The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2 Reduction Catalyst
Abstract
There is considerable interest in both catalysts for CO(2) conversion and understanding how CO(2) reacts with transition metal complexes. Here we develop a simple model for predicting the thermodynamic favorability of CO(2) insertion into Ir(III) hydrides. In general this reaction is unfavorable; however, we demonstrate that with a hydrogen bond donor in the secondary coordination sphere it is possible to isolate a formate product from this reaction. Furthermore, our CO(2) inserted product is one of the most active water-soluble catalysts reported to date for CO(2) hydrogenation.
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Metadata
- Authors
- Schmeier, T. J., Dobereiner, G. E., Crabtree, R. H., & Hazari, N.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-01
- Volume
- 133
- Issue
- 24
- Pages
- 9274-9277
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2087081982
- Cited by
- 438
- References
- 18
- FWCI
- 15.23
- Type
- journal article
- Language
- en
- Open access
- closed
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