The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate
Open accessAbstract
Abstract The electrocatalytic CO2 reduction reaction (eCO2RR) has been gaining increasing attention owing to its potential to contribute to sustainability in our society, although enhanced catalytic performance is a prerequisite for its implementation. Herein, Cu electrocatalysts modified with sulfur proved to selectively produce formate via aqueous eCO2RR and thus to unexpectedly prevent the mechanistic fingerprint of Cu (i.e., the CO path). Initially, sulfur-modified copper catalysts (Cu–S) were prepared by the in situ reductive reconstruction of nano CuS precursors, revealing a positive correlation between particle size and selectivity toward formate. Subsequent studies over targeted submicron Cu–S particles with varying sulfur content demonstrated their evolution under reaction conditions, attaining a similar surface state comprising metallic Cu and sulfide phases, irrespective of the initial structure of the materials. In accordance, the initial sulfur content showed only a very limited influence on the catalytic performance, which remained at approximately 80% Faradaic efficiency toward formate at −0.8 V vs RHE, outperforming all cost-effective, earth-abundant, and nontoxic electrocatalysts reported to date for the production of formate via the aqueous eCO2RR.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
Kortlever, R., Shen, J., Schouten, K. J. P., Calle-Vallejo, F., & Koper, M. T. M. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01559 · Cited by 2,175
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,640
Materials for solar fuels and chemicals
Montoya, J. H., Seitz, L. C., Chakthranont, P., Vojvodic, A., Jaramillo, T. F., & Nørskov, J. K. (2017) · Nature Materials · doi:10.1038/nmat4778 · Cited by 1,566
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Recent advances in direct formic acid fuel cells (DFAFC)
Yu, X., & Pickup, P. G. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.03.075 · Cited by 1,108
Feaster, J. T., Shi, C., Cave, E. R., Hatsukade, T., Abram, D. N., Kuhl, K. P., Hahn, C., Nørskov, J. K., & Jaramillo, T. F. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00687 · Cited by 950
Rice, C., Ha, S., Masel, R. I., Waszczuk, P., Wieckowski, A., & Barnard, T. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(02)00271-9 · Cited by 824
Ullmann's encyclopedia of industrial chemistry
(1988) · Choice Reviews Online · doi:10.5860/choice.26-1926 · Cited by 749
Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure
Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00261 · Cited by 676
A Gross‐Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO2
Verma, S., Kim, B., Jhong, H. “., Ma, S., & Kenis, P. J. A. (2016) · ChemSusChem · doi:10.1002/cssc.201600394 · Cited by 655
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
Reda, T., Plugge, C. M., Abram, N. J., & Hirst, J. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0801290105 · Cited by 561
Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541
Rasul, S., Anjum, D. H., Jedidi, A., Minenkov, Y., Cavallo, L., & Takanabe, K. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410233 · Cited by 510
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO2 to CO
Sarfraz, S., Garcia-Esparza, A. T., Jedidi, A., Cavallo, L., & Takanabe, K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00269 · Cited by 459
Kortlever, R., Peters, I., Koper, S., & Koper, M. T. M. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00602 · Cited by 447
Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443
Martín, A. J., Larrazábal, G. O., & Pérez-Ramírez, J. (2015) · Green Chemistry · doi:10.1039/c5gc01893e · Cited by 359
Self-citationHori, Y., Murata, A., Takahashi, R., & Suzuki, S. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00250a044 · Cited by 354
Modern Aspects of Electrochemistry
(2008) · Modern Aspects of Electrochemistry · doi:10.1007/978-0-387-49489-0 · Cited by 225
Life cycle assessment of CO 2 -based C1-chemicals
Sternberg, A., Jens, C. M., & Bardow, A. (2017) · Green Chemistry · doi:10.1039/c6gc02852g · Cited by 212
Enhanced Reduction of CO2 to CO over Cu–In Electrocatalysts: Catalyst Evolution Is the Key
Larrazábal, G. O., Martín, A. J., Mitchell, S., Hauert, R., & Pérez-Ramírez, J. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02067 · Cited by 210
Self-citationHoffman, Z. B., Gray, T. S., Moraveck, K. B., Gunnoe, T. B., & Zangari, G. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01161 · Cited by 187
Larrazábal, G. O., Martín, A. J., & Pérez-Ramírez, J. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01380 · Cited by 176
Chemistry of formic acid and its simple derivatives
Gibson, H. W. (1969) · Chemical Reviews · doi:10.1021/cr60261a005 · Cited by 154
Lv, W., Zhou, J., Bei, J., Zhang, R., Wang, L., Xu, Q., & Wang, W. (2016) · Applied Surface Science · doi:10.1016/j.apsusc.2016.10.017 · Cited by 136
Huang, Y., Deng, Y., Handoko, A. D., Goh, G. K. L., & Yeo, B. S. (2017) · ChemSusChem · doi:10.1002/cssc.201701314 · Cited by 132
Jedidi, A., Rasul, S., Masih, D., Cavallo, L., & Takanabe, K. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta05669a · Cited by 119
Wu, C., Yu, S., & Antonietti, M. (2006) · Chemistry of Materials · doi:10.1021/cm060956u · Cited by 101
Rahaman, M., Dutta, A., & Broekmann, P. (2017) · ChemSusChem · doi:10.1002/cssc.201601778 · Cited by 95
Cook, R. L., MacDuff, R. C., & Sammells, A. F. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2097110 · Cited by 64
Shin, H., Ha, Y., & Kim, H. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01876 · Cited by 61
Larrazábal, G. O., Martín, A. J., Krumeich, F., Hauert, R., & Pérez‐Ramírez, J. (2016) · ChemSusChem · doi:10.1002/cssc.201601578 · Cited by 59
Self-citation
Cited by
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Zhuang, T.-T., Liang, Z.-Q., Seifitokaldani, A., Li, Y., De Luna, P., Burdyny, T., Che, F., Meng, F., Min, Y., Quintero-Bermudez, R., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0084-7 · Cited by 784
Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf
Martín, A. J., Shinagawa, T., & Pérez-Ramírez, J. (2019) · Chem · doi:10.1016/j.chempr.2018.10.010 · Cited by 608
Self-citationSolvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2
König, M., Vaes, J., Klemm, E., & Pant, D. (2019) · iScience · doi:10.1016/j.isci.2019.07.014 · Cited by 429
Metadata
- Authors
- Shinagawa, T., Larrazábal, G. O., Martín, A. J., Krumeich, F., & Pérez-Ramírez, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-01-02
- Volume
- 8
- Issue
- 2
- Pages
- 837-844
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2771065863
- Cited by
- 304
- References
- 42
- FWCI
- 5.98
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
