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Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
Abstract
Mn(I)-PNP pincer catalyzed sequential one-pot homogeneous CO 2 hydrogenation to CH 3 OH by molecular H 2 is demonstrated. The hydrogenation consists of two parts—N-formylation of an amine utilizing CO 2 and H 2, and subsequent formamide reduction to CH 3 OH, regenerating the amine in the process. A reported air-stable and well-defined Mn-PNP pincer complex was found active for the catalysis of both steps. CH 3 OH yields up to 84% and 71% (w.r.t amine) were obtained, when benzylamine and morpholine were used as amines, respectively; and a TON of up to 36 was observed. In our opinion, this study represents an important development in the nascent field of base-metal-catalyzed homogeneous CO 2 hydrogenation to CH 3 OH.
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Metadata
- Authors
- Kar, S., Goeppert, A., Kothandaraman, J., & Prakash, G. K. S.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-23
- Volume
- 7
- Issue
- 9
- Pages
- 6347-6351
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2745408185
- Cited by
- 258
- References
- 41
- FWCI
- 9.27
- Type
- journal article
- Language
- en
- Open access
- closed
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