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MoS2 Nanosheets: A Designed Structure with High Active Site Density for the Hydrogen Evolution Reaction
Abstract
Two-dimensional MoS 2 nanosheets (NSs) with high active site density were designed for the hydrogen evolution reaction (HER) through a microdomain reaction method. The effect of the annealing temperature on the microstructure and the HER performance of MoS 2 NSs was examined, and a plausible relation between the stack structures of the MoS 2 catalysts and their HER performance was also explored. The MoS 2 NS electrocatalyst obtained at 550 °C reveals the best HER performance with a relatively small Tafel slope of 68 mV/dec. Both the exposed surface area and active site density are very important for providing a large amount of active sites. The present work has been proved to be an efficient route to achieve a high active site density and a relatively large surface area, which might have potential use in photoelectrocatalytic water splitting.
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Cites
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Trends in the exchange current for hydrogen evolution
Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250
Polyhedral and cylindrical structures of tungsten disulphide
Tenne, R., Margulis, L., Genut, M., & Hodes, G. (1992) · Nature · doi:10.1038/360444a0 · Cited by 2,002
Conway, B. E., & Tilak, B. V. (2002) · Electrochimica Acta · doi:10.1016/s0013-4686(02)00329-8 · Cited by 1,789
Laursen, A. B., Kegnæs, S., Dahl, S., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02618j · Cited by 1,348
Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water
Merki, D., Fierro, S., Vrubel, H., & Hu, X. (2011) · Chem. Sci. · doi:10.1039/c1sc00117e · Cited by 1,342
A Molecular MoS 2 Edge Site Mimic for Catalytic Hydrogen Generation
Karunadasa, H. I., Montalvo, E., Sun, Y., Majda, M., Long, J. R., & Chang, C. J. (2012) · Science · doi:10.1126/science.1215868 · Cited by 1,215
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
Benck, J. D., Chen, Z., Kuritzky, L. Y., Forman, A. J., & Jaramillo, T. F. (2012) · ACS Catalysis · doi:10.1021/cs300451q · Cited by 1,091
Merki, D., Vrubel, H., Rovelli, L., Fierro, S., & Hu, X. (2012) · Chemical Science · doi:10.1039/c2sc20539d · Cited by 941
Hydrogen evolution on nano-particulate transition metal sulfides
Bonde, J., Moses, P. G., Jaramillo, T. F., Nørskov, J. K., & Chorkendorff, I. (2009) · Faraday Discuss. · doi:10.1039/b803857k · Cited by 805
Structure-Function Relations in Molybdenum Sulfide Catalysts: The "Rim-Edge" Model
Daage, M., & Chianelli, R. R. (1994) · Journal of Catalysis · doi:10.1006/jcat.1994.1308 · Cited by 759
Hydrogen evolution catalyzed by MoS3 and MoS2 particles
Vrubel, H., Merki, D., & Hu, X. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02835b · Cited by 726
Size-dependent structure of MoS2 nanocrystals
Lauritsen, J. V., Kibsgaard, J., Helveg, S., Topsøe, H., Clausen, B. S., Lægsgaard, E., & Besenbacher, F. (2007) · Nature Nanotechnology · doi:10.1038/nnano.2006.171 · Cited by 714
Bioinspired molecular co-catalysts bonded to a silicon photocathode for solar hydrogen evolution
Hou, Y., Abrams, B. L., Vesborg, P. C. K., Björketun, M. E., Herbst, K., Bech, L., Setti, A. M., Damsgaard, C. D., Pedersen, T., Hansen, O., et al. (2011) · Nature Materials · doi:10.1038/nmat3008 · Cited by 640
Bockris, J. O., & Khan, S. U. M. (1993) · Springer eBooks · doi:10.1007/978-1-4615-3040-4 · Cited by 606
Nanoscale Advances in Catalysis and Energy Applications
Li, Y., & Somorjai, G. A. (2010) · Nano Letters · doi:10.1021/nl101807g · Cited by 441
Fang, B., Kim, J. H., Kim, M.-S., & Yu, J.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300253f · Cited by 408
Self-citationWang, T., Liu, L., Zhu, Z., Papakonstantinou, P., Hu, J., Liu, H., & Li, M. (2013) · Energy Environ. Sci. · doi:10.1039/c2ee23513g · Cited by 393
Nanoparticles in Energy Technology: Examples from Electrochemistry and Catalysis
Raimondi, F., Scherer, G. G., Kötz, R., & Wokaun, A. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200460466 · Cited by 381
WS2 nanosheets as a highly efficient electrocatalyst for hydrogen evolution reaction
Wu, Z., Fang, B., Bonakdarpour, A., Sun, A., Wilkinson, D. P., & Wang, D. (2012) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2012.05.013 · Cited by 333
Self-citationCopper molybdenum sulfide: a new efficient electrocatalyst for hydrogen production from water
Tran, P. D., Nguyen, M., Pramana, S. S., Bhattacharjee, A., Chiam, S. Y., Fize, J., Field, M. J., Artero, V., Wong, L. H., Loo, J., et al. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22611a · Cited by 329
Fang, B., Chaudhari, N. K., Kim, M.-S., Kim, J. H., & Yu, J.-S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja905749e · Cited by 311
Self-citationAtomic‐Scale Edge Structures on Industrial‐Style MoS2 Nanocatalysts
Hansen, L. P., Ramasse, Q. M., Kisielowski, C., Brorson, M., Johnson, E., Topsøe, H., & Helveg, S. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103745 · Cited by 252
Yoosuk, B., Kim, J. H., Song, C., Ngamcharussrivichai, C., & Prasassarakich, P. (2008) · Catalysis Today · doi:10.1016/j.cattod.2007.07.003 · Cited by 195
Graphene oxide as a highly selective substrate to synthesize a layered MoS2 hybrid electrocatalyst
Firmiano, E. G. S., Cordeiro, M. A. L., Rabelo, A. C., Dalmaschio, C. J., Pinheiro, A. N., Pereira, E. C., & Leite, E. R. (2012) · Chemical Communications · doi:10.1039/c2cc33397j · Cited by 181
Wirth, S., Harnisch, F., Weinmann, M., & Schröder, U. (2012) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2012.07.023 · Cited by 172
Bian, X., Zhu, J., Liao, L., Scanlon, M. D., Ge, P., Ji, C., Girault, H. H., & Liu, B. (2012) · Electrochemistry Communications · doi:10.1016/j.elecom.2012.06.009 · Cited by 152
The reactivity of MoS2 single crystal edge planes
Chianelli, R. R. (1985) · Journal of Catalysis · doi:10.1016/0021-9517(85)90236-2 · Cited by 128
Fang, B., Kim, J. H., Kim, M., Bonakdarpour, A., Lam, A., Wilkinson, D. P., & Yu, J. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33435f · Cited by 114
Self-citationFang, B., Kim, M.-S., Kim, J. H., Song, M. Y., Wang, Y.-J., Wang, H., Wilkinson, D. P., & Yu, J.-S. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10847f · Cited by 89
Self-citationKautek, W., & Gerischer, H. (1982) · Surface Science · doi:10.1016/0039-6028(82)90186-8 · Cited by 87
Optical absorption and catalytic activity of molybdenum sulfide edge surfaces
Roxlo, C. B. (1986) · Journal of Catalysis · doi:10.1016/0021-9517(86)90083-7 · Cited by 81
CO adsorption and kinetics on well-characterized Pd films on Pt() in alkaline solutions
Arenz, M., Stamenković, V. R., Schmidt, T. J., Wandelt, K. R., ROSS, P. N. J., & Marković, N. M. (2002) · Surface Science · doi:10.1016/s0039-6028(02)01423-1 · Cited by 77
Usman, U., Kubota, T., Araki, Y., Ishida, K., & Okamoto, Y. (2004) · Journal of Catalysis · doi:10.1016/j.jcat.2004.08.028 · Cited by 73
Kim, J. H., Fang, B., Song, M. Y., & Yu, J.-S. (2012) · Chemistry of Materials · doi:10.1021/cm203520a · Cited by 72
Self-citationLau, V. W., Masters, A. F., Bond, A. M., & Maschmeyer, T. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201200255 · Cited by 70
Fang, B., Kim, J. H., & Yu, J.-S. (2008) · Electrochemistry Communications · doi:10.1016/j.elecom.2008.01.022 · Cited by 68
Self-citationBahl, O. P., Evans, E. L., & Thomas, J. M. (1968) · Proceedings of the Royal Society of London A Mathematical and Physical Sciences · doi:10.1098/rspa.1968.0137 · Cited by 62
Preparation of MoS2 nanoflakes by a novel mechanical activation method
Wu, Z., Wang, D., & Sun, A. (2009) · Journal of Crystal Growth · doi:10.1016/j.jcrysgro.2009.10.024 · Cited by 46
Self-citationLau, V. W., Masters, A. F., Bond, A. M., & Maschmeyer, T. (2011) · ChemCatChem · doi:10.1002/cctc.201100212 · Cited by 42
Elezović, N. R., Gajić-Krstajić, L., Radmilovic, V. R., Vračar, L. M., & Krstajic, N. V. (2008) · Electrochimica Acta · doi:10.1016/j.electacta.2008.08.067 · Cited by 36
Hydrogen-evolution and -oxidation on Ag(111) covered by Pt
Tölle, R., & Otto, A. (2005) · Surface Science · doi:10.1016/j.susc.2004.10.058 · Cited by 19
Research works printed but not linked: 8
- Alvarez L., 2008, Catal. Lett., 125, 35, 10.1007/s10562-008-9541-2 · doi:10.1007/s10562-008-9541-2
- Zhou T., 2010, Catal. Lett., 134, 343, 10.1007/s10562-009-0210-x · doi:10.1007/s10562-009-0210-x
- Wang H., 2009, J. Catal., 267, 193, 10.1016/j.jcat.2009.08.013 · doi:10.1016/j.jcat.2009.08.013
- Liu B., 2012, Fuel, 95, 457, 10.1016/j.fuel.2011.12.019 · doi:10.1016/j.fuel.2011.12.019
- Okamato Y., 2009, J. Catal., 268, 49, 10.1016/j.jcat.2009.08.017 · doi:10.1016/j.jcat.2009.08.017
- Wu Z., 2010, Adv. Eng. Mater., 12, 534, 10.1002/adem.201000127 · doi:10.1002/adem.201000127
- Okamoto Y., 2005, J. Catal., 233, 16, 10.1016/j.jcat.2005.04.010 · doi:10.1016/j.jcat.2005.04.010
- Huirache-Acuna R., 2006, Appl. Catal., A, 308, 134, 10.1016/j.apcata.2006.04.015 · doi:10.1016/j.apcata.2006.04.015
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Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials
Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P., & Jaramillo, T. F. (2014) · ACS Catalysis · doi:10.1021/cs500923c · Cited by 1,617
Lu, Q., Yu, Y., Ma, Q., Chen, B., & Zhang, H. (2016) · Advanced Materials · doi:10.1002/adma.201503270 · Cited by 1,447
Voiry, D., Yang, J., & Chhowalla, M. (2016) · Advanced Materials · doi:10.1002/adma.201505597 · Cited by 949
Metadata
- Authors
- Wu, Z., Fang, B., Wang, Z., Wang, C., Liu, Z., Liu, F., Wang, W., Alfantazi, A., Wang, D., & Wilkinson, D. P.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-16
- Volume
- 3
- Issue
- 9
- Pages
- 2101-2107
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2332269594
- Cited by
- 382
- References
- 49
- FWCI
- 13.22
- Type
- journal article
- Language
- en
- Open access
- closed
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