The DOI matches its Crossref record.
Sequestration of Hydrophobic Organic Contaminants by Geosorbents
Abstract
The chemical interactions of hydrophobic organic contaminants (HOCs) with soils and sediments (geosorbents) may result in strong binding and slow subsequent release rates that significantly affect remediation rates and endpoints. The underlying physical and chemical phenomena potentially responsible for this apparent sequestration of HOCs by geosorbents are not well understood. This challenges our concepts for assessing exposure and toxicity and for setting environmental quality criteria. Currently there are no direct observational data revealing the molecular-scale locations in which nonpolar organic compounds accumulate when associated with natural soils or sediments. Hence macroscopic observations are used to make inferences about sorption mechanisms and the chemical factors affecting the sequestration of HOCs by geosorbents. Recent observations suggest that HOC interactions with geosorbents comprise different inorganic and organic surfaces and matrices, and distinctions may be drawn along these lines, particularly with regard to the roles of inorganic micropores, natural sorbent organic matter components, combustion residue particulate carbon, and spilled organic liquids. Certain manipulations of sorbates or sorbent media may help reveal sorption mechanisms, but mixed sorption phenomena complicate the interpretation of macroscopic data regarding diffusion of HOCs into and out of different matrices and the hysteretic sorption and aging effects commonly observed for geosorbents. Analytical characterizations at the microscale, and mechanistic models derived therefrom, are needed to advance scientific knowledge of HOC sequestration, release, and environmental risk.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Pignatello, J. J., Oliveros, E., & MacKay, A. (2006) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380500326564 · Cited by 4,133
Self-citationPresent and long-term composition of MSW landfill leachate: a review
Kjeldsen, P., Barlaz, M. A., Rooker, A. P., Baun, A., Ledin, A., & Christensen, T. H. (2002) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380290813462 · Cited by 2,522
Biogeochemistry of landfill leachate plumes
Christensen, T. H., Kjeldsen, P., Bjerg, P. L., Jensen, D. L., Christensen, J. B., Baun, A., Albrechtsen, H.-J., & Heron, G. (2001) · Applied Geochemistry · doi:10.1016/s0883-2927(00)00082-2 · Cited by 1,382
Adsorption behavior of organic pollutants on microplastics
Fu, L., Li, J., Wang, G., Luan, Y., & Dai, W. (2021) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2021.112207 · Cited by 932
Kookana, R. S., Sarmah, A. K., Van Zwieten, L., Krull, E., & Singh, B. (2011) · Advances in agronomy · doi:10.1016/b978-0-12-385538-1.00003-2 · Cited by 712
Pesticide soil sorption parameters: theory, measurement, uses, limitations and reliability
Wauchope, R. D., Yeh, S., Linders, J. B. H. J., Kloskowski, R., Tanaka, K., Rubin, B., Katayama, A., Kördel, W., Gerstl, Z., Lane, M., et al. (2002) · Pest Management Science · doi:10.1002/ps.489 · Cited by 593
Rodrigues, J. P., Duarte, A. C., Santos-Echeandía, J., & Rocha-Santos, T. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.11.038 · Cited by 491
Suspended Particles: Their Role in Estuarine Biogeochemical Cycles
Turner, A., & Millward, G. E. (2002) · Estuarine, Coastal and Shelf Science · doi:10.1006/ecss.2002.1033 · Cited by 462
Guelfo, J. L., & Higgins, C. P. (2013) · Environmental Science & Technology · doi:10.1021/es3048043 · Cited by 436
Huang, W., Peng, P., Yu, Z., & Fu, J. (2003) · Applied Geochemistry · doi:10.1016/s0883-2927(02)00205-6 · Cited by 435
Interactive Priming of Biochar and Labile Organic Matter Mineralization in a Smectite-Rich Soil
Keith, A., Singh, B., & Singh, B. P. (2011) · Environmental Science & Technology · doi:10.1021/es202186j · Cited by 343
The way forward in biochar research: targeting trade‐offs between the potential wins
Jeffery, S., Bezemer, T. M., Cornelissen, G., Kuyper, T. W., Lehmann, J., Mommer, L., Sohi, S. P., van de Voorde, T. F. J., Wardle, D. A., & van Groenigen, J. W. (2015) · GCB Bioenergy · doi:10.1111/gcbb.12132 · Cited by 305
Effect of solution chemistry on the adsorption of perfluorooctane sulfonate onto mineral surfaces
Tang, C. Y., Shiang Fu, Q., Gao, D., Criddle, C. S., & Leckie, J. O. (2010) · Water Research · doi:10.1016/j.watres.2010.01.038 · Cited by 284
Surface area and porosity of primary silicate minerals
Brantley, S. L., & Mellott, N. P. (2000) · American Mineralogist · doi:10.2138/am-2000-11-1220 · Cited by 282
Kookana, R. S. (2010) · Soil Research · doi:10.1071/sr10007 · Cited by 280
Comprehensive retention model for PFAS transport in subsurface systems
Brusseau, M. L., Yan, N., Van Glubt, S., Wang, Y., Chen, W., Lyu, Y., Dungan, B., Carroll, K. C., & Holguin, F. O. (2019) · Water Research · doi:10.1016/j.watres.2018.10.035 · Cited by 232
Self-citationLi, F., Zhang, C., Qu, Y., Chen, J., Chen, L., Liu, Y., & Zhou, Q. (2010) · Science of The Total Environment · doi:10.1016/j.scitotenv.2009.10.032 · Cited by 191
Kariyawasam, T., Doran, G. S., Howitt, J. A., & Prenzler, P. D. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2021.132981 · Cited by 103
Fossil Lipids for Life-Detection: A Case Study from the Early Earth Record
Eigenbrode, J. L. (2008) · Space Science Reviews · doi:10.1007/s11214-007-9252-9 · Cited by 79
Zhang, T., Sun, H., Gerecke, A. C., Kannan, K., Müller, C. E., & Alder, A. C. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2010.05.061 · Cited by 60
Organic carbon and salinity affect desorption of PFAS from estuarine sediments
Navarro, D. A., Oliver, D. P., Simpson, S. L., & Kookana, R. S. (2022) · Journal of Soils and Sediments · doi:10.1007/s11368-022-03172-5 · Cited by 42
Metadata
- Authors
- Luthy, R. G., Aiken, G. R., Brusseau, M. L., Cunningham, S. D., Gschwend, P. M., Pignatello, J. J., Reinhard, M., Traina, S. J., Weber, W. J., & Westall, J. C.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-11-26
- Volume
- 31
- Issue
- 12
- Pages
- 3341-3347
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2034953653
- Cited by
- 1,037
- References
- 0
- FWCI
- 26.59
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
