The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Mechanistic Insights into the Electrochemical Reduction of CO2 to CO on Nanostructured Ag Surfaces
Abstract
Electroreduction of CO 2 in a highly selective and efficient manner is a crucial step toward CO 2 utilization. Nanostructured Ag catalysts have been found to be effective candidates for CO 2 to CO conversion. In this report, we combine experimental and computational efforts to explore the electrocatalytic reaction mechanism of CO 2 reduction on nanostructured Ag catalyst surfaces in an aqueous electrolyte. In contrast to bulk Ag catalysts, both nanoparticle and nanoporous Ag catalysts show enhanced ability to reduce the activation energy of the CO 2 to COOH ads intermediate step through the low-coordinated Ag surface atoms, resulting in a reaction mechanism involving a fast first electron and proton transfer followed by a slow second proton transfer as the rate-limiting step.
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Cited by
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Metadata
- Authors
- Rosen, J., Hutchings, G. S., Lu, Q., Rivera, S., Zhou, Y., Vlachos, D. G., & Jiao, F.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-16
- Volume
- 5
- Issue
- 7
- Pages
- 4293-4299
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2227166172
- Cited by
- 606
- References
- 11
- FWCI
- 13.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rosen, J., Hutchings, G. S., Lu, Q., Rivera, S., Zhou, Y., Vlachos, D. G., & Jiao, F. (2015). Mechanistic Insights into the Electrochemical Reduction of CO2 to CO on Nanostructured Ag Surfaces. ACS Catalysis. https://doi.org/10.1021/acscatal.5b00840
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