The DOI matches its Crossref record; 74 of the 74 references it cites were found in a registry or an index.
In Situ Transformation of Hydrogen-Evolving CoP Nanoparticles: Toward Efficient Oxygen Evolution Catalysts Bearing Dispersed Morphologies with Co-oxo/hydroxo Molecular Units
Abstract
Reported herein is elucidation of a novel Co-based oxygen evolution catalyst generated in situ from cobalt phosphide (CoP) nanoparticles. The present CoP nanoparticles, efficient alkaline hydrogen-evolving materials at the cathode, are revealed to experience unique metamorphosis upon anodic potential cycling in an alkaline electrolyte, engendering efficient and robust catalytic environments toward the oxygen evolution reaction (OER). Our extensive ex situ characterization shows that the transformed catalyst bears porous and nanoweb-like dispersed morphologies along with unique microscopic environments mainly consisting of discrete cobalt-oxo/hydroxo molecular units within a phosphate-enriched amorphous network. Outstanding OER efficiency is achievable with the activated catalyst, which is favorably comparable to even a precious iridium catalyst. A more remarkable feature is its outstanding long-term stability, superior to iridium and conventional cobalt oxide-based materials. Twelve-hour bulk electrolysis continuously operating at high current density is completely tolerable with the present catalyst.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Biesinger, M. C., Payne, B. P., Grosvenor, A. P., Lau, L. W. M., Gerson, A. R., & Smart, R. S. C. (2011) · Applied Surface Science · doi:10.1016/j.apsusc.2010.10.051 · Cited by 11,640
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
Liang, Y., Li, Y., Wang, H., Zhou, J., Wang, J., Regier, T., & Dai, H. (2011) · Nature Materials · doi:10.1038/nmat3087 · Cited by 5,494
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B., & Shao-Horn, Y. (2011) · Science · doi:10.1126/science.1212858 · Cited by 5,441
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
Cook, T. R., Dogutan, D. K., Reece, S. Y., Surendranath, Y., Teets, T. S., & Nocera, D. G. (2010) · Chemical Reviews · doi:10.1021/cr100246c · Cited by 3,064
Subbaraman, R., Tripkovic, D., Chang, K.-C., Strmcnik, D., Paulikas, A. P., Hirunsit, P., Chan, M., Greeley, J., Stamenkovic, V., & Markovic, N. M. (2012) · Nature Materials · doi:10.1038/nmat3313 · Cited by 3,053
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250
Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodiscs
Yang, J., Liu, H., Martens, W. N., & Frost, R. L. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp908548f · Cited by 1,719
Water-Splitting Chemistry of Photosystem II
McEvoy, J. P., & Brudvig, G. W. (2006) · Chemical Reviews · doi:10.1021/cr0204294 · Cited by 1,550
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
Yin, Q., Tan, J. M., Besson, C., Geletii, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., & Hill, C. L. (2010) · Science · doi:10.1126/science.1185372 · Cited by 1,438
Enhanced Activity of Gold-Supported Cobalt Oxide for the Electrochemical Evolution of Oxygen
Yeo, B. S., & Bell, A. T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200559j · Cited by 1,421
Bajdich, M., García-Mota, M., Vojvodic, A., Nørskov, J. K., & Bell, A. T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405997s · Cited by 1,403
Kong, D., Wang, H., Lu, Z., & Cui, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501497n · Cited by 1,392
Liang, Y., Wang, H., Zhou, J., Li, Y., Wang, J., Regier, T., & Dai, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210924t · Cited by 1,374
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
Vrubel, H., & Hu, X. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207111 · Cited by 1,302
Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction
Xiao, P., Sk, M. A., Thia, L., Ge, X., Lim, R. J., Wang, J.-Y., Lim, K. H., & Wang, X. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00957f · Cited by 1,297
Hydrogen‐Evolution Catalysts Based on Non‐Noble Metal Nickel–Molybdenum Nitride Nanosheets
Chen, W., Sasaki, K., Ma, C., Frenkel, A. I., Marinkovic, N., Muckerman, J. T., Zhu, Y., & Adzic, R. R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200699 · Cited by 1,297
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
Surendranath, Y., Kanan, M. W., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106102b · Cited by 1,232
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Liu, Q., Tian, J., Cui, W., Jiang, P., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201404161 · Cited by 1,117
Low Overpotential in Vacancy-Rich Ultrathin CoSe2 Nanosheets for Water Oxidation
Liu, Y., Cheng, H., Lyu, M., Fan, S., Liu, Q., Zhang, W., Zhi, Y., Wang, C., Xiao, C., Wei, S., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5085157 · Cited by 1,094
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production
Chen, W.-F., Wang, C.-H., Sasaki, K., Marinkovic, N., Xu, W., Muckerman, J. T., Zhu, Y., & Adzic, R. R. (2013) · Energy & Environmental Science · doi:10.1039/c2ee23891h · Cited by 934
Tian, J., Liu, Q., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403842 · Cited by 848
A Janus cobalt-based catalytic material for electro-splitting of water
Cobo, S., Heidkamp, J., Jacques, P.-A., Fize, J., Fourmond, V., Guetaz, L., Jousselme, B., Ivanova, V., Dau, H., Palacin, S., et al. (2012) · Nature Materials · doi:10.1038/nmat3385 · Cited by 845
Gerken, J. B., McAlpin, J. G., Chen, J. Y. C., Rigsby, M. L., Casey, W. H., Britt, R. D., & Stahl, S. S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja205647m · Cited by 814
Liang, Y., Wang, H., Diao, P., Chang, W., Hong, G., Li, Y., Gong, M., Xie, L., Zhou, J., Wang, J., et al. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305623m · Cited by 794
Cobalt–phosphate oxygen-evolving compound
Kanan, M. W., Surendranath, Y., & Nocera, D. G. (2009) · Chem. Soc. Rev. · doi:10.1039/b802885k · Cited by 740
Electrocatalytic properties of transition metal oxides for oxygen evolution reaction
Matsumoto, Y., & Sato, E. (1986) · Materials Chemistry and Physics · doi:10.1016/0254-0584(86)90045-3 · Cited by 717
Kanan, M. W., Yano, J., Surendranath, Y., Dincă, M., Yachandra, V. K., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1023767 · Cited by 711
Water Oxidation Electrocatalyzed by an Efficient Mn3O4/CoSe2Nanocomposite
Gao, M.-R., Xu, Y.-F., Jiang, J., Zheng, Y.-R., & Yu, S.-H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja211526y · Cited by 681
Doyle, R. L., Godwin, I. J., Brandon, M. P., & Lyons, M. E. G. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp51213d · Cited by 600
EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH
McAlpin, J. G., Surendranath, Y., Dincǎ, M., Stich, T. A., Stoian, S. A., Casey, W. H., Nocera, D. G., & Britt, R. D. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1013344 · Cited by 545
Nitrogen-Doped Graphene Supported CoSe2Nanobelt Composite Catalyst for Efficient Water Oxidation
Gao, M.-R., Cao, X., Gao, Q., Xu, Y.-F., Zheng, Y.-R., Jiang, J., & Yu, S.-H. (2014) · ACS Nano · doi:10.1021/nn500880v · Cited by 537
Size-Dependent Activity of Co3O4 Nanoparticle Anodes for Alkaline Water Electrolysis
Esswein, A. J., McMurdo, M. J., Ross, P. N., Bell, A. T., & Tilley, T. D. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp904022e · Cited by 534
Grosvenor, A. P., Wik, S. D., Cavell, R. G., & Mar, A. (2005) · Inorganic Chemistry · doi:10.1021/ic051004d · Cited by 464
Zou, X., Goswami, A., & Asefa, T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407174u · Cited by 425
A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries
Lu, J., Lei, Y., Lau, K. C., Luo, X., Du, P., Wen, J., Assary, R. S., Das, U., Miller, D. J., Elam, J. W., et al. (2013) · Nature Communications · doi:10.1038/ncomms3383 · Cited by 424
Ordered Mesoporous Cobalt Oxide as Highly Efficient Oxygen Evolution Catalyst
Rosen, J., Hutchings, G. S., & Jiao, F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja400555q · Cited by 419
Xu, Y., Gao, M., Zheng, Y., Jiang, J., & Yu, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303495 · Cited by 403
Feng, L., Vrubel, H., Bensimon, M., & Hu, X. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00482e · Cited by 402
Lyons, M. E. G., & Brandon, M. P. (2008) · International Journal of Electrochemical Science · doi:10.1016/s1452-3981(23)15531-3 · Cited by 380
Lyons, M. E. G., & Brandon, M. P. (2010) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2009.11.024 · Cited by 364
An Efficient CeO2/CoSe2Nanobelt Composite for Electrochemical Water Oxidation
Zheng, Y.-R., Gao, M.-R., Gao, Q., Li, H.-H., Xu, J., Wu, Z.-Y., & Yu, S.-H. (2015) · Small · doi:10.1002/smll.201401423 · Cited by 360
Steinmiller, E. M. P., & Choi, K.-S. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0910203106 · Cited by 352
The Nature of Lithium Battery Materials under Oxygen Evolution Reaction Conditions
Lee, S. W., Carlton, C., Risch, M., Surendranath, Y., Chen, S., Furutsuki, S., Yamada, A., Nocera, D. G., & Shao-Horn, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307814j · Cited by 316
Nakagawa, T., Beasley, C. A., & Murray, R. W. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9060076 · Cited by 315
Park, J., Koo, B., Yoon, K. Y., Hwang, Y., Kang, M., Park, J.-G., & Hyeon, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0427496 · Cited by 307
Cobalt−Oxo Core of a Water-Oxidizing Catalyst Film
Risch, M., Khare, V., Zaharieva, I., Gerencser, L., Chernev, P., & Dau, H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja902121f · Cited by 281
Hara, M., Waraksa, C. C., Lean, J. T., Lewis, B. A., & Mallouk, T. E. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp000321x · Cited by 277
He, Q., Li, Q., Khene, S., Ren, X., López-Suárez, F. E., Lozano-Castelló, D., Bueno-López, A., & Wu, G. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp401814f · Cited by 262
Du, G., Liu, X., Zong, Y., Hor, T. S. A., Yu, A., & Liu, Z. (2013) · Nanoscale · doi:10.1039/c3nr00300k · Cited by 250
Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode
Ahn, H. S., & Tilley, T. D. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201200920 · Cited by 249
Oxygen evolution reaction on Ni-substituted Co3O4 nanowire array electrodes
Lu, B., Cao, D., Wang, P., Wang, G., & Gao, Y. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.09.056 · Cited by 244
Comparison of Cobalt‐based Nanoparticles as Electrocatalysts for Water Oxidation
Chou, N. H., Ross, P. N., Bell, A. T., & Tilley, T. D. (2011) · ChemSusChem · doi:10.1002/cssc.201100075 · Cited by 228
Synthesis of Cobalt Phosphides and Their Application as Anodes for Lithium Ion Batteries
Yang, D., Zhu, J., Rui, X., Tan, H., Cai, R., Hoster, H. E., Yu, D. Y. W., Hng, H. H., & Yan, Q. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am302877q · Cited by 185
ABU, I., & SMITH, K. (2006) · Journal of Catalysis · doi:10.1016/j.jcat.2006.05.010 · Cited by 175
Electrode-assisted catalytic water oxidation by a flavin derivative
Mirzakulova, E., Khatmullin, R., Walpita, J., Corrigan, T., Vargas-Barbosa, N. M., Vyas, S., Oottikkal, S., Manzer, S. F., Hadad, C. M., & Glusac, K. D. (2012) · Nature Chemistry · doi:10.1038/nchem.1439 · Cited by 169
Ha, D.-H., Moreau, L. M., Bealing, C. R., Zhang, H., Hennig, R. G., & Robinson, R. D. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10337g · Cited by 164
Morris, N. D., Suzuki, M., & Mallouk, T. E. (2004) · The Journal of Physical Chemistry A · doi:10.1021/jp0480145 · Cited by 148
Symes, M. D., Surendranath, Y., Lutterman, D. A., & Nocera, D. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja110908v · Cited by 138
Zhang, H., Ha, D., Hovden, R., Kourkoutis, L. F., & Robinson, R. D. (2010) · Nano Letters · doi:10.1021/nl103400a · Cited by 131
Phosphorus promotion of Ni (Co)-containing Mo-free catalysts in thiophene hydrodesulfurization
Korányi, T. I. (2003) · Applied Catalysis A General · doi:10.1016/s0926-860x(02)00390-3 · Cited by 123
Atomistic Structure of Cobalt-Phosphate Nanoparticles for Catalytic Water Oxidation
Hu, X. L., Piccinin, S., Laio, A., & Fabris, S. (2012) · ACS Nano · doi:10.1021/nn3044325 · Cited by 67
Rotole, J. A., & Sherwood, P. M. A. (2001) · Chemistry of Materials · doi:10.1021/cm0009468 · Cited by 54
Siconolfi, D. J., & Frankenthal, R. P. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2097436 · Cited by 24
Kim, H., Chae, Y., Lee, D. H., Kim, M., Huh, J., Kim, Y., Kim, H., Kim, H. J., Kim, S. O., Baik, H., et al. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001822 · Cited by 17
Self-citation
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting
Liang, H., Gandi, A. N., Anjum, D. H., Wang, X., Schwingenschlögl, U., & Alshareef, H. N. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03803 · Cited by 1,237
Metadata
- Authors
- Ryu, J., Jung, N., Jang, J. H., Kim, H.-J., & Yoo, S. J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-05
- Volume
- 5
- Issue
- 7
- Pages
- 4066-4074
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2299572817
- Cited by
- 455
- References
- 74
- FWCI
- 17.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.