Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 160

The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.

Ru to W electron donation for boosted HER from acidic to alkaline on Ru/WNO sponges

Meng, Ge, Tian, Han, Peng, Lingxin, Ma, Zhonghua, Chen, Yafeng, Chen, Chang, Chang, Ziwei, Cui, Xiangzhi, Shi, Jianlin·2021·Nano Energy
DOI 10.1016/j.nanoen.2020.105531
Open this paper in CoChat — free account

Abstract

Abstract Developing high-efficiency hydrogen evolution reaction (HER) catalysts is of great interest for the large-scale high-purity hydrogen production, which, unfortunately, is largely blocked by the sluggish kinetics of the electro-chemical dissociation step of water molecules. Herein, a MOF-derived method has been developed to prepare Ru nanoparticles-anchored sponge-like WNO embedded in N-doped carbon layers (Ru@WNO-C). The fabricated catalyst Ru@WNO-C (Ru: 0.9 wt%) shows excellent HER catalytic activity and long-term stability with the overpotentials of 172, 358 and 24 mV at 10 mA/cm2 in 0.5 M H2SO4, 1 M Na2SO4 and 1 M KOH, respectively. More impressively, the overpotentials, especially in neutral medium, decrease markedly during the durability tests owing to the catalyst structure activation after residual Zn species leaching. The enhanced catalytic activity of Ru@WNO-C during operation is mainly attributed to the in-situ electron donation from Ru to W, leading to the easier cleavage of highly polarized H‒OH bond of water molecules and thus endowing Ru@WNO-C with excellent HER catalytic performance in non-acidic solution.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1016/j.nanoen.2020.105531

Cites

11 of 11 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 11 references

Research works printed but not linked: 51

  1. Zhao, 2018, Heterostructures for electrochemical hydrogen evolution reaction: a review, Adv. Funct. Mater., 28, 10.1002/adfm.201803291 · DOI · Paper page
  2. Yu, 2019, A hierarchically porous and hydrophilic 3D nickel–iron/MXene electrode for accelerating oxygen and hydrogen evolution at high current densities, Nano Energy, 63, 10.1016/j.nanoen.2019.103880 · DOI · Paper page
  3. Song, 2018, Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions, Nat. Commun., 9, 4531, 10.1038/s41467-018-06728-7 · DOI · Paper page
  4. Guo, 2019, Intermediate modulation on noble metal hybridized to 2D metal-organic framework for accelerated water electrocatalysis, Chem, 5, 2429, 10.1016/j.chempr.2019.06.016 · DOI · Paper page
  5. Yu, 2012, Review of Pt-based bimetallic catalysis: from model surfaces to supported catalysts, Chem. Rev., 112, 5780, 10.1021/cr300096b · DOI · Paper page
  6. Park, 2019, Investigation of the support effect in atomically dispersed Pt on WO3−xfor utilization of Pt in the hydrogen evolution reaction, Angew. Chem., Int. Ed., 58, 16038, 10.1002/anie.201908122 · DOI · Paper page
  7. Markovic, 1996, Hydrogen electrochemistry on platinum low-index single-crystal surfaces in alkaline solution, J. Chem. Soc. Faraday Trans., 92, 3719, 10.1039/FT9969203719 · DOI · Paper page
  8. Lu, 2019, Highly crystalline Ni-doped FeP/carbon hollow nanorods as all-pH efficient and durable hydrogen evolving electrocatalysts, Sci. Adv., 5, 10.1126/sciadv.aav6009 · DOI · Paper page
  9. Men, 2019, Tailoring the electronic structure of Co2P by N doping for boosting hydrogen evolution reaction at all pH values, ACS Catal., 9, 3744, 10.1021/acscatal.9b00407 · DOI · Paper page
  10. Zhuang, 2019, Three-dimensional open nano-netcage electrocatalysts for efficient pH-universal overall water splitting, Nat. Commun., 10, 4875, 10.1038/s41467-019-12885-0 · DOI · Paper page
  11. Wang, 2020, ACS Appl. Energy Mater., 3, 1027, 10.1021/acsaem.9b02075 · DOI
  12. Xiao, 2020, Hierarchical ultrathin carbon encapsulating transition metal doped MoP electrocatalysts for efficient and pH-universal hydrogen evolution reaction, Nano Energy, 70, 10.1016/j.nanoen.2020.104445 · DOI · Paper page
  13. Hu, 2018, Coordination-assisted polymerization of mesoporous cobalt sulfide/heteroatom (N,S)-doped double-layered carbon tubes as an efficient bifunctional oxygen electrocatalyst, ACS Appl. Mater. Interfaces, 10, 33124, 10.1021/acsami.8b07343 · DOI
  14. Zhang, 2019, Cable-like Ru/WNO@C nanowires for simultaneous high-efficiency hydrogen evolution and low-energy consumption chlor-alkali electrolysis, Energy Environ. Sci., 12, 2569, 10.1039/C9EE01647C · DOI · Paper page
  15. Liu, 2019, Hierarchical bimetallic Ni–Co–P microflowers with ultrathin nanosheet arrays for efficient hydrogen evolution reaction over all pH values, ACS Appl. Mater. Interfaces, 11, 42233, 10.1021/acsami.9b15194 · DOI
  16. Dou, 2020, How cobalt and iron doping determine the oxygen evolution electrocatalytic activity of NiOOH, Cell Rep. Phys. Sci., 1
  17. Zhang, 2018, Activity origins in nanocarbons for the electrocatalytic hydrogen evolution reaction, Small, 14
  18. Jin, 2018, Transition metal induced the contraction of tungsten carbide lattice as superior hydrogen evolution reaction catalyst, ACS Appl. Mater. Interfaces, 10, 22094, 10.1021/acsami.8b04553 · DOI
  19. Zhao, 2020, Synergistically interactive pyridinic‐N–MoP sites: identified active centers for enhanced hydrogen evolution in alkaline solution, Angew. Chem. Int. Ed., 59, 8982, 10.1002/anie.201908760 · DOI · Paper page
  20. Zhang, 2019, Tailoring active sites in mesoporous defect‐rich NC/Vo‐WON heterostructure array for superior electrocatalytic hydrogen evolution, Adv. Energy Mater., 9
  21. Yu, 2015, Holey tungsten oxynitride nanowires: novel anodes efficiently integrate microbial chemical energy conversion and electrochemical energy storage, Adv. Mater., 27, 3085, 10.1002/adma.201500493 · DOI · Paper page
  22. Li, 2015, N-doped carbon-coated tungsten oxynitride nanowire arrays for highly efficient electrochemical hydrogen evolution, Chemsuschem, 8, 2487, 10.1002/cssc.201500398 · DOI
  23. Yu, 2019, Recent advances and prospective in ruthenium-based materials for electrochemical water splitting, ACS Catal., 9, 9973, 10.1021/acscatal.9b02457 · DOI · Paper page
  24. Kresse, 1996, Efficient iterative schemes forab initiototal-energy calculations using a plane-wave basis set, Phys. Rev. B, 54, 11169, 10.1103/PhysRevB.54.11169 · DOI · Paper page
  25. Kresse, 1996, Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set, Comp. Mater. Sci., 6, 15, 10.1016/0927-0256(96)00008-0 · DOI · Paper page
  26. Perdew, 1996, Generalized gradient approximation made simple, Phys. Rev. Lett., 77, 3865, 10.1103/PhysRevLett.77.3865 · DOI · Paper page
  27. Kresse, 1999, From ultrasoft pseudopotentials to the projector augmented-wave method, Phys. Rev. B, 59, 1758, 10.1103/PhysRevB.59.1758 · DOI · Paper page
  28. Grimme, 2010, Chem. Phys., 132
  29. Monkhorst, 1976, Special points for Brillouin-zone integrations, Phys. Rev. B, 13, 5188, 10.1103/PhysRevB.13.5188 · DOI · Paper page
  30. Henkelman, 2000, A climbing image nudged elastic band method for finding saddle points and minimum energy paths, J. Chem. Phys., 113, 9901, 10.1063/1.1329672 · DOI · Paper page
  31. Henkelman, 2000, Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points, J. Chem. Phys., 113, 9978, 10.1063/1.1323224 · DOI · Paper page
  32. Nørskov, 2005, Trends in the exchange current for hydrogen evolution, J. Electrochem. Soc., 152, J23, 10.1149/1.1856988 · DOI · Paper page
  33. Zhao, 2007, Preparation and characterization of tungsten oxynitride nanowires, J. Mater. Chem., 17, 4436, 10.1039/b709486h · doi:10.1039/b709486h
  34. Kartachova, 2012, Electrochemical capacitance of mesoporous tungsten oxynitride in aqueous electrolytes, Sources, 220, 298, 10.1016/j.jpowsour.2012.07.132 · doi:10.1016/j.jpowsour.2012.07.132
  35. Yuan, 2019, A universal synthesis strategy for single atom dispersed cobalt/metal clusters heterostructure boosting hydrogen evolution catalysis at all pH values, Nano Energy, 59, 472, 10.1016/j.nanoen.2019.02.062 · DOI · Paper page
  36. Jiang, 2019, Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER, Energy Environ. Sci., 12, 322, 10.1039/C8EE03276A · DOI · Paper page
  37. Xu, 2012, Patterned growth of tungsten oxide and tungsten oxynitride nanorods from Au-coated W foil, Nanoscale, 4, 7031, 10.1039/c2nr32169f · doi:10.1039/c2nr32169f
  38. Fujioka, 2013, Formation of ruthenium cluster on nanocrystalline tungsten trioxide, J. Phys. Chem. C, 117, 7506, 10.1021/jp310038a · doi:10.1021/jp310038a
  39. Fujioka, 2012, Structural properties of pure and nickel-modified nanocrystalline tungsten trioxide, J. Phys. Chem. C, 16, 17029, 10.1021/jp304082t · doi:10.1021/jp304082t
  40. Cao, 2019, Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution, Nat. Catal., 2, 134, 10.1038/s41929-018-0203-5 · DOI · Paper page
  41. Zhong, 2019, Enhanced synergistic catalysis by a novel triple-phase interface design of NiO/Ru@Ni for the hydrogen evolution reaction, J. Mater. Chem. A, 7, 2344, 10.1039/C8TA11171E · DOI
  42. Sun, 2019, High-performance Ru@C4N electrocatalyst for hydrogen evolution reaction in both acidic and alkaline solutions, ACS Appl. Mater. Interfaces, 11, 19176, 10.1021/acsami.9b04255 · DOI
  43. Zhu, 2018, Rationally designed hierarchically structured tungsten nitride and nitrogen-rich graphene-like carbon nanocomposite as efficient hydrogen evolution electrocatalyst, Adv. Sci., 5, 10.1002/advs.201700603 · DOI · Paper page
  44. Chen, 2019, Low‐coordinate iridium oxide confined on graphitic carbon nitride for highly efficient oxygen evolution, Angew. Chem. Int. Ed., 58, 12540, 10.1002/anie.201907017 · DOI · Paper page
  45. Wu, 2019, Regulating the allocation of N and P in codoped grapheneviasupramolecular control to remarkably boost hydrogen evolution, Energy Environ. Sci., 12, 2697, 10.1039/C9EE00555B · DOI
  46. Lei, 2019, Efficient alkaline hydrogen evolution on atomically dispersed Ni–NxSpecies anchored porous carbon with embedded Ni nanoparticles by accelerating water dissociation kinetics, Energy Environ. Sci., 12, 149, 10.1039/C8EE01841C · DOI · Paper page
  47. Sun, 2018, Ultrathin nitrogen-doped Holey carbon@graphene bifunctional electrocatalyst for oxygen reduction and evolution reactions in alkaline and acidic media, Angew. Chem. Int. Ed., 57, 16511, 10.1002/anie.201811573 · DOI · Paper page
  48. Wang, 2018, Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction, Energy Environ. Sci., 11, 800, 10.1039/C7EE03345A · DOI · Paper page
  49. Wu, 2017, Stabilizing the MXenes by carbon nanoplating for developing hierarchical nanohybrids with efficient lithium storage and hydrogen evolution capability, Adv. Mater., 29, 10.1002/adma.201607017 · DOI · Paper page
  50. Li, 2015, Under-water superaerophobic pine-shaped Pt nanoarray electrode for ultrahigh-performance hydrogen evolution, Adv. Funct. Mater., 25, 1737, 10.1002/adfm.201404250 · DOI · Paper page
  51. Liu, 2018, Few layered N, P dual-doped carbon-encapsulated ultrafine MoP nanocrystal/MoP cluster hybrids on carbon cloth: an ultrahigh active and durable 3D self-supported integrated electrode for hydrogen evolution reaction in a wide pH range, Adv. Funct. Mater., 28

Cited by

See all 160

Metadata

Authors
Meng, G., Tian, H., Peng, L., Ma, Z., Chen, Y., Chen, C., Chang, Z., Cui, X., & Shi, J.
Venue
Nano Energy
Publisher
Elsevier BV
Published
2021-02
Volume
80
Pages
105531
ISSN
2211-2855 (ISSN-L)
DOI
10.1016/j.nanoen.2020.105531
OpenAlex
W3097853434
Cited by
160
References
11
FWCI
3.90
Type
journal article
Language
en
Open access
closed
Licence
Funders
  • State Key Laboratory for Modification of Chemical Fibers and Polymer Materials
  • Natural Science Foundation of Shanghai (19ZR 1479400)
  • Donghua University (KF1818)
  • Wuhan University of Technology

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Ru to W electron donation for boosted HER from acidic to alkaline on Ru/WNO sponges. https://app.cochat.ai/papers/10.1016/j.nanoen.2020.105531
The paper
Meng, G., Tian, H., Peng, L., Ma, Z., Chen, Y., Chen, C., Chang, Z., Cui, X., & Shi, J. (2021). Ru to W electron donation for boosted HER from acidic to alkaline on Ru/WNO sponges. Nano Energy. https://doi.org/10.1016/j.nanoen.2020.105531

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.