The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond
Abstract
Electrochemical reduction of CO2 is an attractive technique for reducing CO2 emission and converting it into useful chemicals, but it suffers from high overpotential, low efficiency or poor product selectivity. Here, N-doped nanodiamond/Si rod array (NDD/Si RA) was proposed as an efficient nonmetallic electrocatalyst for CO2 reduction. It preferentially and rapidly converted CO2 to acetate over formate with an onset potential of -0.36 V (vs RHE), overcoming the usual limitation of low selectivity for C2 products. Moreover, faradic efficiency of 91.2-91.8% has been achieved for CO2 reduction at -0.8 to -1.0 V. Its superior performance for CO2 reduction can be attributed to its high overpotential for hydrogen evolution and N doping, where N-sp(3)C species was highly active for CO2 reduction. Electrokinetic data and in situ infrared spectrum revealed the main pathway for CO2 reduction might be CO2 → CO2(•-) → (COO)2(•) → CH3COO(-).
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Cited by
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Metadata
- Authors
- Liu, Y., Chen, S., Quan, X., & Yu, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-04
- Volume
- 137
- Issue
- 36
- Pages
- 11631-11636
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2417598793
- Cited by
- 599
- References
- 8
- FWCI
- 11.83
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- National Natural Science Foundation of China (21437001)
- Ministry of Education of the People's Republic of China (PCSIRT_13R05)
- Ministry of Science and Technology of the People's Republic of China (2011CB936002)
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- Liu, Y., Chen, S., Quan, X., & Yu, H. (2015). Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b02975
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