Quantitative evaluation of fractionated and homogeneous nucleation of polydisperse distributions of water-dispersed maleic anhydride-grafted-polypropylene micro-and nano-sized droplets
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In polydisperse systems, curvature in the first-order kinetic plot can be appreciated because larger droplets solidify before smaller ones, giving more complex and time-dependent kinetics.
“In the case of particularly polydisperse systems, a certain curvature can be appreciated [36] , since larger droplets will solidify before smaller ones, giving rise to a more complex and timedependent kinetics.”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [36]
For waterborne iPP microemulsions, both surface and volume-based nucleation equations could fit the kinetic data, but in light of the explored crystallization temperature range, the mechanism can probably be attributed to homogeneous nucleation.
“For the case of waterborne iPP microemulsions, both surface and volume-based nucleation equations could fit the obtained kinetic data appropriately [36] , however, in light of the explored crystallization temperature range, we can probably attribute the mechanism to homogeneous nucleation (see later section 3.2 ).”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [36]
The selected non-isothermal crystallization temperatures of iPP in isolated polymer domains are ascribed to the homogeneous nucleation mechanism.
“The selected temperatures are ascribed to the homogeneous nucleation mechanism.”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [36]
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Self-citation- Self-citation
- Authors
- Ibarretxe, J., Groeninckx, G., Bremer, L., & Mathot, V. B. F.
- Affiliations
- DSM (Netherlands) (NL)
- KU Leuven (BE)
- Corresponding author
- Mathot, V.B.F.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2009-09
- Volume
- 50
- Issue
- 19
- Pages
- 4584-4595
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2053583001
- Cited by
- 34
- References
- 36
- Citations by year
- 2023: 1 · 2022: 3 · 2021: 3 · 2020: 1 · 2019: 1 · 2018: 2 · 2017: 3 · 2016: 3 · 2015: 7 · 2013: 2 · 2012: 2
- FWCI
- 2.24
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Funders
- KU Leuven
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › nanoparticles nucleation surface interactions
- Keywords
- maleic anhydride grafted polypropylene, waterborne dispersions, homogeneous nucleation, heterogeneous nucleation, self-nucleation, nucleation rate, polydispersity, particle size distribution, polypropylene crystallization, nucleation kinetics
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