The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Stable Zr(IV)-Based Metal–Organic Frameworks with Predesigned Functionalized Ligands for Highly Selective Detection of Fe(III) Ions in Water
Abstract
Metal–organic frameworks are a class of attractive materials for fluorescent sensing. Improvement of hydrolytic stability, sensitivity, and selectivity of function is the key to advance application of fluorescent MOFs in aqueous media. In this work, two stable MOFs, [Zr 6 O 4 (OH) 8 (H 2 O) 4 (L 1 ) 2 ] (BUT-14) and [Zr 6 O 4 (OH) 8 (H 2 O) 4 (L 2 ) 2 ] (BUT-15), were designed and synthesized for the detection of metal ions in water. Two new ligands utilized for construction of the MOFs, namely, 5′,5‴-bis(4-carboxyphenyl)-[1,1′:3′,1″:4″,1‴:3‴,1′′′′-quinquephenyl]-4,4′′′′-dicarboxylate (L 1 ) and 4,4′,4″,4‴-(4,4′-(1,4-phenylene)bis(pyridine-6,4,2-triyl))tetrabenzoate (L 2 ), are structurally similar with the only difference being that the latter is functionalized by pyridine N atoms. The two MOFs are isostructural with a sqc - a topological framework structure, and highly porous with the Brunauer–Emmett–Teller (BET) surface areas of 3595 and 3590 m 2 g –1, respectively. Interestingly, they show intense fluorescence in water, which can be solely quenched by trace amounts of Fe 3+ ions. The detection limits toward the Fe 3+ ions were calculated to be 212 and 16 ppb, respectively. The efficient fluorescent quenching effect is attributed to the photoinduced electron transfer between Fe 3+ ions and the ligands in these MOFs. Moreover, the introduced pyridine N donors in the ligand of BUT-15 additionally donate their lone-pair electrons to the Fe 3+ ions, leading to significantly enhanced detection ability. It is also demonstrated that BUT-15 exhibits an uncompromised performance for the detection of Fe 3+ ions in a simulated biological system.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Single-crystal structure validation with the program PLATON
Spek, A. L. (2003) · Journal of Applied Crystallography · doi:10.1107/s0021889802022112 · Cited by 14,084
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Self-citationLuminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430
Luminescent metal–organic frameworks
Allendorf, M. D., Bauer, C. A., Bhakta, R. K., & Houk, R. J. T. (2009) · Chemical Society Reviews · doi:10.1039/b802352m · Cited by 4,960
Luminescent metal–organic frameworks for chemical sensing and explosive detection
Hu, Z., Deibert, B. J., & Li, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00010b · Cited by 4,169
Self-citationApplications of metal–organic frameworks in heterogeneous supramolecular catalysis
Liu, J., Chen, L., Cui, H., Zhang, J., Zhang, L., & Su, C.-Y. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00094c · Cited by 2,894
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500330a · Cited by 2,888
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
Bai, Y., Dou, Y., Xie, L.-H., Rutledge, W., Li, J.-R., & Zhou, H.-C. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00837a · Cited by 2,545
Self-citationAndrews, N. C. (1999) · New England Journal of Medicine · doi:10.1056/nejm199912233412607 · Cited by 2,130
Feng, D., Gu, Z., Li, J., Jiang, H., Wei, Z., & Zhou, H. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204475 · Cited by 1,978
Self-citationWang, B., Lv, X.-L., Feng, D., Xie, L.-H., Zhang, J., Li, M., Xie, Y., Li, J.-R., & Zhou, H.-C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01663 · Cited by 1,568
Self-citationWater adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
Aragay, G., Pons, J., & Merkoçi, A. (2011) · Chemical Reviews · doi:10.1021/cr100383r · Cited by 1,396
Highly Selective Detection of Nitro Explosives by a Luminescent Metal–Organic Framework
Nagarkar, S. S., Joarder, B., Chaudhari, A. K., Mukherjee, S., & Ghosh, S. K. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201208885 · Cited by 1,353
Pramanik, S., Zheng, C., Zhang, X., Emge, T. J., & Li, J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja106851d · Cited by 1,137
Self-citationA Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions
Chen, B., Wang, L., Zapata, F., Qian, G., & Lobkovsky, E. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802035e · Cited by 1,014
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
Mondloch, J. E., Bury, W., Fairen-Jimenez, D., Kwon, S., DeMarco, E. J., Weston, M. H., Sarjeant, A. A., Nguyen, S. T., Stair, P. C., Snurr, R. Q., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4050828 · Cited by 1,008
Iron and Oxidative Stress in Bacteria
Touati, D. (2000) · Archives of Biochemistry and Biophysics · doi:10.1006/abbi.1999.1518 · Cited by 924
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M. (2012) · Inorganic Chemistry · doi:10.1021/ic300825s · Cited by 906
Alezi, D., Belmabkhout, Y., Suyetin, M., Bhatt, P. M., Weseliński, Ł. J., Solovyeva, V., Adil, K., Spanopoulos, I., Trikalitis, P. N., Emwas, A.-H., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b07053 · Cited by 839
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence
Jiang, H., Feng, D., Wang, K., Gu, Z., Wei, Z., Chen, Y., & Zhou, H.-C. “. (2013) · Journal of the American Chemical Society · doi:10.1021/ja406844r · Cited by 740
New fluorescent chemosensors for metal ions in solution
Formica, M., Fusi, V., Giorgi, L., & Micheloni, M. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2011.09.010 · Cited by 722
Luminescent Materials: Locking π‐Conjugated and Heterocyclic Ligands with Boron(III)
Frath, D., Massue, J., Ulrich, G., & Ziessel, R. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201305554 · Cited by 628
Superacidity in Sulfated Metal–Organic Framework-808
Jiang, J., Gándara, F., Zhang, Y.-B., Na, K., Yaghi, O. M., & Klemperer, W. G. (2014) · Journal of the American Chemical Society · doi:10.1021/ja507119n · Cited by 606
Zheng, M., Tan, H., Xie, Z., Zhang, L., Jing, X., & Sun, Z. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am302862k · Cited by 520
Nagarkar, S. S., Desai, A. V., & Ghosh, S. K. (2014) · Chem. Commun. · doi:10.1039/c4cc03053b · Cited by 505
Wanderley, M. M., Wang, C., Wu, C.-D., & Lin, W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302110d · Cited by 455
Ong, T., Michaelis, V. K., Shustova, N. B., Cozzolino, A. F., Griffin, R. G., & Dincă, M. (2012) · DSpace@MIT (Massachusetts Institute of Technology) · Cited by 432
Cation Sensing by a Luminescent Metal–Organic Framework with Multiple Lewis Basic Sites
Tang, Q., Liu, S., Liu, Y., Miao, J., Li, S., Zhang, L., Shi, Z., & Zheng, Z. (2013) · Inorganic Chemistry · doi:10.1021/ic400029p · Cited by 404
Rudd, N. D., Wang, H., Fuentes-Fernandez, E. M. A., Teat, S. J., Chen, F., Hall, G., Chabal, Y. J., & Li, J. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b10890 · Cited by 399
Self-citationDong, X.-Y., Wang, R., Wang, J.-Z., Zang, S.-Q., & Mak, T. C. W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04421e · Cited by 357
Zhou, X.-H., Li, L., Li, H.-H., Li, A., Yang, T., & Huang, W. (2013) · Dalton Transactions · doi:10.1039/c3dt51081f · Cited by 352
Chen, S., Shi, Z., Qin, L., Jia, H., & Zheng, H. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.6b01197 · Cited by 324
Zhou, Y., Chen, H.-H., & Yan, B. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta01297f · Cited by 307
Chen, Z., Sun, Y., Zhang, L., Sun, D., Liu, F., Meng, Q., Wang, R., & Sun, D. (2013) · Chemical Communications · doi:10.1039/c3cc46613b · Cited by 296
Self-citationA chiral lanthanide metal–organic framework for selective sensing of Fe(iii) ions
Zhao, X.-L., Tian, D., Gao, Q., Sun, H.-W., Xu, J., & Bu, X.-H. (2016) · Dalton Transactions · doi:10.1039/c5dt03283k · Cited by 289
Tuning CO2 Selective Adsorption over N2 and CH4 in UiO-67 Analogues through Ligand Functionalization
Wang, B., Huang, H., Lv, X.-L., Xie, Y., Li, M., & Li, J.-R. (2014) · Inorganic Chemistry · doi:10.1021/ic5013473 · Cited by 278
Self-citationFan, L.-J., Zhang, Y., Murphy, C. B., Angell, S. E., Parker, M. F. L., Flynn, B. R., & Jones, W. E. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.03.008 · Cited by 260
A Water-Stable Metal–Organic Framework for Highly Sensitive and Selective Sensing of Fe3+ Ion
Hou, B.-L., Tian, D., Liu, J., Dong, L.-Z., Li, S.-L., Li, D.-S., & Lan, Y.-Q. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b01809 · Cited by 251
Choi, Y., Park, Y., Kang, T., & Lee, L. P. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.258 · Cited by 250
MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates
Deria, P., Bury, W., Hod, I., Kung, C.-W., Karagiaridi, O., Hupp, J. T., & Farha, O. K. (2015) · Inorganic Chemistry · doi:10.1021/ic502639v · Cited by 215
An amine-functionalized metal–organic framework as a sensing platform for DNA detection
Zhang, H.-T., Zhang, J.-W., Huang, G., Du, Z.-Y., & Jiang, H.-L. (2014) · Chem. Commun. · doi:10.1039/c4cc05571c · Cited by 198
Ultraporous, Water Stable, and Breathing Zirconium-Based Metal–Organic Frameworks with ftw Topology
Deria, P., Gómez-Gualdrón, D. A., Bury, W., Schaef, H. T., Wang, T. C., Thallapally, P. K., Sarjeant, A. A., Snurr, R. Q., Hupp, J. T., & Farha, O. K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08860 · Cited by 166
Deria, P., Chung, Y. G., Snurr, R. Q., Hupp, J. T., & Farha, O. K. (2015) · Chemical Science · doi:10.1039/c5sc01784j · Cited by 133
Topology-dependent emissive properties of zirconium-based porphyrin MOFs
Deria, P., Yu, J., Balaraman, R. P., Mashni, J. A., & White, S. N. (2016) · Chemical Communications · doi:10.1039/c6cc07343c · Cited by 91
Lin, X., Hong, Y., Zhang, C., Huang, R., Wang, C., & Lin, W. (2015) · Chemical Communications · doi:10.1039/c5cc06453h · Cited by 64
Gaining Insights on the H2–Sorbent Interactions: Robust soc-MOF Platform as a Case Study
Cairns, A., Eckert, J., Wojtas, Ł., Thommes, M., Wallacher, D., Georgiev, P. A., Forster, P. M., Belmabkhout, Y., Ollivier, J., & Eddaoudi, M. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02817 · Cited by 59
Gao, M., Wei, N., & Han, Z. (2016) · RSC Advances · doi:10.1039/c6ra08500h · Cited by 35
Cited by
When defects turn into virtues: The curious case of zirconium-based metal-organic frameworks
Taddei, M. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.04.010 · Cited by 341
Liu, W., Liu, Y., Yuan, Z., & Lu, C. (2023) · Industrial Chemistry & Materials · doi:10.1039/d2im00024e · Cited by 71
Metadata
- Authors
- Wang, B., Yang, Q., Guo, C., Sun, Y., Xie, L.-H., & Li, J.-R.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-03-10
- Volume
- 9
- Issue
- 11
- Pages
- 10286-10295
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2593194056
- Cited by
- 423
- References
- 52
- FWCI
- 21.00
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
