Synthesis of Poly(lactide)s with Modified Thermal and Mechanical Properties
Abstract
The use of poly(lactide)‐based materials is, in part, limited by their physical and mechanical properties. This article reviews the methods that have been employed to enable enhancement of the materials properties through synthetic manipulation of the polymer structure including block copolymer synthesis and modification of the lactide monomer structure, focusing on the application of ring‐opening polymerization. In turn the effect of these structural modifications on the properties of the resultant materials are reported. magnified image
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PLA exhibits high strength and poor toughness, while PCL exhibits good toughness and low strength.
“However, PLA exhibits high strength and poor toughness, while PCL exhibits good toughness and low strength [11,12,13].”
From Synthesis of Poly(l-lactide-co-ε-caprolactone) Copolymer: Structure, Toughness, and Elasticity (2021) · cites this paper as [12]
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- Authors
- Becker, J. M., Pounder, R. J., & Dove, A. P.
- Affiliations
- University of Warwick (GB)
- Corresponding author
- Dove, Andrew P.
- ORCID
- Dove, Andrew P.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2010-11-09
- Volume
- 31
- Issue
- 22
- Pages
- 1923-1937
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2013584225
- Semantic Scholar
- 5119163962a6cf66b8cd586fcec570035101d432
- Cited by
- 146
- References
- 90
- Citations by year
- 2026: 1 · 2025: 5 · 2024: 6 · 2023: 10 · 2022: 9 · 2021: 9 · 2020: 2 · 2019: 12 · 2018: 12 · 2017: 5 · 2016: 13 · 2015: 9 · 2014: 16 · 2013: 14 · 2012: 17
- FWCI
- 4.88
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Keywords
- polylactic acid, ring-opening polymerization, block copolymers, polymer structure-property relationships, thermal properties, mechanical properties, biodegradable polymers
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