The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Yolk–Shell Structure of Polyaniline-Coated Sulfur for Lithium–Sulfur Batteries
Abstract
Lithium–sulfur batteries have attracted much attention in recent years due to their high theoretical capacity of 1672 mAh g(–1) and low cost. However, a rapid capacity fade is normally observed, attributed mainly to polysulfide dissolution and volume expansion. Although many strategies have been reported to prolong the cyclability, the high cost and complex preparation processes still hinder their practical application. Here, we report the synthesis of a polyaniline–sulfur yolk–shell nanocomposite through a heating vulcanization of a polyaniline–sulfur core–shell structure. We observed that this heating treatment was much more effective than chemical leaching to prepare uniform yolk–shell structures. Compared with its sulfur–polyaniline core–shell counterparts, the yolk–shell nanostructures delivered much improved cyclability owing to the presence of internal void space inside the polymer shell to accommodate the volume expansion of sulfur during lithiation. The yolk–shell material exhibited a stable capacity of 765 mAh g(–1) at 0.2 C after 200 cycles, representing a promising future for industrial scale Li–S batteries.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Nanostructured materials for advanced energy conversion and storage devices
Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005) · Nature Materials · doi:10.1038/nmat1368 · Cited by 8,826
Lithium Batteries and Cathode Materials
Whittingham, M. S. (2004) · Chemical Reviews · doi:10.1021/cr020731c · Cited by 6,267
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
Ji, X., Lee, K. T., & Nazar, L. F. (2009) · Nature Materials · doi:10.1038/nmat2460 · Cited by 5,988
Challenges and Prospects of Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., & Su, Y.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300179v · Cited by 2,380
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
Guo, Y., Hu, J., & Wan, L. (2008) · Advanced Materials · doi:10.1002/adma.200800627 · Cited by 2,223
Wang, H., Yang, Y., Liang, Y., Robinson, J. T., Li, Y., Jackson, A., Cui, Y., & Dai, H. (2011) · Nano Letters · doi:10.1021/nl200658a · Cited by 2,119
Wei Seh, Z., Li, W., Cha, J. J., Zheng, G., Yang, Y., McDowell, M. T., Hsu, P.-C., & Cui, Y. (2013) · Nature Communications · doi:10.1038/ncomms2327 · Cited by 2,107
Porous Hollow Carbon@Sulfur Composites for High‐Power Lithium–Sulfur Batteries
Jayaprakash, N., Shen, J., Moganty, S. S., Corona, A., & Archer, L. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100637 · Cited by 1,811
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
Kovalenko, I., Zdyrko, B., Magasinski, A., Hertzberg, B., Milicev, Z., Burtovyy, R., Luzinov, I., & Yushin, G. (2011) · Science · doi:10.1126/science.1209150 · Cited by 1,802
Cited by
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Designing high-energy lithium–sulfur batteries
Seh, Z. W., Sun, Y., Zhang, Q., & Cui, Y. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00410a · Cited by 2,573
A highly efficient polysulfide mediator for lithium–sulfur batteries
Liang, X., Hart, C., Pang, Q., Garsuch, A., Weiss, T., & Nazar, L. F. (2015) · Nature Communications · doi:10.1038/ncomms6682 · Cited by 2,062
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Powering Lithium–Sulfur Battery Performance by Propelling Polysulfide Redox at Sulfiphilic Hosts
Yuan, Z., Peng, H.-J., Hou, T.-Z., Huang, J.-Q., Chen, C.-M., Wang, D.-W., Cheng, X.-B., Wei, F., & Zhang, Q. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b04166 · Cited by 1,438
Designing polymers for advanced battery chemistries
Lopez, J., Mackanic, D. G., Cui, Y., & Bao, Z. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0103-6 · Cited by 894
Advances in Lithium–Sulfur Batteries: From Academic Research to Commercial Viability
Chen, Y., Wang, T., Tian, H., Su, D., Zhang, Q., & Wang, G. (2021) · Advanced Materials · doi:10.1002/adma.202003666 · Cited by 870
A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium–sulfur batteries
Li, Z., Zhang, J., Guan, B., Wang, D., Liu, L.-M., & Lou, X. W. (2016) · Nature Communications · doi:10.1038/ncomms13065 · Cited by 677
Polyaniline (PANi) based electrode materials for energy storage and conversion
Wang, H., Lin, J., & Shen, Z. X. (2016) · Journal of Science: Advanced Materials and Devices · doi:10.1016/j.jsamd.2016.08.001 · Cited by 631
Current Status and Future Prospects of Metal–Sulfur Batteries
Chung, S., & Manthiram, A. (2019) · Advanced Materials · doi:10.1002/adma.201901125 · Cited by 622
A novel synergistic composite with multi-functional effects for high-performance Li–S batteries
Li, Y.-J., Fan, J.-M., Zheng, M.-S., & Dong, Q.-F. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00104a · Cited by 600
He, J., Chen, Y., & Manthiram, A. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00893k · Cited by 565
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Progress in Mechanistic Understanding and Characterization Techniques of Li‐S Batteries
Xu, R., Lu, J., & Amine, K. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500408 · Cited by 507
Feng, J.-X., Tong, S.-Y., Tong, Y.-X., & Li, G.-R. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12968 · Cited by 489
Carbon nanomaterials for advanced lithium sulfur batteries
Xu, Z.-L., Kim, J.-K., & Kang, K. (2018) · Nano Today · doi:10.1016/j.nantod.2018.02.006 · Cited by 454
Kim, H., Lee, J., Ahn, H., Kim, O., & Park, M. J. (2015) · Nature Communications · doi:10.1038/ncomms8278 · Cited by 428
Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application
Yang, X., Li, X., Adair, K., Zhang, H., & Sun, X. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0010-3 · Cited by 411
Yang, X., Zhang, L., Zhang, F., Huang, Y., & Chen, Y. (2014) · ACS Nano · doi:10.1021/nn501284q · Cited by 396
Peng, H., Hou, T., Zhang, Q., Huang, J., Cheng, X., Guo, M., Yuan, Z., He, L., & Wei, F. (2014) · Advanced Materials Interfaces · doi:10.1002/admi.201400227 · Cited by 393
A review of recent developments in rechargeable lithium–sulfur batteries
Kang, W., Deng, N., Ju, J., Li, Q., Wu, D., Ma, X., Li, L., Naebe, M., & Cheng, B. (2016) · Nanoscale · doi:10.1039/c6nr04923k · Cited by 391
Zhou, W., Xiao, X., Cai, M., & Yang, L. (2014) · Nano Letters · doi:10.1021/nl502238b · Cited by 382
Self-citationSynthesis, stabilization and applications of 2-dimensional 1T metallic MoS 2
Shi, S., Sun, Z., & Hu, Y. H. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta08152b · Cited by 374
Zhang, Z., Peng, H., Zhao, M., & Huang, J. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201707536 · Cited by 357
A Revolution in Electrodes: Recent Progress in Rechargeable Lithium–Sulfur Batteries
Fang, X., & Peng, H. (2015) · Small · doi:10.1002/smll.201402354 · Cited by 346
Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries
Yu, S.-H., Feng, X., Zhang, N., Seok, J., & Abruña, H. D. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00487 · Cited by 334
Self-citationPang, Q., Liang, X., Kwok, C. Y., & Nazar, L. F. (2015) · Journal of The Electrochemical Society · doi:10.1149/2.0171514jes · Cited by 323
Wang, Z., Shen, J., Liu, J., Xu, X., Liu, Z., Hu, R., Yang, L., Feng, Y., Liu, J., Shi, Z., et al. (2019) · Advanced Materials · doi:10.1002/adma.201902228 · Cited by 309
Self-citationTwo‐dimensional MXenes for lithium‐sulfur batteries
Zhang, C. (., Cui, L., Abdolhosseinzadeh, S., & Heier, J. (2020) · InfoMat · doi:10.1002/inf2.12080 · Cited by 308
Nanostructured positive electrode materials for post-lithium ion batteries
Wang, F., Wu, X., Li, C., Zhu, Y., Fu, L., Wu, Y., & Liu, X. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02070d · Cited by 293
Cathode materials for lithium–sulfur batteries: a practical perspective
Eftekhari, A., & Kim, D.-W. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta00799j · Cited by 285
Durable Carbon-Coated Li2S Core–Shell Spheres for High Performance Lithium/Sulfur Cells
Nan, C., Lin, Z., Liao, H., Song, M.-K., Li, Y., & Cairns, E. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja412943h · Cited by 282
Du, D., Shi, W., Wang, L., & Zhang, J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.07.043 · Cited by 266
Metadata
- Authors
- Zhou, W., Yu, Y., Chen, H., DiSalvo, F. J., & Abruña, H. D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-23
- Volume
- 135
- Issue
- 44
- Pages
- 16736-16743
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1986195379
- Cited by
- 782
- References
- 39
- FWCI
- 51.12
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
