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Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption
Abstract
Low-cost transition-metal dichalcogenides (MS 2 ) have attracted great interest as alternative catalysts for hydrogen evolution. However, a significant challenge is the formation of sulfur–hydrogen bonds on MS 2 (S–H ads ), which will severely suppress hydrogen evolution reaction (HER). Here we report Cu nanodots (NDs)-decorated Ni 3 S 2 nanotubes (NTs) supported on carbon fibers (CFs) (Cu NDs/Ni 3 S 2 NTs-CFs) as efficient electrocatalysts for HER in alkaline media. The electronic interactions between Cu and Ni 3 S 2 result in Cu NDs that are positively charged and can promote water adsorption and activation. Meanwhile, Ni 3 S 2 NTs are negatively charged and can weaken S–H ads bonds formed on catalyst surfaces. Therefore, the Cu/Ni 3 S 2 hybrids can optimize H adsorption and desorption on electrocatalysts and can promote both Volmer and Heyrovsky steps of HER. The strong interactions between Cu and Ni 3 S 2 cause the Cu NDs/Ni 3 S 2 NTs-CFs electrocatalysts to exhibit the outstanding HER catalytic performance with low onset potential, high catalytic activity, and excellent stability.
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Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
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Metadata
- Authors
- Feng, J.-X., Wu, J.-Q., Tong, Y.-X., & Li, G.-R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-01-02
- Volume
- 140
- Issue
- 2
- Pages
- 610-617
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2766144411
- Cited by
- 671
- References
- 10
- FWCI
- 20.92
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- Ministry of Education of the People's Republic of China (16lgjc67)
- Ministry of Science and Technology of the People's Republic of China (2015CB932304, 2016YFA0202603)
- National Natural Science Foundation of China (91645104)
- Natural Science Foundation of Guangdong Province (2016A010104004, 2017A010103007)
- Guangzhou Municiplity (201704030019)
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- Feng, J.-X., Wu, J.-Q., Tong, Y.-X., & Li, G.-R. (2018). Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b08521
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