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Cited by 1,750

The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.

Langmuir−Blodgett Assembly of Graphite Oxide Single Layers

Cote, Laura J., Kim, Franklin, Huang, Jiaxing·2009·Journal of the American Chemical Society
DOI 10.1021/ja806262m
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Abstract

Single-layer graphite oxide can be viewed as an unconventional type of soft material and has recently been recognized as a promising material for composite and electronics applications. It is of both scientific curiosity and technical importance to know how these atomically thin sheets assemble. There are two fundamental geometries of interacting single layers: edge-to-edge and face-to-face. Such interactions were studied at the air-water interface by Langmuir-Blodgett assembly. Stable monolayers of graphite oxide single layers were obtained without the need for any surfactant or stabilizing agent, due to the strong electrostatic repulsion between the 2D confined layers. Such repulsion also prevented the single layers from overlapping during compression, leading to excellent reversibility of the monolayers. In contrast to molecular and hard colloidal particle monolayers, the single layers tend to fold and wrinkle at edges to resist collapsing into multilayers. The monolayers can be transferred to a substrate, readily creating a large area of flat graphite oxide single layers. The density of such films can be continuously tuned from dilute, close-packed to overpacked monolayers of interlocking single layers. For size-mismatched single layers, face-to-face interaction caused irreversible stacking, leading to double layers. The graphite oxide monolayers can be chemically reduced to graphene for electronic applications such as transparent conducting thin films.

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Crossref · 10.1021/ja806262m

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Cites

Show all 26 references

Research works printed but not linked: 8

  1. Hamley, I. W.Introduction to Soft Matter: Polymers, Colloids, Amphiphiles and Liquid Crystals,2nd ed.;Wiley:New York,2007; p340.
  2. Israelachvili, J. N.Intermolecular and Surface Forces,2nd ed.;Academic Press:San Diego,1992; p450.
  3. Sun F., 1996, J. Am. Chem. Soc., 118, 1856, 10.1021/ja952225t · doi:10.1021/ja952225t
  4. Reitzel N., 2000, J. Am. Chem. Soc., 122, 5788, 10.1021/ja9924501 · doi:10.1021/ja9924501
  5. Abraham F. F., 1992, Europhys. Lett., 19, 293, 10.1209/0295-5075/19/4/008 · doi:10.1209/0295-5075/19/4/008
  6. Hwa T., 1991, Phys. Rev. A, 44, R2235, 10.1103/PhysRevA.44.R2235 · doi:10.1103/physreva.44.r2235
  7. Lipp M. M., 1997, Rev. Sci. Instrum., 68, 2574, 10.1063/1.1148163 · doi:10.1063/1.1148163
  8. Ybert C., 2002, J. Phys. Chem. B, 106, 2004, 10.1021/jp013173z · doi:10.1021/jp013173z

Cited by

Metadata

Authors
Cote, L. J., Kim, F., & Huang, J.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2008-10-22
Volume
131
Issue
3
Pages
1043-1049
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja806262m
OpenAlex
W2085909317
Cited by
1,750
References
26
FWCI
34.86
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.