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Achieving Fast and Durable Lithium Storage through Amorphous FeP Nanoparticles Encapsulated in Ultrathin 3D P-Doped Porous Carbon Nanosheets
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Conversion-type transition-metal phosphide anode materials with high theoretical capacity usually suffer from low-rate capability and severe capacity decay, which are mainly caused by their inferior electronic conductivities and large volumetric variations together with the poor reversibility of discharge product (Li 3 P), impeding their practical applications. Herein, guided by density functional theory calculations, these obstacles are simultaneously mitigated by confining amorphous FeP nanoparticles into ultrathin 3D interconnected P-doped porous carbon nanosheets (denoted as FeP@CNs) via a facile approach, forming an intriguing 3D flake-CNs-like configuration. As an anode for lithium-ion batteries (LIBs), the resulting FeP@CNs electrode not only reaches a high reversible capacity (837 mA h g –1 after 300 cycles at 0.2 A g –1 ) and an exceptional rate capability (403 mA h g –1 at 16 A g –1 ) but also exhibits extraordinary durability (2500 cycles, 563 mA h g –1 at 4 A g –1, 98% capacity retention). By combining DFT calculations, in situ transmission electron microscopy, and a suite of ex situ microscopic and spectroscopic techniques, we show that the superior performances of FeP@CNs anode originate from its prominent structural and compositional merits, which render fast electron/ion-transport kinetics and abundant active sites (amorphous FeP nanoparticles and structural defects in P-doped CNs) for charge storage, promote the reversibility of conversion reactions, and buffer the volume variations while preventing pulverization/aggregation of FeP during cycling, thus enabling a high rate and highly durable lithium storage. Furthermore, a full cell composed of the prelithiated FeP@CNs anode and commercial LiFePO 4 cathode exhibits impressive rate performance while maintaining superior cycling stability. This work fundamentally and experimentally presents a facile and effective structural engineering strategy for markedly improving the performance of conversion-type anodes for advanced LIBs.
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Cited by
Fast Charging Anode Materials for Lithium‐Ion Batteries: Current Status and Perspectives
Li, S., Wang, K., Zhang, G., Li, S., Xu, Y., Zhang, X., Zhang, X., Zheng, S., Sun, X., & Ma, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202200796 · Cited by 607
Metadata
- Authors
- Zheng, Z., Wu, H.-H., Liu, H., Zhang, Q., He, X., Yu, S., Petrova, V., Feng, J., Kostecki, R., Liu, P., Peng, D.-L., Liu, M., & Wang, M.-S.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-07-13
- Volume
- 14
- Issue
- 8
- Pages
- 9545-9561
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W3040716950
- Cited by
- 334
- References
- 73
- FWCI
- 20.00
- Type
- journal article
- Language
- en
- Open access
- green
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