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Nest-like NiCoP for Highly Efficient Overall Water Splitting
Abstract
The investigation of high-efficiency nonprecious electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of great significance for renewable energy technologies. Here, we provide a successive hydrothermal, oxidation, and phosphidation method to fabricate a 3D nest-like ternary NiCoP/carbon cloth (CC) electrocatalyst with superior catalytic activity and stability toward HER/OER. Nest-like NiCoP/CC requires overpotentials of 44 and 62 mV to reach the current density of 10 mA cm –2 in acidic and alkaline media, respectively, toward HER. For OER, the NiCoP/CC exhibits high active and durable performance with an overpotential of 242 mV at current density of 10 mA cm –2 in alkaline solutions. Furthermore, the practical application of NiCoP/CC as a bifunctional catalyst for overall water splitting reaction yields current densities of 10 and 100 mA cm –2 at 1.52 and 1.77 V, respectively.
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Metadata
- Authors
- Du, C., Yang, L., Yang, F., Cheng, G., & Luo, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-05-17
- Volume
- 7
- Issue
- 6
- Pages
- 4131-4137
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2612587682
- Cited by
- 549
- References
- 43
- FWCI
- 17.51
- Type
- journal article
- Language
- en
- Open access
- closed
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