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Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters

Pratt, Russell C., Lohmeijer, Bas G. G., Long, David A., Waymouth, Robert M., Hedrick, James L.·2006·Journal of the American Chemical Society

Abstract

1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) is an effective organocatalyst for acyl transfer as well as the ring-opening polymerization of cyclic esters. Its high activity is attributed to its ability to simultaneously activate both esters and alcohols, as demonstrated in a model reaction. This unique mechanism makes TBD a remarkably simple example of a bifunctional catalyst. The simplicity of the reaction conditions, the ready commercial availability of the catalyst, and its high activity provide an accessible methodology to allow future studies of tailor-made polyesters.

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Research works printed but not linked: 22

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Cited by

Metadata

Authors
Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Waymouth, R. M., & Hedrick, J. L.
Venue
Journal of the American Chemical Society
Published
2006-03-17
Volume
128
Issue
14
Pages
4556-4557
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2004350652
Cited by
543
References
2
FWCI
10.65
Type
journal article
Language
en
Open access
closed

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