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Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction

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Liang, Hai-Wei, Wei, Wei, Wu, Zhong-Shuai, Feng, Xinliang, Müllen, Klaus·2013·Journal of the American Chemical Society

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Abstract

A family of mesoporous nonprecious metal (NPM) catalysts for oxygen reduction reaction (ORR) in acidic media, including cobalt-nitrogen-doped carbon (C-N-Co) and iron-nitrogen-doped carbon (C-N-Fe), was prepared from vitamin B12 (VB12) and the polyaniline-Fe (PANI-Fe) complex, respectively. Silica nanoparticles, ordered mesoporous silica SBA-15, and montmorillonite were used as templates for achieving mesoporous structures. The most active mesoporous catalyst was fabricated from VB12 and silica nanoparticles and exhibited a remarkable ORR activity in acidic medium (half-wave potential of 0.79 V, only ∼58 mV deviation from Pt/C), high selectivity (electron-transfer number >3.95), and excellent electrochemical stability (only 9 mV negative shift of half-wave potential after 10,000 potential cycles). The unprecedented performance of these NPM catalysts in ORR was attributed to their well-defined porous structures with a narrow mesopore size distribution, high Brunauer-Emmett-Teller surface area (up to 572 m(2)/g), and homogeneous distribution of abundant metal-Nx active sites.

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Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
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Authors: Liang, H.-W., Wei, W., Wu, Z.-S., Feng, X., & Müllen, K.
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2013-10-17
Volume: 135
Issue: 43
Pages: 16002-16005
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja407552k
OpenAlex: W1964442294
Cited by: 1,205
References: 31
FWCI: 35.11
Type: journal article
Language: en
Open access: green

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Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction

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