The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation
Abstract
A highly selective and robust catalyst based on Pt nanoclusters (NCs) confined inside the cavities of an amino-functionalized Zr-terephthalate metal–organic framework (MOF), UiO-66-NH 2 was developed. The Pt NCs are monodisperse and confined in the cavities of UiO-66-NH 2 even at 10.7 wt % Pt loading. This confinement was further confirmed by comparing the catalytic performance of Pt NCs confined inside and supported on the external surface of the MOF in the hydrogenation of ethylene, 1-hexene, and 1,3-cyclooctadiene. The benefit of confining Pt NCs inside UiO-66-NH 2 was also demonstrated by evaluating their performance in the chemoselective hydrogenation of cinnamaldehyde. We found that both high selectivity to cinnamyl alcohol and high conversion of cinnamaldehyde can be achieved using the MOF-confined Pt nanocluster catalyst, while we could not achieve high cinnamyl alcohol selectivity on Pt NCs supported on the external surface of the MOF. The catalyst can be recycled ten times without any loss in its activity and selectivity. To confirm the stability of the recycled catalysts, we conducted kinetic studies for the first 20 h of reaction during four recycle runs on the catalyst. Both the conversion and selectivity are almost overlapping for the four runs, which indicates the catalyst is very stable under the employed reaction conditions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Luminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
Hydrogen Storage in Metal–Organic Frameworks
Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
Corma, A., García, H., & Llabrés i Xamena, F. X. (2010) · Chemical Reviews · doi:10.1021/cr9003924 · Cited by 3,478
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
Yoon, M., Srirambalaji, R., & Kim, K. (2012) · Chemical Reviews · doi:10.1021/cr2003147 · Cited by 2,856
Crooks, R. M., Zhao, M., Sun, L., Chechik, V., & Yeung, L. K. (2001) · Accounts of Chemical Research · doi:10.1021/ar000110a · Cited by 2,115
Synthesis and Stability of Tagged UiO-66 Zr-MOFs
Kandiah, M., Nilsen, M. H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., Larabi, C., Quadrelli, E. A., Bonino, F., & Lillerud, K. P. (2010) · Chemistry of Materials · doi:10.1021/cm102601v · Cited by 2,031
Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals
Schaate, A., Roy, P., Godt, A., Lippke, J., Waltz, F., Wiebcke, M., & Behrens, P. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201003211 · Cited by 1,701
Hwang, Y. K., Hong, D., Chang, J., Jhung, S. H., Seo, Y., Kim, J., Vimont, A., Daturi, M., Serre, C., & Férey, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705998 · Cited by 1,243
Selective Hydrogenation of α,β-Unsaturated Aldehydes
GALLEZOT, P., & RICHARD, D. (1998) · Catalysis Reviews · doi:10.1080/01614949808007106 · Cited by 978
Application of Carbon Nanotubes as Supports in Heterogeneous Catalysis
Planeix, J. M., Coustel, N., Coq, B., Brotons, V., Kumbhar, P. S., Dutartre, R., Geneste, P., Bernier, P., & Ajayan, P. M. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00096a076 · Cited by 973
Aijaz, A., Karkamkar, A., Choi, Y. J., Tsumori, N., Rönnebro, E., Autrey, T., Shioyama, H., & Xu, Q. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3043905 · Cited by 945
Synthesis, Characterization, and Applications of Dendrimer-Encapsulated Nanoparticles
Scott, R. W. J., Wilson, O. M., & Crooks, R. M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0469665 · Cited by 866
Metal–Organic Frameworks for Light Harvesting and Photocatalysis
Wang, J.-L., Wang, C., & Lin, W. (2012) · ACS Catalysis · doi:10.1021/cs3005874 · Cited by 802
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO 2 Surfaces
Kaden, W. E., Wu, T., Kunkel, W. A., & Anderson, S. L. (2009) · Science · doi:10.1126/science.1180297 · Cited by 633
Size-specific catalytic activity of platinum clusters enhances oxygen reduction reactions
Yamamoto, K., Imaoka, T., Chun, W.-J., Enoki, O., Katoh, H., Takenaga, M., & Sonoi, A. (2009) · Nature Chemistry · doi:10.1038/nchem.288 · Cited by 585
Wang, Y., Ren, J., Deng, K., Gui, L., & Tang, Y. (2000) · Chemistry of Materials · doi:10.1021/cm0000853 · Cited by 578
H2storage in isostructural UiO-67 and UiO-66 MOFs
Chavan, S., Vitillo, J. G., Gianolio, D., Zavorotynska, O., Civalleri, B., Jakobsen, S., Nilsen, M. H., Valenzano, L., Lamberti, C., Lillerud, K. P., et al. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp23434j · Cited by 485
Schröder, F., Esken, D., Cokoja, M., van den Berg, M. W. E., Lebedev, O. I., Van Tendeloo, G., Walaszek, B., Buntkowsky, G., Limbach, H.-H., Chaudret, B., et al. (2008) · Journal of the American Chemical Society · doi:10.1021/ja078231u · Cited by 372
Zlotea, C., Campesi, R., Cuevas, F., Leroy, E., Dibandjo, P., Volkringer, C., Loiseau, T., Férey, G., & Latroche, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9084995 · Cited by 347
Wu, B., Huang, H., Yang, J., Zheng, N., & Fu, G. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108593 · Cited by 325
Stabilized gold clusters: from isolation toward controlled synthesis
Maity, P., Xie, S., Yamauchi, M., & Tsukuda, T. (2012) · Nanoscale · doi:10.1039/c2nr30900a · Cited by 302
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
Dhakshinamoorthy, A., Opanasenko, M., Čejka, J., & Garcia, H. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00350g · Cited by 296
Esken, D., Turner, S., Lebedev, O. I., Van Tendeloo, G., & Fischer, R. A. (2010) · Chemistry of Materials · doi:10.1021/cm102529c · Cited by 281
Huang, W., Kuhn, J. N., Tsung, C.-K., Zhang, Y., Habas, S. E., Yang, P., & Somorjai, G. A. (2008) · Nano Letters · doi:10.1021/nl801325m · Cited by 267
Self-citationCastillejos, E., Debouttière, P., Roiban, L., Solhy, A., Martinez, V., Kihn, Y., Ersen, O., Philippot, K., Chaudret, B. N., & Serp, P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805273 · Cited by 257
Li, P.-Z., Aranishi, K., & Xu, Q. (2012) · Chemical Communications · doi:10.1039/c2cc17302f · Cited by 251
Silver Cluster Formation, Dynamics, and Chemistry in Metal−Organic Frameworks
Houk, R. J. T., Jacobs, B. W., Gabaly, F. E., Chang, N. N., Talin, A. A., Graham, D. D., House, S. D., Robertson, I. M., & Allendorf, M. D. (2009) · Nano Letters · doi:10.1021/nl901397k · Cited by 249
Coq, B., & Figueras, F. (1998) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(98)00058-7 · Cited by 231
Ni/Pd@MIL‐101: Synergistic Catalysis with Cavity‐Conform Ni/Pd Nanoparticles
Hermannsdörfer, J., Friedrich, M., Miyajima, N., Albuquerque, R. Q., Kümmel, S., & Kempe, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201205078 · Cited by 192
Cheon, Y. E., & Suh, M. P. (2008) · Chemistry – A European Journal · doi:10.1002/chem.200701813 · Cited by 186
Huang, Y., Zheng, Z., Liu, T., Lü, J., Lin, Z., Li, H., & Cao, R. (2011) · Catalysis Communications · doi:10.1016/j.catcom.2011.07.004 · Cited by 179
Lim, D., Yoon, J. W., Ryu, K. Y., & Suh, M. P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206055 · Cited by 171
Li, H., Zhu, Z., Zhang, F., Xie, S., Li, H., Li, P., & Zhou, X. (2011) · ACS Catalysis · doi:10.1021/cs200351p · Cited by 163
Direct Imaging of Loaded Metal−Organic Framework Materials (Metal@MOF-5)
Turner, S., Lebedev, O. I., Schröder, F., et al. (2008) · Chemistry of Materials · doi:10.1021/cm801165s · Cited by 156
Karabacak, M., Çınar, M., Unal, Z., & Kurt, M. (2010) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2010.07.033 · Cited by 138
Blackmond, D. G. (1991) · Journal of Catalysis · doi:10.1016/0021-9517(91)90275-9 · Cited by 136
Zahmakıran, M. (2012) · Dalton Transactions · doi:10.1039/c2dt31779f · Cited by 133
Peter, M., Camacho, J. M. F., Adamovski, S., et al. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209476 · Cited by 84
Oduro, W. O., Cailuo, N., Yu, K. M. K., Yang, H., & Tsang, S. C. E. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp01832e · Cited by 67
Cited by
Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
Yang, Q., Xu, Q., & Jiang, H.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00724d · Cited by 1,892
Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms
Zhang, L., Zhou, M., Wang, A., & Zhang, T. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00230 · Cited by 1,611
Ordered macro-microporous metal-organic framework single crystals
Shen, K., Zhang, L., Chen, X., Liu, L., Zhang, D., Han, Y., Chen, J., Long, J., Luque, R., Li, Y., et al. (2018) · Science · doi:10.1126/science.aao3403 · Cited by 1,207
Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research
Yang, D., & Gates, B. C. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04515 · Cited by 932
Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Metadata
- Authors
- Guo, Z., Xiao, C., Maligal-Ganesh, R. V., Zhou, L., Goh, T. W., Li, X., Tesfagaber, D., Thiel, A., & Huang, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-02
- Volume
- 4
- Issue
- 5
- Pages
- 1340-1348
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2094642979
- Cited by
- 419
- References
- 43
- FWCI
- 15.80
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
