The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes
Abstract
Iridium dihydride complexes supported by PCP-type pincer ligands rapidly insert CO(2) to yield κ(2)-formate monohydride products in THF. In acetonitrile/water mixtures, these complexes become efficient and selective catalysts for electrocatalytic reduction of CO(2) to formate. Electrochemical and NMR spectroscopic studies have provided mechanistic details and structures of key intermediates.
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Metadata
- Authors
- Kang, P., Cheng, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-14
- Volume
- 134
- Issue
- 12
- Pages
- 5500-5503
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1965587829
- Cited by
- 330
- References
- 30
- FWCI
- 9.60
- Type
- journal article
- Language
- en
- Open access
- closed
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