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A Microporous Metal−Organic Framework for Separation of CO2/N2 and CO2/CH4 by Fixed-Bed Adsorption
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A microporous MOF Zn(BDC)(4,4‘-Bipy) 0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4‘-Bipy = 4,4‘-bipyridine) was examined for the separation and removal of CO 2 from its binary CO 2 /N 2 and CO 2 /CH 4 and ternary CO 2 /CH 4 /N 2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 × 4.0 Å to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO 2 with the adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO 2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential applications in this very important industrial and environmental process.
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Self-citation
Metadata
- Authors
- Bastin, L., Bárcia, P. S., Hurtado, E. J., Silva, J. A. C., Rodrigues, A. E., & Chen, B.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-01-16
- Volume
- 112
- Issue
- 5
- Pages
- 1575-1581
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2006819285
- Cited by
- 442
- References
- 1
- FWCI
- 26.22
- Type
- journal article
- Language
- en
- Open access
- green
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