vehicle engine cannot be considered as a direct application of electric energy storage through cryogenic energy conversion, but in some aspects it could be considered as a CEEM.
“Dearman vehicle engine cannot be considered as a direct application of the electric energy storage through cryogenic energy conversion, but in some aspects, it could also be considered as a CEEM.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe Wakana et al. design included a cold storage unit conceived in a specifically designed regenerator.
“As previously described, this design included a form of cold storage unit which is conceived in specifically designed regenerator.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Wakana et al. (2005)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe round trip efficiency of a CES system integrated with a nuclear power plant could be higher than 70%.
“The round trip efficiency of this system could be higher than 70%.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al. (2014)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe idea of using stored cold energy in refrigerated warehouses was first introduced by Fikiin et al. (2017).
“This idea was first introduced by Fikiin et al. (2017) .”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Fikiin et al. (2017) source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisereasoningAccording to the author, the poor value of 8% for the only fully built LAES demonstrator is due to the small size of the plant.
“According to the author, this poor value is due to the small size of the plant.”
Quote in the paperNot a substantial claim- Rests on an assumption: The only fully built LAES demonstrator has an RTE of 8% compared to a theoretical 49%.
Probably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenInitial research activities on energy storage and recovery via cryogens began with simplified systems using independent liquefaction/recovery subsystems.
“As described in this paper, initial research activities on energy storage and recovery via cryogens had begun with simplified systems using independent liquefaction/recovery subsystems.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationFour basic methods for Cryogenic Energy Extraction Methods are mentioned in the literature.
“In general, four basic methods for Cryogenic Energy Extraction Methods (CEEMs) are mentioned in literature ( Hamdy et al., 2017 ;Li et al., 2010a ) ( Fig 4 ).”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites Hamdy et al., 2017 source
- cites Li et al., 2010a
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe overall efficiency of the proposed system was claimed to reach 70%.
“The overall efficiency of the proposed system was claimed to reach 70%.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al. (2013)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
InterpretationreasoningIntegrating the LAES system would enable demand-side energy management and supply of cooling to refrigerated warehouses at the same time.
“Integrating the LAES system would enable demand-side energy management and supply of cooling to refrigerated warehouses at the same time.”
Quote in the paperNot a substantial claimClassified as probably not a substantial claim.
InterpretationreasoningThe advantage of this cycle would be that compression would be less energy intensive because the working fluid is at a lower absolute inlet temperature.
“The advantage of this cycle would be that the compression would be less energy intensive since the working fluid is at a lower absolute inlet temperature.”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThe Highview plant is now in operation and is providing power for around 200,000 homes during a day.
“The plant is now in operation and it is providing power for around 20 0,0 0 0 homes during a day ( Highviewpower, 2019 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Highviewpower, 2019
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
May combine two claims.
PremisecitationThe authors' analysis of this configuration yielded the highest power output and the best round trip efficiency (68%).
“The authors' analysis of this configuration yielded the highest power output and the best round trip efficiency (68%).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Antonelli et al. (2017) source
May combine two claims.
PremisecitationThe only reported performance indicator for the first prototype was the efficiency of the LA discharge system, which could reach 77%, without taking into account the energy consumed by the air liquefaction plant and accounting only for the chemical energy of the fuel burnt in the combustor.
“The only reported performance indicator was the efficiency of the LA discharge system which could reach 77%, without taking into account the energy consumed by the air liquefaction plant, but only accounting for the chemical energy of the fuel burnt in the combustor.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Kishimoto et al., 1998
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
InterpretationreasoningThe cycle that may replace Linde Hampson because of low complexity and enhanced efficiency is Solvay.
“The cycle that may replace Linde Hampson because of low complexity and enhanced efficiency is Solvay.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
InterpretationcitationAside from capturing and storing cold exergy for the liquefaction process, stored cold energy might also be used in refrigerated warehouses or food/pharmaceutical plants.
“Aside from capturing and storing the cold exergy of the released liquid air for the liquefaction process, the stored cold energy might also be used in refrigerated warehouses or food/pharmaceutical plants.”
Quote in the paperNot a substantial claimMay combine two claims.
InterpretationreasoningReplacement of the JT valve by a liquid turbine assures better efficiency with minimum investment.
“The replacement of JT valve by a Liquid turbine assures better efficiency with minimum investment.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationBy employing RES to liquefy and store cryogens, CryoHub balances the power grid while meeting the cooling demand of a refrigerated food warehouse and recovering waste heat from its equipment and components.
“By employing RES to liquefy and store cryogens, CryoHub balances the power grid, while meeting the cooling demand of a refrigerated food warehouse and recovering the waste heat from its equipment and components.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites CryoHub, 2019
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe first suggestion was to include an Organic Rankine Cycle where cryogenic temperatures of released liquid air could be used as the lower temperature sink of the ORC.
“The first suggestion was to include an Organic Rankine Cycle (ORC) where cryogenic temperatures of released liquid air could be used as the lower temperature sink of the ORC.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Antonelli et al. (2017) source
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationA second proposition consisted of a combustion-based cycle where air cooled by cryogen entered the compressor.
“A second proposition consisted of a combustion based cycle, where air cooled by cryogen entered the compressor.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Antonelli et al. (2017) source
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationA 100MW/600MWh 'best built' configuration was proposed and a round trip efficiency of 60% was claimed as achievable with current technology.
“A 10 0MW/60 0 MWh”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Morgan et al., 2014
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenOne of the most important features of cryogenic energy storage is that it can generate both mechanical/electrical energy and cold energy at the same time by the regasification process.
“As said in the beginning of this paragraph, one of the most important features of the cryogenic energy storage is that it can generate both mechanical/electrical energy and cold energy at the same time by the regasification process.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisereasoningTwo major groups of LAES are distinguished in literature: independent subsystems and thermally linked subsystems.
“Therefore, two major groups of LAES are distinguished in literature: “independent subsystems” and “thermally linked subsystems”.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S4 (based).
Interpretationnone givenLAES technology needs an important investment regarding the size of machinery required, including number of compressors and turbines and engineering/conception study price.
“LAES technology needs an important investment regarding the size of machinery required (number of compressors and turbines and engineering/conception study price).”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationHigh grade hot and cold storage and recycle is included in almost all recent studies related to cryogenic energy storage system for electrical storage applications, where mainly a super-heating based cycle is used for the generation process.
“High grade hot and cold storage and recycle is included in almost all recent studies related to cryogenic energy storage system for electrical storage applications ( Abdo et al., 2015 ;Ameel et al., 2013 ;Chino and Araki, 20 0 0 ;Li, 2011 ;Li et al., 2014 ;Morgan et al., 2015 ;Sciacovelli et al., 2017 ) where mainly a super-heating based cycle is used for the generation process.”
Quote in the paperNot a substantial claim0 of 3 sources checkedMay combine two claims.
InterpretationreasoningDepending on the industrial site where the CES is implemented, availability of a waste heat source is not certain, and therefore the RTE changes consequently.
“Depending on the industrial site where the CES is implemented, availability of waste heat source is not certain, and therefore, the of the RTE changes consequently.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationIn Li et al. (2013), air would be separated into liquid oxygen for oxy-fuel combustion of gas turbines and liquid nitrogen as the working fluid and medium of CO2 removal.
“In the latter study by Li et al. (2013) , the air would be separated into liquid oxygen (for the oxy-fuel combustion of the gas turbines), and liquid nitrogen (the working fluid in the circuit and the medium of CO 2 removal).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al. (2013)
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe process separates solid CO2 in the form of dry ice.
“The process then, separates solid CO 2 in the form of dry ice ( Li et al., 2013 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Li et al., 2013
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationOxy-fuel combustion with CO2 capture has been investigated by companies like Air Liquide and Alstom in the case of coal-fired power plants.
“Oxy-fuel combustion with CO2 capture has been investigated by companies like Air Liquide ( Châtel-Pélage et al., 2003 ) and Alstom ( Nsakala et al., 2001 ) in the case of coal-fired power plant.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites Châtel-Pélage et al., 2003
- cites Nsakala et al., 2001
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S4 (based).
Premisenone givenMany authors confirmed that integration between liquefaction and energy recovery units through cold and hot storage considerably enhances system performance.
“Many authors confirmed that the integration between liquefaction and energy recovery units through cold and hot storage considerably enhances the system performance.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationCryogenic energy can also be used for CO2 carbon capture and sequestration or more recently for turning CO2 into coal.
“The cryogenic energy can also be used for CO 2 carbon capture and for sequestration or more recently for turning it into coal ( Cockburn, 2019 ).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites Cockburn, 2019
Couldn’t be matched to a paper in Crossref, so it can’t be checked.
Probably not a substantial claim: may not pass S2 (checkable), S4 (based).
InterpretationreasoningThe possibility to increase energy recovery and energy efficiency while respecting environmental issues in renewable energy integration makes CES a potential method for large-scale EES.
“The possibility to increase the energy recovery and so the energy efficiency of the system, and to respect the environmental issues in the context of renewable energy integration, makes of the CES a potential method for the large scale EES.”
Quote in the paperNot a substantial claimMay combine two claims.
Premisenone givenStudies have shown attractive results of thermodynamic efficiency as well as possibilities of cogeneration of cold energy and/or hot energy depending on the industrial site needs where the plant is implemented.
“Studies have shown attractive results of thermodynamic efficiency as well as possibilities of cogeneration of cold energy or/and hot energy depending on the industrial site needs where the plant is implemented.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenLinde-Hampson, Claude and Solvay cycles were mentioned in previous works to be the most appropriate for cryogen liquefaction.
“Linde-Hampson, Claude and Solvay cycles were mentioned in previous works to be the most appropriate for cryogen liquefaction.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
InterpretationreasoningThe lack of experimental validation is due to huge investment related to the project, even at a demonstration level.
“This is due to huge investment related to the project, even at a demonstration level.”
Quote in the paperNot a substantial claimClassified as probably not a substantial claim. May combine two claims.
Interpretationnone givenOne advantage of LAES is its energy storage density, and another is its independence from location constraints such as gravitational potential for PHS or underground caves for CAES.
“One advantage of this technology is the energy storage density and, secondly, its independence from location constraints like the presence of a gravitational potential (PHS) or underground caves (CAES).”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S2 (checkable), S3 (load-bearing).
InterpretationreasoningMore and more integration possibilities can emerge from LAES in the form of by-products of liquid air production/use.
“More and more integration possibilities can emerge from LAES in the form of by-products of liquid air production/use.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenPotential round-trip efficiency has been claimed to be more than 80% when using combustion for the LA discharge cycle.
“Potential round-trip efficiency has been claimed to be more than 80% when using combustion for LA discharge cycle.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S4 (based).
Interpretationnone givenA difficulty of using liquid air as cryogen is that particular attention should be given to stratification and oxygen enrichment during storage.
“A difficulty of using liquid air used as cryogen is that a particular attention should be given to the problem of stratification and oxygen enrichment during storage.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Interpretationnone givenA part of liquefied oxygen or nitrogen can be sold on the market or provided for local use as sub-products without diverting from the main purpose of storing energy.
“A part of liquefied oxygen or nitrogen can be sold on the market or provided for local use as sub-products, without diverting from the main purpose of storing energy.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S4 (based). May combine two claims.
Interpretationnone givenThe combustion process has an undeniably negative impact on the environment, which conflicts with the environmentally friendly characteristic of LAES as a solution for the green energy transition.
“Combustion process has undeniably negative impact on the environment and this goes against the environmentally friendly characteristic of LAES as a solution for the green energy worldly transition.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenSuper-heating and combustion methods combined with direct expansion are the most popular energy recovery methods in studies related to CES or LAES.
“Super-heating and combustion methods combined to direct expansion are the most popular energy recovery methods in studies related to CES or LAES.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenCarbon capture and storage using liquid nitrogen is one of many options already investigated by some authors.
“As discussed previously, carbon capture and storage using liquid nitrogen is one of many options already investigated by some authors.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S4 (based).
Interpretationnone givenLAES is a novel EES technology that could respond to grid-scale requirements.
“LAES, as a particular sub-set of LAES, is a novel EES technology that could respond to grid-scale requirements.”
Quote in the paperNot a substantial claim
The authors state this as an assumption.
No review paper has been published so far about the CES topic.
“to the best of our knowledge, no review paper has been published so far about the CES topic.”
The paper relies on this without support.
LAES is still at the development and demonstration stage because no commercial or pre-commercial plants have been built.
“The current state of LAES is still at the development and demonstration stage since no commercial or pre-commercial plants have been built.”
The paper relies on this without support.
The only fully built LAES demonstrator has an RTE of 8% compared to a theoretical 49%.
“The only system that was fully built as LAES demonstrator has only 8% compared to the theoretical 49%.”
The paper relies on this without support.
Combustion includes CO2 emissions.
“But combustion also includes CO 2 emissions.”
The paper relies on this without support.
The use of liquid air energy storage as a large-scale energy storage technology has attracted more attention with the increased share of intermittent renewable energy sources connected to the electricity grid.
“The use of liquid air energy storage, as a large-scale energy storage technology, has attracted more and more attention with the increased share of intermittent renewable energy sources connected to the electricity grid.”
The paper relies on this without support.
The power generation sector is the main source of CO2 emissions worldwide.
“The power generation sector is the main source of CO 2 emissions worldwide.”
The paper relies on this without support.
Oxy-fuel combustion presents reduced NOx emission compared with usual air-firing.
“Oxy-fuel combustion should be considered since it presents reduced NOx emission than the usual air-firing.”
The paper relies on this without support.
CAES and PHS are constrained by geographical features.
“CAES and PHS are technologies currently deployed for large-scale energy storage which are constrained by geographical features.”
The paper relies on this without support.
Cryogenics have been used in superconductivity, rocketry, cryosurgery, and cooled electronics since the 1960s.
“In fact, hybridization of LAES is open to multiple opportunities when considering that cryogenics have been used in superconductivity, rocketry, cryosurgery, cooled electronics since the 60 s.”
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
Each contradiction between two passages listed here was confirmed by an independent check.
Pre-commercial plant described as both unbuilt and operating
MajorThe abstract says no pre-commercial plants have been built, but the introduction says construction of a pre-commercial plant began in 2015 and that it started operating in 2018.
“no commercial or pre-commercial plants have been built.”
“the construction of a pre-commercial plant by the same company began on February 2015 and operation has started from April 2018.”
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- Authors
- Damak, C., Leducq, D., Hoang, H. M., Negro, D., & Delahaye, A.
- Affiliations
- Génie des procédés FRIgorifiques pour la Sécurité alimentaire et l'Environnement (FR)
- London South Bank University (GB)
- Corresponding author
- Damak, Cyrine
- Venue
- International Journal of Refrigeration
- Publisher
- Elsevier BV
- Published
- 2020-02
- Volume
- 110
- Pages
- 208-218
- ISSN
- 0140-7007 (ISSN-L)
- OpenAlex
- W2989120982
- Semantic Scholar
- 0da2f6c42c620afb7913fd5ddd4e6b65ad88e45d
- Cited by
- 175
- References
- 40
- Citations by year
- 2026: 9 · 2025: 31 · 2024: 22 · 2023: 27 · 2022: 38 · 2021: 33 · 2020: 15
- FWCI
- 12.09
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- International Journal of Refrigeration (publishedVersion, cc-by)
- HAL (submittedVersion, other-oa)
- Funders
- European Commission
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Thermodynamic and Exergetic Analyses of Power and Cooling Systems
- Physical Sciences › Energy › Energy Engineering and Power Technology › Power Systems and Renewable Energy
- Physical Sciences › Engineering › Aerospace Engineering › Spacecraft and Cryogenic Technologies
- Keywords
- liquid air energy storage, cryogenic energy storage, electrical energy storage, renewable energy integration, grid balancing, cryogenic fluids, cold energy recovery, cold storage facilities, commercial viability
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