Reaction mechanism for the aqueous-phase mineral carbonation of heat-activated serpentine at low temperatures and pressures in flue gas conditions
Abstract
Mineral carbonation is known as one of the safest ways to sequester CO2. Nevertheless, the slow kinetics and low carbonation rates constitute a major barrier for any possible industrial application. To date, no studies have focused on reacting serpentinite with a relatively low partial pressure of CO2 (pCO2) close to flue gas conditions. In this work, finely ground and heat-treated serpentinite [Mg3Si2O5(OH)4] extracted from mining residues was reacted with a 18.2 vol % CO2 gas stream at moderate global pressures to investigate the effect on CO2 solubility and Mg leaching. Serpentinite dissolution rates were also measured to define the rate-limiting step. Successive batches of gas were contacted with the same serpentinite to identify surface-limiting factors using scanning electron microscopy (SEM) analysis. Investigation of the serpentinite carbonation reaction mechanisms under conditions close to a direct flue gas treatment showed that increased dissolution rates could be achieved relative to prior work, with an average Mg dissolution rate of 3.55 × 10(-11) mol cm(-2) s(-1). This study provides another perspective of the feasibility of applying a mineral carbonation process to reduce industrial greenhouse gas (GHG) emissions from large emission sources.
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The ultramafic rock-hosted ore deposits favored for integrated mineral carbonation technologies include chrysotile, nickel, chromium, diamond, and platinum group element mines.
“The ultramafic rock-hosted ore deposits that are favored for integrated mineral carbonation technologies include chrysotile [63], nickel [64-66], chromium [67,68], diamond [69] and platinum group element (PGE) mines [70,71].”
From Integrated Mineral Carbonation of Ultramafic Mine Deposits—A Review (2018) · cites this paper as [67]
The most common methods for mine waste pre-treatment are thermal activation using calcination, microwave heating, steam mediation, and chemical activation using organic or inorganic acids.
“The most common methods for mine waste pre-treatment are thermal activation using calcination [67], microwave heating [11], steam mediation [110], and chemical activation using organic or inorganic acids [11].”
From Integrated Mineral Carbonation of Ultramafic Mine Deposits—A Review (2018) · cites this paper as [67]
Cites
Climate Change 2014 Impacts, Adaptation, and Vulnerability
(IPCC), I. P. O. C. C. (2014) · Cambridge University Press eBooks · doi:10.1017/cbo9781107415379 · Cited by 14,874 · see citing works
Change, I. P. O. C. (2007) · Cambridge University Press eBooks · doi:10.1017/cbo9780511546013 · Cited by 7,742 · see citing works
Intergovernmental Panel on Climate Change (IPCC)
Reinman, S. L. (2012) · Reference Reviews · doi:10.1108/09504121211205250 · Cited by 4,484 · see citing works
Carbon dioxide in water and seawater: the solubility of a non-ideal gas
Weiss, R. F. (1974) · Marine Chemistry · doi:10.1016/0304-4203(74)90015-2 · Cited by 3,373 · see citing works
Holland, T. J. B., & Powell, R. (2011) · Journal of Metamorphic Geology · doi:10.1111/j.1525-1314.2010.00923.x · Cited by 2,519 · see citing works
Progress in carbon dioxide separation and capture: A review
Yang, H., Xu, Z., Fan, M., Gupta, R. P., Slimane, R. B., Bland, A. E., & Wright, I. G. (2008) · Journal of Environmental Sciences · doi:10.1016/s1001-0742(08)60002-9 · Cited by 2,088 · see citing works
Advanced Technology Paths to Global Climate Stability: Energy for a Greenhouse Planet
Hoffert, M. I., Caldeira, K., Benford, G., Criswell, D. R., Green, C., Herzog, H. J., Jain, A. K., Kheshgi, H. S., Lackner, K. S., Lewis, J. S., et al. (2002) · Science · doi:10.1126/science.1072357 · Cited by 1,550 · see citing works
CO2 Sequestration in Deep Sedimentary Formations
Benson, S. M., & Cole, D. R. (2008) · Elements · doi:10.2113/gselements.4.5.325 · Cited by 1,102 · see citing works
Spycher, N., Pruess, K., & Ennis-King, J. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(03)00273-4 · Cited by 991 · see citing works
Oelkers, E. H., Gislason, S. R., & Matter, J. (2008) · Elements · doi:10.2113/gselements.4.5.333 · Cited by 676 · see citing works
Carbon capture and storage using alkaline industrial wastes
Bobicki, E. R., Liu, Q., Xu, Z., & Zeng, H. (2012) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2011.11.002 · Cited by 666 · see citing works
Ex situ aqueous mineral carbonation
Gerdemann, S. J., O'Connor, W. K., Dahlin, D. C., Penner, L. R., & Rush, H. (2007) · Environmental Science & Technology · doi:10.1021/es0619253 · Cited by 633 · see citing works
The clathrate hydrate process for post and pre-combustion capture of carbon dioxide
Linga, P., Kumar, R., & Englezos, P. (2007) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2007.06.086 · Cited by 547 · see citing works
Precipitation in the Mg-carbonate system—effects of temperature and CO2 pressure
Hänchen, M., Prigiobbe, V., Baciocchi, R., & Mazzotti, M. (2008) · Chemical Engineering Science · doi:10.1016/j.ces.2007.09.052 · Cited by 545 · see citing works
Wiebe, R., & Gaddy, V. L. (1940) · Journal of the American Chemical Society · doi:10.1021/ja01861a033 · Cited by 484 · see citing works
Carbon dioxide sequestration in cement kiln dust through mineral carbonation
Huntzinger, D. N., Gierke, J. S., Kawatra, S. K., Eisele, T. C., & Sutter, L. L. (2009) · Environmental Science & Technology · doi:10.1021/es802910z · Cited by 442 · see citing works
Carbon Sequestration via Aqueous Olivine Mineral Carbonation: Role of Passivating Layer Formation
Béarat, H. A., McKelvy, M. J., Chizmeshya, A. V. G., Gormley, D., Nunez, R., Carpenter, R. W., Squires, K. D., & Wolf, G. H. (2006) · Environmental Science & Technology · doi:10.1021/es0523340 · Cited by 426 · see citing works
Dissolution kinetics of magnesium silicates
Luce, R. W., Bartlett, R. W., & Parks, G. A. (1972) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(72)90119-6 · Cited by 384 · see citing works
Carbonate Chemistry for Sequestering Fossil Carbon
Lackner, K. S. (2002) · Annual Review of Energy and the Environment · doi:10.1146/annurev.energy.27.122001.083433 · Cited by 361 · see citing works
Accelerated carbonation of brucite in mine tailings for carbon sequestration
Harrison, A. L., Power, I. M., & Dipple, G. M. (2013) · Environmental Science & Technology · doi:10.1021/es3012854 · Cited by 328 · see citing works
Dissolution and precipitation kinetics of sheet silicates
Nagy, K. L. (1995) · Reviews in Mineralogy and Geochemistry · Cited by 274 · see citing works
Wilson, S., Dipple, G. M., Power, I. M., Thom, J. M., Anderson, R. G., Raudsepp, M., Gabites, J. E., & Southam, G. (2009) · Economic Geology · doi:10.2113/gsecongeo.104.1.95 · Cited by 261 · see citing works
Cost evaluation of CO2 sequestration by aqueous mineral carbonation
Huijgen, W. J. J., Comans, R. N. J., & Witkamp, G.-J. (2007) · Energy Conversion and Management · doi:10.1016/j.enconman.2007.01.035 · Cited by 249 · see citing works
Chemical weathering rates of silicate minerals; an overview
White, A. F., & Brantley, S. L. (1995) · Reviews in Mineralogy and Geochemistry · Cited by 236 · see citing works
Geological Sequestration of Carbon Dioxide - Thermodynamics, Kinetics, and Reaction Path Modeling
(2007) · Developments in geochemistry · doi:10.1016/s0921-3198(06)x8011-0 · Cited by 218 · see citing works
Wilson, S. A. (2006) · American Mineralogist · doi:10.2138/am.2006.2058 · Cited by 172 · see citing works
Energy Consumption and Net CO <sub>2</sub> Sequestration of Aqueous Mineral Carbonation
Huijgen, W. J. J., Ruijg, G. J., Comans, R. N. J., & Witkamp, G.-J. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie060636k · Cited by 162 · see citing works
Pokrovsky, O. S., & Schott, J. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00013-7 · Cited by 153 · see citing works
Dissolution kinetics of chrysotile at pH 7 to 10
Bales, R. C., & Morgan, J. J. (1985) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(85)90228-5 · Cited by 152 · see citing works
Avi-Yonah, R. S., & Uhlmann, D. M. (2008) · SSRN Electronic Journal · doi:10.2139/ssrn.1109167 · Cited by 151 · see citing works
Chen, Z., O’Connor, W. K., & Gerdemann, S. J. (2006) · Environmental Progress · doi:10.1002/ep.10127 · Cited by 145 · see citing works
Exploration of the role of heat activation in enhancing serpentine carbon sequestration reactions
McKelvy, M. J., Chizmeshya, A. V. G., Diefenbacher, J., Béarat, H., & Wolf, G. (2004) · Environmental Science & Technology · doi:10.1021/es049473m · Cited by 140 · see citing works
Evaluation of reaction variables in the dissolution of serpentine for mineral carbonation
Alexander, G., Maroto‐Valer, M. M., & Aksoy, P. (2006) · Fuel · doi:10.1016/j.fuel.2006.04.034 · Cited by 137 · see citing works
Heat optimisation of a staged gas–solid mineral carbonation process for long-term CO2 storage
Zevenhoven, R., Teir, S., & Eloneva, S. (2007) · Energy · doi:10.1016/j.energy.2007.11.005 · Cited by 133 · see citing works
Carbon sequestration kinetic and storage capacity of ultramafic mining waste
Pronost, J., Beaudoin, G., Tremblay, J., Larachi, F., Duchesne, J., Hébert, R., & Constantin, M. (2011) · Environmental Science & Technology · doi:10.1021/es203063a · Cited by 128 · see citing works
Gas–solid carbonation kinetics of Air Pollution Control residues for CO2 storage
Prigiobbe, V., Polettini, A., & Baciocchi, R. (2008) · Chemical Engineering Journal · doi:10.1016/j.cej.2008.08.031 · Cited by 118 · see citing works
Mineral carbonation process for CO2 sequestration
Prigiobbe, V., Hänchen, M., Werner, M., Baciocchi, R., & Mazzotti, M. (2009) · Energy Procedia · doi:10.1016/j.egypro.2009.02.318 · Cited by 105 · see citing works
Microbially mediated mineral carbonation: Roles of phototrophy and heterotrophy
Power, I. M., Wilson, S., Small, D. P., Dipple, G. M., Wan, W., & Southam, G. (2011) · Environmental Science & Technology · doi:10.1021/es201648g · Cited by 103 · see citing works
Experiments and geochemical modelling of CO2 sequestration by olivine: Potential, quantification
Garcia, B., Beaumont, V., Perfetti, E., Rouchon, V., Blanchet, D., Oger, P., Dromart, G., Huc, A. Y., & Haeseler, F. (2010) · Applied Geochemistry · doi:10.1016/j.apgeochem.2010.06.009 · Cited by 101 · see citing works
Solubilities of Gases in Liquids at High Pressure
Frölich, P. K., Tauch, E. J., Hogan, J. J., & Peer, A. A. (1931) · Industrial & Engineering Chemistry · doi:10.1021/ie50257a019 · Cited by 92 · see citing works
Carbon Dioxide Sequestration by Aqueous Mineral Carbonation of Magnesium Silicate Minerals
Gerdemann, S. J., DAHLIN, D., & O’Connor, W. K. (2003) · Elsevier eBooks · doi:10.1016/b978-008044276-1/50108-2 · Cited by 88 · see citing works
Assima, G. P., Larachi, F., Beaudoin, G., & Molson, J. (2013) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2012.10.001 · Cited by 87 · see citing works
Carbonation of magnesium silicate mineral using a pressurised gas/solid process
Fagerlund, J., Teir, S., Nduagu, E. I., & Zevenhoven, R. (2009) · Energy Procedia · doi:10.1016/j.egypro.2009.02.321 · Cited by 81 · see citing works
Assima, G. P., Larachi, F., Beaudoin, G., & Molson, J. W. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie202693q · Cited by 80 · see citing works
Pasquier, L.-C., Mercier, G., Blais, J.-F., Cecchi, E., & Kentish, S. (2014) · Applied Geochemistry · doi:10.1016/j.apgeochem.2014.08.008 · Cited by 66 · see citing works
Self-citationDissolution of magnesium from calcined serpentinite in hydrochloric acid
Fedoročková, A., Hreus, M., Raschman, P., & Sučík, G. (2012) · Minerals Engineering · doi:10.1016/j.mineng.2012.03.006 · Cited by 61 · see citing works
Mineralisation of carbon dioxide (CO2)
Zevenhoven, R., & Fagerlund, J. (2010) · Elsevier eBooks · doi:10.1533/9781845699581.4.433 · Cited by 29 · see citing works
Werner, M., Verduyn, M. A., van Mossel, G., & Mazzotti, M. (2011) · Energy Procedia · doi:10.1016/j.egypro.2011.02.086 · Cited by 16 · see citing works
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Cited by
Sorted by citations
An Overview of the Status and Challenges of CO2 Storage in Minerals and Geological Formations
Kelemen, P., Benson, S. M., Pilorgé, H., Psarras, P., & Wilcox, J. (2019) · Frontiers in Climate · doi:10.3389/fclim.2019.00009 · Cited by 587 · see citing works
“…2009; Larachi et al., 2010, 2012; Balucan et al., 2011; Fedoročková et al., 2012; Balucan and Dlugogorski, 2013; Werner et al., 2013, 2014; Dlugogorski and Balucan, 2014; Ghoorah et al., 2014; Hariharan et al., 2014, 2016; Pasquier et al., 2014; Sanna et al., 2014; Hariharan and Mazzotti, 2017).”
BackgroundCO2 mineral carbonation using industrial solid wastes: A review of recent developments
Liu, W., Teng, L., Rohani, S., Qin, Z., Zhao, B., Xu, C. C., Ren, S., Liu, Q., & Liang, B. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.129093 · Cited by 508 · see citing works
Kinetics and mechanism of mineral carbonation of olivine for CO2 sequestration
Wang, F., Dreisinger, D., Jarvis, M., & Hitchins, T. (2019) · Minerals Engineering · doi:10.1016/j.mineng.2018.11.024 · Cited by 187 · see citing works
Recent developments and challenges of aqueous mineral carbonation: a review
Veetil, S. P., & Hitch, M. (2020) · International Journal of Environmental Science and Technology · doi:10.1007/s13762-020-02776-z · Cited by 134 · see citing works
Gadikota, G., Matter, J., Kelemen, P., Brady, P. V., & Park, A.-H. A. (2020) · Fuel · doi:10.1016/j.fuel.2020.117900 · Cited by 128 · see citing works
Integrated Mineral Carbonation of Ultramafic Mine Deposits—A Review
Li, J., Hitch, M., Power, I., & Pan, Y. (2018) · Minerals · doi:10.3390/min8040147 · Cited by 114 · see citing works
“The ultramafic rock-hosted ore deposits that are favored for integrated mineral carbonation technologies include chrysotile [63], nickel [64–66], chromium [67,68], diamond [69] and platinum group element (PGE) mines [70,71].”
BackgroundMethodInfluentialAdvances in process development of aqueous CO2 mineralisation towards scalability
Zhang, N., Chai, Y. E., Santos, R. M., & Šiller, L. (2020) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2020.104453 · Cited by 88 · see citing works
Aqueous mineral carbonation for CO 2 sequestration: From laboratory to pilot scale
Kemache, N., Pasquier, L.-C., Cecchi, E., Mouedhen, I., Blais, J., & Mercier, G. (2017) · Fuel Processing Technology · doi:10.1016/j.fuproc.2017.06.005 · Cited by 81 · see citing works
Self-citationQuantifying kinetics of mineralization of carbon dioxide by olivine under moderate conditions
Wang, F., Dreisinger, D. B., Jarvis, M., Hitchins, T., & Dyson, D. A. W. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.11.200 · Cited by 75 · see citing works
Direct aqueous carbonation on olivine at a CO2 partial pressure of 6.5 MPa
Li, J., Jacobs, A. D., & Hitch, M. (2019) · Energy · doi:10.1016/j.energy.2019.02.125 · Cited by 74 · see citing works
Rim, G., Marchese, A. K., Stallworth, P., Greenbaum, S. G., & Park, A.-H. A. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.125204 · Cited by 72 · see citing works
Stokreef, S., Sadri, F., Stokreef, A., & Ghahreman, A. (2022) · Cleaner Engineering and Technology · doi:10.1016/j.clet.2022.100491 · Cited by 71 · see citing works
Song, Y., Diao, X., Xu, R. L., Wang, X., Han, Y., Shi, T., Fang, B., Liu, Y., & Corr, D. J. (2025) · Environmental Science & Technology · doi:10.1021/acs.est.5c03561 · Cited by 70 · see citing works
Insights into the dissolution kinetics of thermally activated serpentine for CO2 sequestration
Farhang, F., Rayson, M. S., Brent, G. F., Hodgins, T. W., Stockenhuber, M., & Kennedy, E. M. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.08.073 · Cited by 69 · see citing works
Pasquier, L.-C., Mercier, G., Blais, J.-F., Cecchi, E., & Kentish, S. (2014) · Applied Geochemistry · doi:10.1016/j.apgeochem.2014.08.008 · Cited by 66 · see citing works
Self-citationMineralization of alkaline waste for CCUS
Walker, I., Bell, R., & Rippy, K. C. (2024) · npj Materials Sustainability · doi:10.1038/s44296-024-00031-x · Cited by 63 · see citing works
A review on chemical precipitation in carbon capture, utilization and storage
Lin, J.-Y., Garcia, E. A., Ballesteros, F., Garcia‐Segura, S., & Lu, M. (2022) · Sustainable Environment Research · doi:10.1186/s42834-022-00155-6 · Cited by 61 · see citing works
Werner, M., Hariharan, S., & Mazzotti, M. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp02786h · Cited by 60 · see citing works
Benhelal, E., Rashid, M. I., Rayson, M. S., Brent, G. F., Oliver, T. K., Stockenhuber, M., & Kennedy, E. M. (2019) · Applied Energy · doi:10.1016/j.apenergy.2019.03.170 · Cited by 59 · see citing works
Study on mineral carbonation of heat activated lizardite at pilot and laboratory scale
Benhelal, E., Rashid, M. I., Rayson, M. S., Prigge, J.-D., Molloy, S., Brent, G. F., Cote, A., Stockenhuber, M., & Kennedy, E. M. (2018) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2018.05.015 · Cited by 51 · see citing works
Li, J., & Hitch, M. (2015) · Powder Technology · doi:10.1016/j.powtec.2015.12.011 · Cited by 49 · see citing works
Effect of pCO 2 on direct flue gas mineral carbonation at pilot scale
Mouedhen, I., Kemache, N., Pasquier, L.-C., Cecchi, E., Blais, J., & Mercier, G. (2017) · Journal of Environmental Management · doi:10.1016/j.jenvman.2017.04.048 · Cited by 46 · see citing works
Self-citationRausis, K., Ćwik, A., & Casanova, I. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.12.007 · Cited by 46 · see citing works
Li, J., & Hitch, M. (2018) · International Biodeterioration & Biodegradation · doi:10.1016/j.ibiod.2016.08.026 · Cited by 45 · see citing works
Zhang, N., Santos, R. M., Smith, S. M., & Šiller, L. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.11.177 · Cited by 41 · see citing works
Kemache, N., Pasquier, L.-C., Mouedhen, I., Cecchi, E., Blais, J.-F., & Mercier, G. (2016) · Applied Geochemistry · doi:10.1016/j.apgeochem.2016.02.003 · Cited by 40 · see citing works
Self-citationHamedi, H., Gonzales‐Calienes, G., & Shadbahr, J. (2025) · Clean Technologies · doi:10.3390/cleantechnol7020044 · Cited by 39 · see citing works
Rim, G., Roy, N., Zhao, D., Kawashima, S., Stallworth, P. E., Greenbaum, S., & Park, A. A. (2021) · Faraday Discussions · doi:10.1039/d1fd00022e · Cited by 39 · see citing works
A comprehensive review of enhanced in-situ CO2 mineralisation in Australia and New Zealand
Kalbani, M. A., Serati, M., Hofmann, H., & Boré, T. (2023) · International Journal of Coal Geology · doi:10.1016/j.coal.2023.104316 · Cited by 38 · see citing works
Guermech, S., Mocellin, J., Tran, L. H., Mercier, G., & Pasquier, L.-C. (2022) · Journal of Crystal Growth · doi:10.1016/j.jcrysgro.2022.126540 · Cited by 34 · see citing works
Self-citationLi, L., Yu, H. B., Zhou, S., Dao, V. T. N., Chen, M., Ji, L., & Benhelal, E. (2023) · Materials Today Sustainability · doi:10.1016/j.mtsust.2023.100530 · Cited by 33 · see citing works
Modified wollastonite sequestrating CO 2 and exploratory application of the carbonation products
Ding, W., Yang, H., Ouyang, J., & Long, H. (2016) · RSC Advances · doi:10.1039/c6ra13908f · Cited by 30 · see citing works
Rim, G., Wang, D., Rayson, M. S., Brent, G. F., & Park, A. A. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.9b07050 · Cited by 30 · see citing works
Breuil, C. D., Pasquier, L.-C., Dipple, G. M., Blais, J., Iliuta, M. C., & Mercier, G. (2019) · Applied Clay Science · doi:10.1016/j.clay.2019.105286 · Cited by 27 · see citing works
Self-citationBreuil, C. D., Pasquier, L.-C., Dipple, G. M., Blais, J., Iliuta, M. C., & Mercier, G. (2019) · Minerals · doi:10.3390/min9110680 · Cited by 27 · see citing works
Self-citationRemoval of atmospheric CO2 by engineered soils in infrastructure projects
Jorat, M. E., Kraavi, K. E., & Manning, D. A. C. (2022) · Journal of Environmental Management · doi:10.1016/j.jenvman.2022.115016 · Cited by 25 · see citing works
Ahmed, A., & Hassan, Z. F. A. (2025) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2025.179544 · Cited by 24 · see citing works
Zheng, X., Ji, L., Liu, M., Zhai, H., Li, K., He, Q., & Yan, S. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.148037 · Cited by 24 · see citing works
Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production
Sierra, C., Chouinard, S., Pasquier, L.-C., Mercier, G., & Blais, J.-F. (2017) · Waste and Biomass Valorization · doi:10.1007/s12649-017-9926-9 · Cited by 24 · see citing works
Self-citationMilani, D., McDonald, R., Fawell, P. D., Weldekidan, H., Puxty, G., & Feron, P. H. M. (2024) · Minerals Engineering · doi:10.1016/j.mineng.2024.109124 · Cited by 23 · see citing works
Kinetic study of high-pressure acid leaching of Mg and Ni from serpentine
Wu, L., Yang, X.-Y., Xu, H. X., Zhong, Z.-J., & Wang, X. (2022) · Journal of Central South University · doi:10.1007/s11771-022-4912-1 · Cited by 23 · see citing works
Tebbiche, I., Pasquier, L.-C., Mercier, G., Blais, J.-F., & Kentish, S. E. (2021) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2021.06.002 · Cited by 22 · see citing works
Self-citationBenhelal, E., Oliver, T. K., Farhang, F., Hook, J. M., Rayson, M. S., Brent, G. F., Stockenhuber, M., & Kennedy, E. M. (2019) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.9b04379 · Cited by 22 · see citing works
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Jorat, M. E., Aziz, M. A., Marto, A., Zaini, N., Jusoh, S. N., & Manning, D. A. C. (2018) · Geosciences · doi:10.3390/geosciences8120483 · Cited by 19 · see citing works
Activation methods for enhancing CO2 mineralization via mine tailings—A critical review
Norouzpour, M., Santos, R. M., & Chiang, Y. W. (2025) · Carbon Capture Science & Technology · doi:10.1016/j.ccst.2025.100430 · Cited by 17 · see citing works
Carbon Dioxide Fixation via the Synthesis of Sodium Ethyl Carbonate in NaOH-Dissolved Ethanol
Han, S., & Wee, J. (2016) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6b03250 · Cited by 16 · see citing works
Industrial symbiosis: Boron waste valorization through CO2 utilization
Çopur, M., Pekdemir, T., Kocakerìm, M. M., Korucu, H., & Guliyev, R. (2022) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-022-1192-2 · Cited by 15 · see citing works
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Oliver, T. K., Farhang, F., Hodgins, T. W., Rayson, M. S., Brent, G. F., Molloy, T. S., Stockenhuber, M., & Kennedy, E. M. (2018) · Energy & Fuels · doi:10.1021/acs.energyfuels.8b02823 · Cited by 15 · see citing works
Growth of carbon structures on chrysotile surface for organic contaminants removal from wastewater
Lemos, B. R. S., Soares, É. A. R., Teixeira, A. P. D. C., Ardisson, J. D., Fernandez-Outon, L. E., Amorim, C. C., Lago, R. M., & Moura, F. C. C. (2016) · Chemosphere · doi:10.1016/j.chemosphere.2016.06.022 · Cited by 14 · see citing works
Chen, Y., Yang, X., Wu, L., Tong, L., & Zhu, J. (2023) · Minerals · doi:10.3390/min13030318 · Cited by 13 · see citing works
Rausis, K., & Ćwik, A. (2020) · Applied Geochemistry · doi:10.1016/j.apgeochem.2020.104851 · Cited by 13 · see citing works
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Fara, A. A., Rayson, M. R., Brent, G. F., Oliver, T. K., Stockenhuber, M., & Kennedy, E. M. (2019) · Environmental Progress & Sustainable Energy · doi:10.1002/ep.13244 · Cited by 10 · see citing works
Tebbiche, I., Pasquier, L.-C., Mercier, G., Blais, J.-F., & Kentish, S. E. (2020) · Hydrometallurgy · doi:10.1016/j.hydromet.2020.105391 · Cited by 9 · see citing works
Self-citationReynes, J. F., Mercier, G., Blais, J.-F., & Pasquier, L.-C. (2023) · Dalton Transactions · doi:10.1039/d3dt00563a · Cited by 9 · see citing works
Self-citationRausis, K., Ćwik, A., & Casanova, I. (2020) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2020.103114 · Cited by 9 · see citing works
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Landry, M., Larachi, F., & González, P. (2024) · Carbon Capture Science & Technology · doi:10.1016/j.ccst.2024.100299 · Cited by 7 · see citing works
Al-Azani, K. H., Rezk, M. G., & Ibrahim, A. F. (2025) · Scientific Reports · doi:10.1038/s41598-025-32469-x · Cited by 6 · see citing works
Zhu, P., Xia, B., Li, H., Liu, H., & Qian, G. (2020) · Environmental Engineering Science · doi:10.1089/ees.2020.0105 · Cited by 6 · see citing works
Samputu, I., Radfarnia, H. R., & Zanganeh, K. E. (2025) · ACS Omega · doi:10.1021/acsomega.5c06358 · Cited by 4 · see citing works
Guermech, S., Mocellin, J., Tebbiche, I., Tran, L. H., Mercier, G., & Pasquier, L.-C. (2022) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.1c04560 · Cited by 4 · see citing works
Self-citationÇopur, M., Şenol, A. M., Pekdemir, T., & Onganer, Y. (2023) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.3c01095 · Cited by 4 · see citing works
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Guermech, S., Tebbiche, I., Tran, L. H., Mocellin, J., Mercier, G., & Pasquier, L.-C. (2025) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.4c00707 · Cited by 3 · see citing works
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Abidoye, L. K., & Oladipo, H. B. (2022) · Advances in Geological and Geotechnical Engineering Research · doi:10.30564/agger.v4i2.4465 · Cited by 3 · see citing works
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Худякова, Л. И., Кислов, Е. В., Paleev, P. L., & Малышев, А. В. (2020) · Bulletin of the Tomsk Polytechnic University Geo Assets Engineering · doi:10.18799/24131830/2020/8/2769 · Cited by 2 · see citing works
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Iozzia, M. L., Casu, A., Calloni, A., Hallqvist, C. P., Locarno, S. A., Gatta, G. D., Comboni, D., Bonizzoni, L., Vecchi, R., Bassi, A. L., et al. (2026) · Energy & Fuels · doi:10.1021/acs.energyfuels.6c01123 · Cited by 1 · see citing works
Abidoye, L. K., & Oladipo, H. B. (2021) · Research Square · doi:10.21203/rs.3.rs-699283/v1
Известия Томского политехнического университета. Инжиниринг георесурсов. Т. 331, № 8
(2020) · Bulletin of the Tomsk Polytechnic University Geo Assets Engineering · doi:10.18799/24131830/2020/8
Mouedhen, I. (2015) · EspaceINRS (National Institute for Scientific Research (Canada))
Development of a Continuous High-Pressure CO2 to Precipitated Calcium Carbonate Reactor
Noh, M. G. M., Yuhana, N. Y., Onn, M. S., Sanom, R. B., Isa, M. A., Shaharuddin, A. S., & bin Jumali, M. H. (2026) · Sustainability · doi:10.3390/su18041795
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Shahriari, L., Antonson, T., Han, S. E., Han, S. M., Hojati, M., & Kim, S. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.173601
Elaboration de membranes mixtes polymère / réseau métallo-organique pour l'élimination du CO2
Bouillon, J. (2021) · theses.fr (ABES) · doi:10.70675/a1a5377dz30faz41a0zbcc1za4fc39ac84c3
- Authors
- Pasquier, L.-C., Mercier, G., Blais, J.-F., Cecchi, E., & Kentish, S.
- Affiliations
- Institut National de la Recherche Scientifique (CA)
- The University of Melbourne (AU)
- Corresponding author
- Blais, Jean-François
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-08
- Volume
- 48
- Issue
- 9
- Pages
- 5163-5170
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2314316515
- Cited by
- 80
- References
- 48
- Citations by year
- 2026: 3 · 2025: 12 · 2024: 5 · 2023: 7 · 2022: 8 · 2021: 5 · 2020: 12 · 2019: 8 · 2018: 7 · 2017: 4 · 2016: 5 · 2015: 2 · 2014: 2
- FWCI
- 3.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- EspaceINRS (National Institute for Scientific Research (Canada)) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- CO2 mineralization, serpentinite, CO2 sequestration, flue gas, reaction mechanism, CO2 solubility, magnesium leaching, dissolution rate, greenhouse gas emissions reduction, mining waste
- MeSH terms
- Carbon Dioxide, Cold Temperature, Gases, Hot Temperature, Microscopy, Electron, Scanning, Minerals, Mining, Pressure, Water, Asbestos, Serpentine
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