Thiyl Radicals in Organic Synthesis

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590

Thiol–Ene Click Chemistry

Hoyle, C. E., & Bowman, C. N. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200903924 · Cited by 4,182

Visible light photoredox catalysis: applications in organic synthesis

Narayanam, J. M. R., & Stephenson, C. R. J. (2011) · Chem. Soc. Rev. · doi:10.1039/b913880n · Cited by 4,161

Thioredoxin and Glutaredoxin Systems

Holmgren, A. (1989) · Journal of Biological Chemistry · doi:10.1016/s0021-9258(18)71625-6 · Cited by 1,796

Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis

Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639

Thiol–enes: Chemistry of the past with promise for the future

Hoyle, C. E., Lee, T. Y., & Roper, T. (2004) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20366 · Cited by 1,457

Protein Radicals in Enzyme Catalysis

Stubbe, J., & van der Donk, W. A. (1998) · Chemical Reviews · doi:10.1021/cr9400875 · Cited by 1,377

Cysteine-Mediated Redox Signaling: Chemistry, Biology, and Tools for Discovery

Paulsen, C. E., & Carroll, K. S. (2013) · Chemical Reviews · doi:10.1021/cr300163e · Cited by 1,278

Mechanisms of free radical oxidation of unsaturated lipids

Porter, N. A., Caldwell, S. E., & Mills, K. A. (1995) · Lipids · doi:10.1007/bf02536034 · Cited by 1,208

Radicals in Organic Synthesis

(2001) · Wiley eBooks · doi:10.1002/9783527618293 · Cited by 1,202

Ribonucleotide Reductases

Nordlund, P., & Reichard, P. (2006) · Annual Review of Biochemistry · doi:10.1146/annurev.biochem.75.103004.142443 · Cited by 1,079

Chemistry of Acyl Radicals

Chatgilialoglu, C., Crich, D., Komatsu, M., & Ryu, I. (1999) · Chemical Reviews · doi:10.1021/cr9601425 · Cited by 898

The power of thiol‐ene chemistry

Kade, M. J., Burke, D. J., & Hawker, C. J. (2010) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.23824 · Cited by 853

Radical Initiation in the Class I Ribonucleotide Reductase: Long-Range Proton-Coupled Electron Transfer?

Stubbe, J., Nocera, D. G., Yee, C. S., & Chang, M. C. Y. (2003) · Chemical Reviews · doi:10.1021/cr020421u · Cited by 823

Robust, Efficient, and Orthogonal Synthesis of Dendrimers via Thiol-ene “Click” Chemistry

Killops, K. L., Campos, L. M., & Hawker, C. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8006325 · Cited by 792

Photoinduced Plasticity in Cross-Linked Polymers

Scott, T. F., Schneider, A. D., Cook, W. D., & Bowman, C. N. (2005) · Science · doi:10.1126/science.1110505 · Cited by 776

The Magnitude of the Primary Kinetic Isotope Effect for Compounds of Hydrogen and Deuterium.

Westheimer, F. H. (1961) · Chemical Reviews · doi:10.1021/cr60211a004 · Cited by 775

Handbook of bond dissociation energies in organic compounds

(2003) · Choice Reviews Online · doi:10.5860/choice.40-5818 · Cited by 732

Oxidation and Antioxidants in Organic Chemistry and Biology

Denisov, E. T., & Afanas'ev, I. B. (2005) · CRC Press eBooks · doi:10.1201/9781420030853 · Cited by 708

Radiation curing in polymer science and technology

Fouassier, J., & Rabek, J. F. (1993) · Elsevier eBooks · Cited by 700

RIBONUCLEOTIDE REDUCTASES

Jordan, A., & Reichard, P. (1998) · Annual Review of Biochemistry · doi:10.1146/annurev.biochem.67.1.71 · Cited by 670

Solvent Effects on the Rates and Mechanisms of Reaction of Phenols with Free Radicals

Litwinienko, G., & Ingold, K. U. (2007) · Accounts of Chemical Research · doi:10.1021/ar0682029 · Cited by 647

The Emergence of Thiol–Ene Coupling as a Click Process for Materials and Bioorganic Chemistry

Dondoni, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200802516 · Cited by 619

Competition Methods and Scales for Alkyl Radical Reaction Kinetics

Newcomb, M. (1993) · Tetrahedron · doi:10.1016/s0040-4020(01)85808-7 · Cited by 614

Structure of ribonucleotide reductase protein R1

Uhlin, U., & Eklund, H. (1994) · Nature · doi:10.1038/370533a0 · Cited by 573

Generation of Superoxide Free Radical during the Autoxidation of Thiols

Misra, H. P. (1974) · Journal of Biological Chemistry · doi:10.1016/s0021-9258(19)42810-x · Cited by 556

Organoboranes as a Source of Radicals

Ollivier, C., & Renaud, P. (2001) · Chemical Reviews · doi:10.1021/cr010001p · Cited by 553

Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis

Lowe, A. B., Hoyle, C. E., & Bowman, C. N. (2010) · Journal of Materials Chemistry · doi:10.1039/b917102a · Cited by 540

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic acids

Barton, D. H. R., Crich, D., & Motherwell, W. B. (1985) · Tetrahedron · doi:10.1016/s0040-4020(01)97173-x · Cited by 537

From RNA to DNA, Why So Many Ribonucleotide Reductases?

Reichard, P. (1993) · Science · doi:10.1126/science.8511586 · Cited by 530

Radical chemistry associated with the thiocarbonyl group

Crich, D., & Quintero, L. (1989) · Chemical Reviews · doi:10.1021/cr00097a001 · Cited by 496

Encyclopedia of Radicals in Chemistry, Biology and Materials

(2012) · Wiley eBooks · doi:10.1002/9781119953678 · Cited by 483

Structure and Function of the Escherichia coli Ribonucleotide Reductase Protein R2

Nordlund, P., & Eklund, H. (1993) · Journal of Molecular Biology · doi:10.1006/jmbi.1993.1374 · Cited by 464

Structure, function, and mechanism of ribonucleotide reductases

Kolberg, M., Strand, K. R., Graff, P., & Andersson, K. K. (2004) · Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics · doi:10.1016/j.bbapap.2004.02.007 · Cited by 437

Free radical scavenging behavior of folic acid: evidence for possible antioxidant activity

Joshi, R., Adhikari, S., Patro, B. S., Chattopadhyay, S., & Mukherjee, T. (2001) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(01)00543-3 · Cited by 432

Ribonucleotide Reductase—a Radical Enzyme

Reichard, P., & Ehrenberg, A. (1983) · Science · doi:10.1126/science.6306767 · Cited by 423

Thiol−Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks

Fairbanks, B. D., Scott, T. F., Kloxin, C. J., Anseth, K. S., & Bowman, C. N. (2009) · Macromolecules · doi:10.1021/ma801903w · Cited by 405

New and improved methods for the radical decarboxylation of acids

Barton, D. H. R., Crich, D., & Motherwell, W. B. (1983) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39830000939 · Cited by 399

Beiträge zur Kenntniss der ungesättigten Verbindungen. II. Ueber die Addition von Mercaptanen an ungesättigte Kohlenwasserstoffe

Posner, T. (1905) · Berichte der deutschen chemischen Gesellschaft · doi:10.1002/cber.190503801106 · Cited by 385

Thiol–Yne Chemistry: A Powerful Tool for Creating Highly Functional Materials

Hoogenboom, R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000401 · Cited by 374

Problems and Possibilities of the Free‐Radical Addition of Thiols to Unsaturated Compounds

Griesbaum, K. (1970) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197002731 · Cited by 357

Free Radical Chain Reactions in Organic Synthesis

(1992) · Elsevier eBooks · doi:10.1016/c2009-0-21557-1 · Cited by 351

Sulfur-Centered Reactive Intermediates in Chemistry and Biology

(1990) · Springer eBooks · doi:10.1007/978-1-4684-5874-9 · Cited by 336

Thiol−Ene Photopolymerization Mechanism and Rate Limiting Step Changes for Various Vinyl Functional Group Chemistries

Cramer, N. B., Reddy, S. K., O'Brien, A. K., & Bowman, C. N. (2003) · Macromolecules · doi:10.1021/ma034667s · Cited by 327

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

Ueng, S.-H., Solovyev, A., Yuan, X., Geib, S. J., Fensterbank, L., Lacôte, E., Malacria, M., Newcomb, M., Walton, J. C., & Curran, D. P. (2009) · Journal of the American Chemical Society · doi:10.1021/ja904103x · Cited by 322

Thiyl Radicals in Ribonucleotide Reductases

Licht, S., Gerfen, G. J., & Stubbe, J. (1996) · Science · doi:10.1126/science.271.5248.477 · Cited by 317

Unified mechanism for polyunsaturated fatty acid autoxidation. Competition of peroxy radical hydrogen atom abstraction, .beta.-scission, and cyclization

Porter, N. A., Lehman, L. S., Weber, B. A., & Smith, K. J. (1981) · Journal of the American Chemical Society · doi:10.1021/ja00411a032 · Cited by 313

Hyperbranched Polymers by Thiol−Yne Chemistry: From Small Molecules to Functional Polymers

Konkolewicz, D., Gray-Weale, A., & Perrier, S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja908206a · Cited by 298

Recent applications of thiol–ene coupling as a click process for glycoconjugation

Dondoni, A., & Marra, A. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15157f · Cited by 293

One-electron reduction of the disulfide linkage in aqueous solution. Formation, protonation, and decay kinetics of the RSSR- radical

Hoffman, M. Z., & Hayon, E. (1972) · Journal of the American Chemical Society · doi:10.1021/ja00778a002 · Cited by 279

Sequential Phosphine-Catalyzed, Nucleophilic Thiol−Ene/Radical-Mediated Thiol−Yne Reactions and the Facile Orthogonal Synthesis of Polyfunctional Materials

Chan, J. W., Hoyle, C. E., & Lowe, A. B. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8099135 · Cited by 276

Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions

Tyson, E. L., Ament, M. S., & Yoon, T. P. (2013) · The Journal of Organic Chemistry · doi:10.1021/jo3020825 · Cited by 275

Assessment of the Importance of Changes in Ground-State Energies on the Bond Dissociation Enthalpies of the O-H Bonds in Phenols and the S-H Bonds in Thiophenols

Bordwell, F. G., Zhang, X.-M., Satish, A. V., & Cheng, J.-P. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00094a015 · Cited by 272

S-Nitrosothiols: cellular formation and transport

Zhang, Y., & Hogg, N. (2005) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2004.12.016 · Cited by 257

Thiol/ene photocurable polymers

Morgan, C. R., Magnotta, F., & Ketley, A. D. (1977) · Journal of Polymer Science: Polymer Chemistry Edition · doi:10.1002/pol.1977.170150311 · Cited by 256

Thiol Chemistry in Peroxidase Catalysis and Redox Signaling

Bindoli, A., Fukuto, J. M., & Forman, H. J. (2008) · Antioxidants & Redox Signaling · doi:10.1089/ars.2008.2063 · Cited by 244

Thiyl Glycosylation of Olefinic Proteins: S‐Linked Glycoconjugate Synthesis

Floyd, N., Vijayakrishnan, B., Koeppe, J. R., & Davis, B. G. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200903135 · Cited by 235

Terpene-Based Renewable Monomers and Polymers via Thiol–Ene Additions

Firdaus, M., Montero de Espinosa, L., & Meier, M. A. R. (2011) · Macromolecules · doi:10.1021/ma201544e · Cited by 230

Glycopolypeptides with a Redox-Triggered Helix-to-Coil Transition

Kramer, J. R., & Deming, T. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3007484 · Cited by 225

Sequential thiol‐ene/thiol‐ene and thiol‐ene/thiol‐yne reactions as a route to well‐defined mono and bis end‐functionalized poly(N‐isopropylacrylamide)

Yu, B., Chan, J. W., Hoyle, C. E., & Lowe, A. B. (2009) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.23436 · Cited by 218

Thiol–ene Click Reaction as a General Route to Functional Trialkoxysilanes for Surface Coating Applications

Tucker‐Schwartz, A. K., Farrell, R. A., & Garrell, R. L. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202292q · Cited by 215

Ribonucleotide reductases: radical enzymes with suicidal tendencies

Stubbe, J., & van der Donk, W. A. (1995) · Chemistry & Biology · doi:10.1016/1074-5521(95)90084-5 · Cited by 200

Pulse radiolysis study of sulfhydryl compounds in aqueous solution

Hoffman, M. Z., & Hayon, E. (1973) · The Journal of Physical Chemistry · doi:10.1021/j100627a005 · Cited by 198

Adding handles to unhandy substrates: anaerobic hydrocarbon activation mechanisms

Heider, J. (2007) · Current Opinion in Chemical Biology · doi:10.1016/j.cbpa.2007.02.027 · Cited by 197

Self-Terminating, Oxidative Radical Cyclizations: A Novel Reaction of Acyloxyl Radicals

Wille, U. (2002) · Journal of the American Chemical Society · doi:10.1021/ja017006o · Cited by 183

Conformation of Glycosyl Radicals: Radical Stabilization by β‐CO Bonds

Dupuis, J., Giese, B., Rüegge, D., Fischer, H., Korth, H., & Sustmann, R. (1984) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198408961 · Cited by 183

Synthesis and Characterization of Ethylene/Carbon Monoxide Copolymers, A New Class of Polyketones1

Brubaker, M. M., Coffman, D. D., & Hoehn, H. H. (1952) · Journal of the American Chemical Society · doi:10.1021/ja01126a047 · Cited by 183

A novel zwitterionic HILIC stationary phase based on “thiol-ene” click chemistry between cysteine and vinyl silica

Shen, A., Guo, Z., Yu, L., Cao, L., & Liang, X. (2011) · Chemical Communications · doi:10.1039/c1cc10421g · Cited by 167

Reactivity and Reversibility in the Reaction of Thiyl Radicals with Olefins1

Walling, C., & Helmreich, W. (1959) · Journal of the American Chemical Society · doi:10.1021/ja01514a032 · Cited by 167

Stress Relaxation via Addition−Fragmentation Chain Transfer in a Thiol-ene Photopolymerization

Kloxin, C. J., Scott, T. F., & Bowman, C. N. (2009) · Macromolecules · doi:10.1021/ma802771b · Cited by 161

Free radical intermediates in the inhibition of the autoxidation reaction

Lucarini, M., & Pedulli, G. F. (2010) · Chemical Society Reviews · doi:10.1039/b901838g · Cited by 161

Oxidation of polyunsaturated fatty acids and lipids through thiyl and sulfonyl radicals: Reaction kinetics, and influence of oxygen and structure of thiyl radicals

Schöneich, C., Dillinger, U., von Bruchhausen, F., & Asmus, K. (1992) · Archives of Biochemistry and Biophysics · doi:10.1016/0003-9861(92)90016-p · Cited by 154

Preparation of controlled-molecular-weight, olefin-terminated polymers by free radical methods. Chain transfer using allylic sulfides

Meijs, G. F., Rizzardo, E., & Thang, S. H. (1988) · Macromolecules · doi:10.1021/ma00188a039 · Cited by 153

Facile Synthesis of Clickable, Water-Soluble, and Degradable Polyphosphoesters

Zhang, S., Li, A., Zou, J., Lin, L. Y., & Wooley, K. L. (2012) · ACS Macro Letters · doi:10.1021/mz200226m · Cited by 151

Highly Branched and Hyperbranched Glycopolymers via Reversible Addition−Fragmentation Chain Transfer Polymerization and Click Chemistry

Semsarilar, M., Ladmiral, V., & Perrier, S. (2010) · Macromolecules · doi:10.1021/ma902587r · Cited by 149

Site-Specific Insertion of 3-Aminotyrosine into Subunit α2 of E. coli Ribonucleotide Reductase: Direct Evidence for Involvement of Y 730 and Y 731 in Radical Propagation

Seyedsayamdost, M. R., Xie, J., Chan, C. T. Y., Schultz, P. G., & Stubbe, J. (2007) · Journal of the American Chemical Society · doi:10.1021/ja076043y · Cited by 147

Trans Lipids: The Free Radical Path

Chatgilialoglu, C., & Ferreri, C. (2005) · Accounts of Chemical Research · doi:10.1021/ar0400847 · Cited by 145

A New Ligation Strategy for Peptide and Protein Glycosylation: Photoinduced Thiol–Ene Coupling

Dondoni, A., Massi, A., Nanni, P., & Roda, A. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200901746 · Cited by 143

Formation of Deoxycytidine Phosphates from Cytidine Phosphates in Extracts from Escherichia coli

Reichard, P. A., Baldesten, A., & Rutberg, L. (1961) · Journal of Biological Chemistry · doi:10.1016/s0021-9258(18)64258-9 · Cited by 142

Thiol–yne and Thiol–ene “Click” Chemistry as a Tool for a Variety of Platinum Drug Delivery Carriers, from Statistical Copolymers to Crosslinked Micelles

Huynh, V. T., Chen, G., SOUZA, P. D., & Stenzel, M. H. (2011) · Biomacromolecules · doi:10.1021/bm200135e · Cited by 139

Chemistry of β-(Acyloxy)alkyl and β-(Phosphatoxy)alkyl Radicals and Related Species: Radical and Radical Ionic Migrations and Fragmentations of Carbon−Oxygen Bonds

BECKWITH, A. L. J., Crich, D., Duggan, P. J., & Yao, Q. (1997) · Chemical Reviews · doi:10.1021/cr950207o · Cited by 139

The Reaction of Trialkyl Phosphites with Thiyl and Alkoxy Radicals1

Walling, C. T., & Rabinowitz, R. (1959) · Journal of the American Chemical Society · doi:10.1021/ja01514a057 · Cited by 138

Radical Deoxygenation of Xanthates and Related Functional Groups with New Minimalist N-Heterocyclic Carbene Boranes

Ueng, S., Fensterbank, L., Lacôte, E., et al. (2010) · Organic Letters · doi:10.1021/ol101015m · Cited by 134

Synthesis, Thiol−Yne “Click” Photopolymerization, and Physical Properties of Networks Derived from Novel Multifunctional Alkynes

Chan, J. W., Shin, J., Hoyle, C. E., Bowman, C. N., & Lowe, A. B. (2010) · Macromolecules · doi:10.1021/ma1004452 · Cited by 129

Cis−Trans Isomerization of Polyunsaturated Fatty Acid Residues in Phospholipids Catalyzed by Thiyl Radicals

Ferreri, C., Costantino, C., Perrotta, L., Landi, L., Mulazzani, Q. G., & Chatgilialoglu, C. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0040969 · Cited by 128

The Kinetics of Thiyl Radical-Induced Reactions of Monounsaturated Fatty Acid Esters

Chatgilialoglu, C., Altieri, A., & Fischer, H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja027428d · Cited by 123

Regioselective Cis−Trans Isomerization of Arachidonic Double Bonds by Thiyl Radicals: The Influence of Phospholipid Supramolecular Organization

Ferreri, C., Samadi, A., Sassatelli, F., Landi, L., & Chatgilialoglu, C. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038072o · Cited by 123

Absolute Kinetics of Amidyl Radical Reactions

Horner, J. H., Musa, O. M., Bouvier, A., & Newcomb, M. (1998) · Journal of the American Chemical Society · doi:10.1021/ja981244a · Cited by 121

Photoinduced Thiol−Ene Coupling as a Click Ligation Tool for Thiodisaccharide Synthesis

Fiore, M., Marra, A., & Dondoni, A. (2009) · The Journal of Organic Chemistry · doi:10.1021/jo900514w · Cited by 119

Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical

Yoshimi, Y., Itou, T., & Hatanaka, M. (2007) · Chemical Communications · doi:10.1039/b714526h · Cited by 119

Preparation of emulsion-templated porous polymers using thiol–ene and thiol–yne chemistry

Lovelady, E., Kimmins, S. D., Wu, J., & Cameron, N. R. (2010) · Polymer Chemistry · doi:10.1039/c0py00374c · Cited by 117

The use of thiols by ribonucleotide reductase

Holmgren, A., & Sengupta, R. (2010) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2010.09.005 · Cited by 116

Cascade Radical Reactions of Isonitriles: A Second‐Generation Synthesis of (20S)‐Camptothecin, Topotecan, Irinotecan, and GI‐147211C

Curran, D. P., Ko, S., & Josien, H. B. (1996) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199526831 · Cited by 116

Photochemical Microcontact Printing by Thiol−Ene and Thiol−Yne Click Chemistry

Wendeln, C., Rinnen, S., Schulz, C., Arlinghaus, H. F., & Ravoo, B. J. (2010) · Langmuir · doi:10.1021/la102966j · Cited by 114

Thiyl radical attack on polyunsaturated fatty acids: A possible route to lipid peroxidation

Schöneich, C., Asmus, K., Dillinger, U., & von Bruchhausen, F. (1989) · Biochemical and Biophysical Research Communications · doi:10.1016/0006-291x(89)91568-4 · Cited by 113

New Free-Radical Ring-Opening Acrylate Monomers

Evans, R. A., Moad, G., Rizzardo, E., & Thang, S. H. (1994) · Macromolecules · doi:10.1021/ma00104a062 · Cited by 112

cis − trans Isomerization of Monounsaturated Fatty Acid Residues in Phospholipids by Thiyl Radicals

Chatgilialoglu, C., Ferreri, C., Ballestri, M., Mulazzani, Q. G., & Landi, L. (2000) · Journal of the American Chemical Society · doi:10.1021/ja994169s · Cited by 111

Ribonucleotide Reductases: Divergent Evolution of an Ancient Enzyme

Torrents, E., Aloy, P., Gibert, I., & Rodríguez-Trelles, F. (2002) · Journal of Molecular Evolution · doi:10.1007/s00239-002-2311-7 · Cited by 111

Free-Radical ring-opening polymerization of cyclic allylic sulfides

Evans, R. A., & Rizzardo, E. (1996) · Macromolecules · doi:10.1021/ma960573p · Cited by 110

Thiyl radicals react with nitric oxide to form S-nitrosothiols with rate constants near the diffusion-controlled limit

Madej, E., Folkes, L. K., Wardman, P., Czapski, G., & Goldstein, S. (2008) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2008.02.015 · Cited by 110

Radical chain reduction of alkyl halides, dialkyl sulphides and O-alkyl S-methyl dithiocarbonates to alkanes by trialkylsilanes

Cole, S. J., Kirwan, J. N., Roberts, B. P., & Willis, C. R. (1991) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/p19910000103 · Cited by 109

Absolute rate constants for the addition of triethylsilyl radicals to various unsaturated compounds

Chatgilialoglu, C., Ingold, K. U., & Scaiano, J. C. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00348a055 · Cited by 109

Multi-molecule reaction of serum albumin can occur through thiol-yne coupling

Conte, M. L., Staderini, S., Marra, A., Sánchez‐Navarro, M., Davis, B. G., & Dondoni, A. (2011) · Chemical Communications · doi:10.1039/c1cc14402b · Cited by 108

An extended form of the Evans–Polanyi equation: a simple empirical relationship for the prediction of activation energies for hydrogen-atom transfer reactions

Roberts, B. P., & Steel, A. J. (1994) · Journal of the Chemical Society Perkin Transactions 2 · doi:10.1039/p29940002155 · Cited by 106

The use of substituted allylic sulfides to prepare end-functional polymers of controlled molecular weight by free-radical polymerization

Meijs, G. F., Morton, T. C., Rizzardo, E., & Thang, S. H. (1991) · Macromolecules · doi:10.1021/ma00012a033 · Cited by 106

Thiol−Yne Click Polymerization: Regio- and Stereoselective Synthesis of Sulfur-Rich Acetylenic Polymers with Controllable Chain Conformations and Tunable Optical Properties

Liu, J., Lam, J. W. Y., Jim, C. K. W., Ng, J. C. Y., Shi, J., Su, H., Yeung, K. F., Hong, Y., Mahtab, F., Yu, Y., et al. (2010) · Macromolecules · doi:10.1021/ma1023473 · Cited by 106

The formation of cyclic peroxides from unsaturated hydroperoxides: models for prostaglandin biosynthesis

Porter, N. A., Funk, M. O., Gilmore, D., Isaac, R., & Nixon, J. (1976) · Journal of the American Chemical Society · doi:10.1021/ja00435a037 · Cited by 105

Photoinduced Addition of Glycosyl Thiols to Alkynyl Peptides: Use of Free-Radical Thiol−Yne Coupling for Post-Translational Double-Glycosylation of Peptides

Conte, M. L., Pacifico, S., Chambery, A., Marra, A., & Dondoni, A. (2010) · The Journal of Organic Chemistry · doi:10.1021/jo1008178 · Cited by 103

trans Lipids: The Free Radical Path

Chatgilialoglu, C., & Ferreri, C. (2005) · ChemInform · doi:10.1002/chin.200540246 · Cited by 103

Correspondence

(1938) · Journal of the Society of Chemical Industry · doi:10.1002/jctb.5000573206 · Cited by 103

Electron spin resonance and pulse radiolysis studies on the spin trapping of sulphur-centered radicals

Davies, M. J., Forni, L. G., & Shuter, S. L. (1987) · Chemico-Biological Interactions · doi:10.1016/0009-2797(87)90038-x · Cited by 102

Hyperbranched alternating block copolymers using thiol–yne chemistry: materials with tuneable properties

Konkolewicz, D., Poon, C. K., Gray-Weale, A. A., & Perrier, S. (2010) · Chemical Communications · doi:10.1039/c0cc02429e · Cited by 102

On-resin peptide macrocyclization using thiol–ene click chemistry

Aimetti, A. A., Shoemaker, R. L., Lin, C., & Anseth, K. S. (2010) · Chemical Communications · doi:10.1039/c001375g · Cited by 100

Synthesis of Shape Amphiphiles Based on Functional Polyhedral Oligomeric Silsesquioxane End-Capped Poly( l -Lactide) with Diverse Head Surface Chemistry

Zhang, W., Li, Y., Li, X., Dong, X., Yu, X., Wang, C., Wesdemiotis, C., Quirk, R. P., & Cheng, S. Z. D. (2011) · Macromolecules · doi:10.1021/ma200268u · Cited by 100

The evolution of ribonucleotide reduction

Reichard, P. A. (1997) · Trends in Biochemical Sciences · doi:10.1016/s0968-0004(97)01003-7 · Cited by 97

Pulse Radiolysis of 2-Mercaptoethanol in Oxygenated Aqueous Solution. Generation and Reactions of the Thiylperoxyl Radical

Zhang, X., Zhang, N., Schuchmann, H., & von Sonntag, C. (1994) · The Journal of Physical Chemistry · doi:10.1021/j100077a020 · Cited by 97

Preparation and sorption properties of a ?-cyclodextrin-linked chitosan derivative

Martel, B., Devassine, M., Crini, G., Weltrowski, M., Bourdonneau, M., & Morcellet, M. (2000) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/1099-0518(20010101)39:1<145::aid-pola160>3.0.co;2-t · Cited by 96

Mechanisms of Protein Damage Induced by Cysteine Thiyl Radical Formation

Schöneich, C. (2008) · Chemical Research in Toxicology · doi:10.1021/tx800005u · Cited by 93

Thiyl Radicals Abstract Hydrogen Atoms from the αC−H Bonds in Model Peptides: Absolute Rate Constants and Effect of Amino Acid Structure

Nauser, T., & Schöneich, C. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0293599 · Cited by 92

Synthesis of Cyclodextrin-Based Carbohydrate Clusters by Photoaddition Reactions

Fulton, D. A., & Stoddart, J. F. (2001) · The Journal of Organic Chemistry · doi:10.1021/jo010705z · Cited by 91

Polymeric Nanoparticles with Encapsulated Superparamagnetic Iron Oxide and Conjugated Cisplatin for Potential Bladder Cancer Therapy

Huang, C., Neoh, K. G., Xu, L., Kang, E. T., & Chiong, E. (2012) · Biomacromolecules · doi:10.1021/bm300739w · Cited by 91

Reactivity of Substituted Phenols Toward Alkyl Radicals

Franchi, P., Lucarini, M., Pedulli, G. F., et al. (1999) · Journal of the American Chemical Society · doi:10.1021/ja982405d · Cited by 90

Estimated Rate Constants for Hydrogen Abstraction from N-Heterocyclic Carbene−Borane Complexes by an Alkyl Radical

Solovyev, A. Y., Ueng, S., Monot, J., et al. (2010) · Organic Letters · doi:10.1021/ol101014q · Cited by 88

Thiyl Radical Reaction with Amino Acid Side Chains: Rate Constants for Hydrogen Transfer and Relevance for Posttranslational Protein Modification

Nauser, T., Pelling, J. C., & Schöneich, C. (2004) · Chemical Research in Toxicology · doi:10.1021/tx049856y · Cited by 87

Stress Relaxation by Addition−Fragmentation Chain Transfer in Highly Cross-Linked Thiol−Yne Networks

Park, H., Kloxin, C. J., Scott, T. F., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma1020209 · Cited by 83

Synthesis of multifunctional polymer brush surfaces via sequential and orthogonal thiol-click reactions

Rahane, S. B., Hensarling, R. M., Sparks, B. J., Stafford, C. M., & Patton, D. L. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm14762e · Cited by 82

An Efficient Synthesis of Cyclodextrin-Based Carbohydrate Cluster Compounds

Fulton, D. A., & Stoddart, J. F. (2000) · Organic Letters · doi:10.1021/ol005668x · Cited by 81

Rapid Assembly of a Library of Lipophilic Iminosugars via the Thiol–Ene Reaction Yields Promising Pharmacological Chaperones for the Treatment of Gaucher Disease

Goddard‐Borger, E. D., Tropak, M. B., Yonekawa, S., Tysoe, C., Mahuran, D. J., & Withers, S. G. (2012) · Journal of Medicinal Chemistry · doi:10.1021/jm201633y · Cited by 80

Trapping of radical intermediates in the photoreduction of benzophenone

Leaver, I. H., & Ramsay, G. C. (1969) · Tetrahedron · doi:10.1016/s0040-4020(01)83073-8 · Cited by 79

Trans lipid formation induced by thiols in human monocytic leukemia cells

Ferreri, C., Kratzsch, S., Brede, O., Marciniak, B., & Chatgilialoglu, C. (2005) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2004.12.026 · Cited by 78

Site-specific immobilisation of gold nanoparticles on a porous monolith surface by using a thiol–yne click photopatterning approach

Guerrouache, M., Mahouche‐Chergui, S., Chehimi, M. M., & Carbonnier, B. (2012) · Chemical Communications · doi:10.1039/c2cc33134a · Cited by 78

On the Reaction of Molecular Oxygen with Thiyl Radicals: A Re-examination

Mönig, J., Asmus, K., Forni, L. G., & WILLSON, R. L. (1987) · International Journal of Radiation Biology and Related Studies in Physics Chemistry and Medicine · doi:10.1080/09553008714552081 · Cited by 78

A Short Synthesis and Biological Evaluation of Potent and Nontoxic Antimalarial Bridged Bicyclic β-Sulfonyl-Endoperoxides

Bachi, M. D., Korshin, E. E., Hoos, R., Szpilman, A. M., Ploypradith, P., Xie, S., Shapiro, T. A., & Posner, G. H. (2003) · Journal of Medicinal Chemistry · doi:10.1021/jm020584a · Cited by 77

Poly(vinylidene fluoride) Graft Copolymer Membranes with “Clickable” Surfaces and Their Functionalization

Cai, T., Neoh, K. G., & Kang, E. T. (2011) · Macromolecules · doi:10.1021/ma2002728 · Cited by 75

Reactions under the Click Chemistry Philosophy Employed in Supramolecular and Mechanostereochemical Systems

Fahrenbach, A. C., & Stoddart, J. F. (2011) · Chemistry - An Asian Journal · doi:10.1002/asia.201100457 · Cited by 74

Enantioselective Total Synthesis of (−)-α-Kainic Acid through Free Radical Cyclization of an Alkenyl Monothioformimide

Bachi, M. D., & Melman, A. (1997) · The Journal of Organic Chemistry · doi:10.1021/jo962100m · Cited by 73

Reversible Intramolecular Hydrogen Transfer between Cysteine Thiyl Radicals and Glycine and Alanine in Model Peptides: Absolute Rate Constants Derived from Pulse Radiolysis and Laser Flash Photolysis

Nauser, T., Casi, G., Koppenol, W. H., & Schöneich, C. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp805133u · Cited by 72

Reactive Polymer Coatings: A General Route to Thiol‐ene and Thiol‐yne Click Reactions

Wu, J., Huang, C., Liang, W., Wu, Y., Yu, J., & Chen, H. (2012) · Macromolecular Rapid Communications · doi:10.1002/marc.201200011 · Cited by 71

Absolute Rate Constants for Iminyl Radical Reactions

Tadic-Biadatti, M.-H. L., Callier‐Dublanchet, A., Horner, J. H., Quiclet‐Sire, B., Zard, S. Z., & Newcomb, M. (1997) · The Journal of Organic Chemistry · doi:10.1021/jo961530+ · Cited by 71

Thiol−Ene Photopolymerization Kinetics of Vinyl Acrylate/Multifunctional Thiol Mixtures

Lee, T. Y., Roper, T. M., Jonsson, E. S., et al. (2004) · Macromolecules · doi:10.1021/ma035728p · Cited by 70

Sequential click synthesis of hyperbranched polymers via the A2 + CB2 approach

Han, J., Zhao, B., Gao, Y., Tang, A., & Gao, C. (2011) · Polymer Chemistry · doi:10.1039/c1py00235j · Cited by 70

Arachidonate geometrical isomers generated by thiyl radicals: the relationship with trans lipids detected in biological samples

Ferreri, C., Mennella, M. R. F., Formisano, C., et al. (2002) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(02)01083-3 · Cited by 67

New decarboxylative chalcogenation of aliphatic and alicyclic carboxylic acids.

BARTON, D. H. R., Bridon, D. P., & Zard, S. Z. (1984) · Tetrahedron Letters · doi:10.1016/s0040-4039(01)81684-1 · Cited by 67

S-(1-Oxido-2-pyridinyl)-1,1,3,3-tetramethylthiouronium Hexafluorophosphate. A New Reagent for Preparing Hindered Barton Esters

Garner, P., Anderson, J. T., Dey, S., Youngs, W. J., & Galat, K. J. (1998) · The Journal of Organic Chemistry · doi:10.1021/jo980870n · Cited by 66

Racemization-Free Synthesis of S-Alkylated Cysteines via Thiol-ene Reaction

Triola, G., Brunsveld, L., & Waldmann, H. (2008) · The Journal of Organic Chemistry · doi:10.1021/jo800198s · Cited by 66

Total Syntheses of Yingzhaosu A and of Its C(14)-Epimer Including the First Evaluation of Their Antimalarial and Cytotoxic Activities

Szpilman, A. M., Korshin, E. E., Rozenberg, H., et al. (2005) · The Journal of Organic Chemistry · doi:10.1021/jo050074z · Cited by 66

Glycoside and peptide clustering around the octasilsesquioxane scaffold via photoinduced free-radical thiol–ene coupling. The observation of a striking glycoside cluster effect

Conte, M. L., Staderini, S., Chambery, A., Berthet, N., Dumy, P., Renaudet, O., Marra, A., & Dondoni, A. (2012) · Organic & Biomolecular Chemistry · doi:10.1039/c2ob07078b · Cited by 64

Polar Effects Control Hydrogen-Abstraction Reactions of Charged, Substituted Phenyl Radicals

Heidbrink, J. L., Ramírez-Arizmendi, L. E., Thoen, K. K., Guler, L., & Kenttämaa, H. I. (2001) · The Journal of Physical Chemistry A · doi:10.1021/jp0103676 · Cited by 62

Reaction Kinetics and Reduced Shrinkage Stress of Thiol–Yne–Methacrylate and Thiol–Yne–Acrylate Ternary Systems

Ye, S., Cramer, N. B., Smith, I. R., Voigt, K. R., & Bowman, C. N. (2011) · Macromolecules · doi:10.1021/ma2018809 · Cited by 61

7-Silylcamptothecins (silatecans): A new family of camptothecin antitumor agents

Josien, H. B., Bom, D. C., Curran, D. P., Zheng, Y., & Chou, T. (1997) · Bioorganic & Medicinal Chemistry Letters · doi:10.1016/s0960-894x(97)10181-0 · Cited by 61

Design and Synthesis of Endoperoxide Antimalarial Prodrug Models

O’Neill, P. M., Stocks, P. A., Pugh, M. D., Araújo, N., Korshin, E. E., Bickley, J. F., Ward, S. A., Bray, P. G., Pasini, E. M., Davies, J. D., et al. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200453859 · Cited by 60

Stress Relaxation via Addition–Fragmentation Chain Transfer in High Tg, High Conversion Methacrylate-Based Systems

Park, H., Kloxin, C. J., Abuelyaman, A. S., Oxman, J. D., & Bowman, C. N. (2012) · Macromolecules · doi:10.1021/ma300228z · Cited by 59

Determination of absolute rate constants for the reversible hydrogen-atom transfer between thiyl radicals and alcohols or ethers

Schöneich, C., Asmus, K., & Bonifacic, M. (1995) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9959101923 · Cited by 58

Rate constants and transition‐state geometry of reactions of alkyl, alkoxyl, and peroxyl radicals with thiols

Denisov, E., Chatgilialoglu, C., Shestakov, A., & Denisova, T. G. (2008) · International Journal of Chemical Kinetics · doi:10.1002/kin.20404 · Cited by 58

Thiyl radicals abstract hydrogen atoms from carbohydrates: reactivity and selectivity

Pogocki, D. (2001) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(01)00559-7 · Cited by 57

A novel polymerization approach via thiol‐yne addition

Türünç, O., & Meier, M. A. R. (2012) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.25957 · Cited by 57

Versatile Strategy for the Synthesis of Hyperbranched Poly(ε-caprolactone)s and Polypseudorotaxanes Thereof

Liu, W. X., & Dong, C. (2010) · Macromolecules · doi:10.1021/ma101730m · Cited by 56

Deoxygenation of alcohols by the reactions of their xanthate esters with triethylsilane: An alternative to tributyltin hydride in the Barton-McCombie reaction

Kirwan, J. N., Roberts, B. P., & Willis, C. R. (1990) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)97814-6 · Cited by 56

Direct Observation of a Transient Tyrosine Radical Competent for Initiating Turnover in a Photochemical Ribonucleotide Reductase

Reece, S. Y., Seyedsayamdost, M. R., Stubbe, J., & Nocera, D. G. (2007) · Journal of the American Chemical Society · doi:10.1021/ja074452o · Cited by 55

An efficient synthesis of bridged-bicyclic peroxides structurally related to antimalarial yingzhaosu A based on radical co-oxygenation of thiols and monoterpenes

Korshin, E. E., Hoos, R., Szpilman, A. M., Konstantinovski, L., Posner, G. H., & Bachi, M. D. (2002) · Tetrahedron · doi:10.1016/s0040-4020(02)00126-6 · Cited by 55

Electron spin resonance investigation of the structure and formation of sulfinyl radicals: reaction of peroxyl radicals with thiols

Swarts, S. G., Becker, D. A., DeBolt, S., & Sevilla, M. D. (1989) · The Journal of Physical Chemistry · doi:10.1021/j100338a034 · Cited by 54

Synthesis of cyclic, multivalent Arg-Gly-Asp using sequential thiol–ene/thiol–yne photoreactions

Aimetti, A. A., Feaver, K. R., & Anseth, K. S. (2010) · Chemical Communications · doi:10.1039/c0cc01292k · Cited by 54

Facile functionalization of polypeptides by thiol-yne photochemistry for biomimetic materials synthesis

Huang, Y., Zeng, Y., Yang, J., Zeng, Z., Zhu, F., & Chen, X. (2011) · Chemical Communications · doi:10.1039/c1cc12177d · Cited by 53

Preparation of stimuli responsive polycaprolactone membranes of controllable porous morphology via combined atom transfer radical polymerization, ring-opening polymerization and thiol–yne click chemistry

Cai, T., Li, M., Neoh, K. G., & Kang, E. T. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33419d · Cited by 53

Geometrical isomerism of monounsaturated fatty acids: thiyl radical catalysis and influence of antioxidant vitamins

Chatgilialoglu, C., Zambonin, L., Altieri, A., Ferreri, C., Mulazzani, Q. G., & Landi, L. (2002) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(02)01143-7 · Cited by 53

Tetrahydrofuran synthesis via free radical mediated addition of functionalized alkenes to aryl vinyl oxiranes

Feldman, K. S., & Fisher, T. E. (1989) · Tetrahedron · doi:10.1016/s0040-4020(01)80124-1 · Cited by 53

Fast and scalable production of hyperbranched polythioether-ynes by a combination of thiol-halogen click-like coupling and thiol-yne click polymerization

Han, J., Zhao, B., Tang, A., Gao, Y., & Gao, C. (2011) · Polymer Chemistry · doi:10.1039/c1py00367d · Cited by 52

Bioreducible micelles and hydrogels with tunable properties from multi-armed biodegradable copolymers

Sun, L., Liu, W. X., & Dong, C. (2011) · Chemical Communications · doi:10.1039/c1cc14663g · Cited by 51

Initiation of Radical Chain Reactions of Thiol Compounds and Alkenes without any Added Initiator: Thiol‐Catalyzed cis/trans Isomerization of Methyl Oleate

Biermann, U., Butte, W., Koch, R., Fokou, P. A., Türünç, O., Meier, M. A. R., & Metzger, J. O. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201103252 · Cited by 51

Thiol–yne ‘click’ chemistry as a route to functional lipid mimetics

Naik, S. S., Chan, J. W., Comer, C., Hoyle, C. E., & Savin, D. A. (2010) · Polymer Chemistry · doi:10.1039/c0py00231c · Cited by 51

Surface glycosylation of polymer membrane by thiol-yne click chemistry for affinity adsorption of lectin

Wang, C., Ren, P., Huang, X., Wu, J., & Xu, Z. (2011) · Chemical Communications · doi:10.1039/c1cc10634a · Cited by 50

Reversible Hydrogen Transfer Reactions in Thiyl Radicals From Cysteine and Related Molecules: Absolute Kinetics and Equilibrium Constants Determined by Pulse Radiolysis

Nauser, T., Koppenol, W. H., & Schöneich, C. (2012) · The Journal of Physical Chemistry B · doi:10.1021/jp210954v · Cited by 49

Radical generation from polymolecular reactions of closed shell molecules. Molecule-assisted homolysis (MAH). Hydrogen atom transfer from a Diels-Alder adduct to an alkene

Pryor, W. A., Coco, J. H., Daly, W. H., et al. (1974) · Journal of the American Chemical Society · doi:10.1021/ja00824a058 · Cited by 48

Characterization of a Substrate-Derived Radical Detected during the Inactivation of Ribonucleotide Reductase fromEscherichia coliby 2‘-Fluoromethylene-2‘-deoxycytidine 5‘-Diphosphate

Gerfen, G. J., van der Donk, W. A., Yu, G., McCarthy, J. R., Jarvi, E. T., Matthews, D. P., Farrar, C. T., Griffin, R. G., & Stubbe, J. (1998) · Journal of the American Chemical Society · doi:10.1021/ja972166e · Cited by 47

1,2-Migrations in alkyl radicals

Lewis, S. N., Miller, J. J., & Winstein, S. (1972) · The Journal of Organic Chemistry · doi:10.1021/jo00975a003 · Cited by 47

Hexadecenoic Fatty Acid Isomers: A Chemical Biology Approach for Human Plasma Biomarker Development

Sansone, A., Melchiorre, M., Chatgilialoglu, C., & Ferreri, C. (2013) · Chemical Research in Toxicology · doi:10.1021/tx400287u · Cited by 47

Electron Relay in Proteins

Bollinger, M. J. (2008) · Science · doi:10.1126/science.1160001 · Cited by 46

Synthesis and in vitro antimalarial activity of sulfone endoperoxides

Bachi, M. D., Korshin, E. E., Ploypradith, P., Cumming, J. N., Xie, S., Shapiro, T. A., & Posner, G. H. (1998) · Bioorganic & Medicinal Chemistry Letters · doi:10.1016/s0960-894x(98)00141-3 · Cited by 46

Reversible Reactions of Thiols and Thiyl Radicals with Nitrone Spin Traps

Potapenko, D. I., Bagryanskaya, E. G., Tsentalovich, Y. P., et al. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp049026t · Cited by 44

A practical decarboxylative hydroxylation of carboxylic acids

Barton, D. H. R., GÉRO, S. D., Holliday, P., Quiclet‐Sire, B., & Zard, S. Z. (1998) · Tetrahedron · doi:10.1016/s0040-4020(98)00337-8 · Cited by 43

Thiophenol-Mediated 1,5-Hydrogen Transfer for the Preparation of Pyrrolizidines, Indolizidines, and Related Compounds

Dénès, F., Beaufils, F., & Renaud, P. (2007) · Organic Letters · doi:10.1021/ol702017t · Cited by 42

Diastereoselective free-radical reactions. Part 1. Preparation of 2-deoxy-β-glycosides by synthesis and reductive decarboxylation of 3-deoxyulosonic acid glycosides

Crich, D., & Ritchie, T. J. (1990) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/p19900000945 · Cited by 42

Thermal reactions of thiyl radicals

Voronkov, M. G., & Deryagina, E. N. (1990) · Russian Chemical Reviews · doi:10.1070/rc1990v059n08abeh003554 · Cited by 41

Synthesis of S-glycosyl amino acids and S-glycopeptides via photoinduced click thiol–ene coupling

Fiore, M., Lo Conte, M., Pacifico, S., Marra, A., & Dondoni, A. (2011) · Tetrahedron Letters · doi:10.1016/j.tetlet.2010.11.097 · Cited by 38

Sequential diastereoselective free radical reactions: Synthesis of an advanced olivomycin A C–D disaccharide

Crich, D., & Hermann, F. (1993) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)79162-3 · Cited by 37

Novel dental restorative materials having low polymerization shrinkage stress via stress relaxation by addition-fragmentation chain transfer

Park, H., Kloxin, C. J., Abuelyaman, A. S., Oxman, J. D., & Bowman, C. N. (2012) · Dental Materials · doi:10.1016/j.dental.2012.06.012 · Cited by 37

Oxirane CC bond homolysis

Stogryn, E. L., & Gianni, M. H. (1970) · Tetrahedron Letters · doi:10.1016/s0040-4039(01)98403-5 · Cited by 36

Kinetic study for spin-trapping reactions of thiyl radicals with nitroso compounds

Ito, O., & Matsuda, M. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00345a044 · Cited by 36

Reversible Hydrogen Transfer between Cysteine Thiyl Radical and Glycine and Alanine in Model Peptides: Covalent H/D Exchange, Radical−Radical Reactions, and l - to d -Ala Conversion

Mozziconacci, O., Kerwin, B. A., & Schöneich, C. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp101508b · Cited by 35

H-atom abstraction by thiyl radicals from peptides and cyclic dipeptides. A theoretical study of reaction rates

Reid, D. L., Armstrong, D. A., Rauk, A., et al. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b307031j · Cited by 35

Synthesis of 2-deoxy-β-C-pyranosides by diastereoselective hydrogen atom transfer

Crich, D., & Lim, L. B. L. (1990) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)98814-2 · Cited by 35

Evaluation of the “radical sink” hypothesis from a chemical-kinetic viewpoint

Wardman, P. (1998) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/bf02383706 · Cited by 34

On the Polymerization Behavior of Telomers: Metathesis versus Thiol–Ene Chemistry

Mutlu, H., Parvulescu, A., Bruijnincx, P. C. A., Weckhuysen, B. M., & Meier, M. A. R. (2012) · Macromolecules · doi:10.1021/ma2026572 · Cited by 34

Formal Synthesis of (+)-Brefeldin A: Application of a Zinc-Mediated Ring Expansion Reaction

Lin, W., & Zercher, C. K. (2007) · The Journal of Organic Chemistry · doi:10.1021/jo0701379 · Cited by 34

Embedding multiple site‐specific functionalities into polymer chains via nitrone‐mediated radical coupling reactions

Wong, E. H. H., Stenzel, M. H., Junkers, T., et al. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24639 · Cited by 33

Synthesis of the C16−C35 Fragment of Integramycin Using Olefin Hydroesterification as a Linchpin Reaction

Wang, L., & Floreancig, P. E. (2004) · Organic Letters · doi:10.1021/ol036339i · Cited by 33

A New Supported Reagent for the Photochemical Generation of Radicals in Solution

Luca, L. D., Giacomelli, G., Porcu, G., et al. (2001) · Organic Letters · doi:10.1021/ol007032b · Cited by 32

E.S.R. of nitroxide radicals. I. Photolysis of indoles, phenols, disulphides, and thiols

Leaver, I., Ramsay, G. C., & Suzuki, E. (1969) · Australian Journal of Chemistry · doi:10.1071/ch9691891 · Cited by 31

Toward the continuous-flow synthesis of chiral tertiary alcohols by enantioselective addition of organozinc reagents to ketones using nanosize isoborneol ligands

Forrat, V. J., Ramón, D. J., & Yus, M. (2008) · Tetrahedron Asymmetry · doi:10.1016/j.tetasy.2008.02.002 · Cited by 29

Synthesis and reactions of antimalarial bicyclic peroxides

Bachi, M. D., Korshin, E. E., Hoos, R., & Szpilman, A. M. (2000) · Journal of Heterocyclic Chemistry · doi:10.1002/jhet.5570370321 · Cited by 29

Native Chemical Ligation and Extended Methods: Mechanisms, Catalysis, Scope, and Limitations

Agouridas, V., El Mahdi, O., Diemer, V., Cargoët, M., Monbaliu, J.-C. M., & Melnyk, O. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00712 · Cited by 650

Photocatalytic Late-Stage C–H Functionalization

Bellotti, P., Huang, H.-M., Faber, T., & Glorius, F. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00478 · Cited by 623

Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

Matsui, J. K., Lang, S. B., Heitz, D. R., & Molander, G. A. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00094 · Cited by 592

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

Heitz, D. R., Tellis, J. C., & Molander, G. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04789 · Cited by 518

Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis

Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518