Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2
Abstract
The addition of carbon dioxide to epoxides to produce either cyclic carbonates or polycarbonates is an important reaction allowing the conversion of a renewable, inexpensive and non-toxic feedstock such as CO2 into useful products with many potential applications. In this perspective article, an overview of the type of catalysts used for this reaction, the mechanisms with which they operate and the parameters influencing their activity and selectivity are presented and discussed critically. In this context, the main challenges to be tackled in this vibrant area of research are highlighted.
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The extent of 5CC formation depends on the nature of the epoxide, the catalyst, and the reaction conditions.
“The extent of this reaction depends on the nature of the epoxide, the catalyst, and the reaction conditions.83,361”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [361]
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Catalysis as an Enabling Science for Sustainable Polymers
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- Authors
- Pescarmona, P. P., & Taherimehr, M.
- Affiliations
- KU Leuven (BE)
- Corresponding author
- Pescarmona, Paolo P.
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 2
- Issue
- 11
- Pages
- 2169
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2026941394
- Cited by
- 392
- References
- 97
- Citations by year
- 2026: 16 · 2025: 23 · 2024: 25 · 2023: 22 · 2022: 22 · 2021: 24 · 2020: 26 · 2019: 36 · 2018: 34 · 2017: 23 · 2016: 34 · 2015: 45 · 2014: 43 · 2013: 17 · 2012: 1
- FWCI
- 16.24
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Science & Technology (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Keywords
- epoxide ring opening, carbon dioxide, cyclic carbonates, polycarbonate, CO2 utilization, heterogeneous catalysis, reaction mechanism, catalyst selectivity, catalytic activity, renewable raw materials
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