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Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption

Feng, Jin-Xian, Wu, Jin-Qi, Tong, Ye-Xiang, Li, Gao-Ren·2018·Journal of the American Chemical Society

Abstract

Low-cost transition-metal dichalcogenides (MS 2 ) have attracted great interest as alternative catalysts for hydrogen evolution. However, a significant challenge is the formation of sulfur–hydrogen bonds on MS 2 (S–H ads ), which will severely suppress hydrogen evolution reaction (HER). Here we report Cu nanodots (NDs)-decorated Ni 3 S 2 nanotubes (NTs) supported on carbon fibers (CFs) (Cu NDs/Ni 3 S 2 NTs-CFs) as efficient electrocatalysts for HER in alkaline media. The electronic interactions between Cu and Ni 3 S 2 result in Cu NDs that are positively charged and can promote water adsorption and activation. Meanwhile, Ni 3 S 2 NTs are negatively charged and can weaken S–H ads bonds formed on catalyst surfaces. Therefore, the Cu/Ni 3 S 2 hybrids can optimize H adsorption and desorption on electrocatalysts and can promote both Volmer and Heyrovsky steps of HER. The strong interactions between Cu and Ni 3 S 2 cause the Cu NDs/Ni 3 S 2 NTs-CFs electrocatalysts to exhibit the outstanding HER catalytic performance with low onset potential, high catalytic activity, and excellent stability.

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Metadata

Authors
Feng, J.-X., Wu, J.-Q., Tong, Y.-X., & Li, G.-R.
Venue
Journal of the American Chemical Society
Published
2018-01-02
Volume
140
Issue
2
Pages
610-617
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2766144411
Cited by
671
References
10
FWCI
20.92
Type
journal article
Language
en
Open access
closed
Funders
  • Ministry of Education of the People's Republic of China (16lgjc67)
  • Ministry of Science and Technology of the People's Republic of China (2015CB932304, 2016YFA0202603)
  • National Natural Science Foundation of China (91645104)
  • Natural Science Foundation of Guangdong Province (2016A010104004, 2017A010103007)
  • Guangzhou Municiplity (201704030019)

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CoChat. (2026). Citation check: Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption. https://app.cochat.ai/papers/10.1021/jacs.7b08521
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Feng, J.-X., Wu, J.-Q., Tong, Y.-X., & Li, G.-R. (2018). Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b08521

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