Cosorption of Phenanthrene and Mercury(II) from Aqueous Solution by Soybean Stalk-Based Biochar
Abstract
Soybean [Glycine max (L.) Merr.] stalk-based biochar was prepared using oxygen-limited pyrolysis. We evaluated phenanthrene (PHE) and Hg(II) sorption, from single and binary component solutions, onto prepared biochar. We found that the prepared biochar efficiently removed PHE and Hg(II) from aqueous solutions. The isotherms for PHE and Hg(II) sorption could be described using linear and Tóth models, respectively, both with high regression coefficients (R(2) > 0.995). When PHE and Hg(II) coexisted in an aqueous solution, we observed direct competitive sorption, each one suppressing another. Our results provide insight into the recycling of agricultural residues, and also a new application for removal of polycyclic aromatic hydrocarbons and heavy metals from contaminated water utilizing biochar from agricultural residue.
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Functional groups of biochar are involved in complex formation with Hg(II) when using soybean stalk biochar and with Cd(II) when using corn straw biochar.
“Similar mechanism was also shown by Kong etal. (2011) and Sun etal. (2014) in adsorbing Hg(II) using biochar derived from soybean stalk and adsorption of Cd(II) using biochar produced from corn straw.”
From Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater (2021) · cites this paper as Kong et al. (2011)
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- Authors
- Kong, H., He, J., Gao, Y., Wu, H., & Zhu, X.
- Affiliations
- Nanjing Agricultural University (CN)
- Nanjing Tech University (CN)
- Corresponding author
- Gao, Yanzheng
- Venue
- Journal of Agricultural and Food Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-10-21
- Volume
- 59
- Issue
- 22
- Pages
- 12116-12123
- ISSN
- 0021-8561 (ISSN-L)
- 1520-5118
- OpenAlex
- W270669537
- Cited by
- 214
- References
- 36
- Citations by year
- 2026: 5 · 2025: 11 · 2024: 13 · 2023: 19 · 2022: 31 · 2021: 23 · 2020: 24 · 2019: 20 · 2018: 15 · 2017: 15 · 2016: 7 · 2015: 9 · 2014: 6 · 2013: 9 · 2012: 7
- FWCI
- 6.84
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Agricultural and Food Chemistry (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- phenanthrene, mercury(II), soybean stalk, biochar, competitive adsorption, polycyclic aromatic hydrocarbons, heavy metal removal, adsorption isotherms, Toth model, contaminated water treatment
- MeSH terms
- Adsorption, Charcoal, Mercury, Phenanthrenes, Glycine max, Water Pollutants, Chemical, Plant Stems, Environmental Restoration and Remediation
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