The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis
Abstract
Electrochemical conversion of CO 2 has been proposed both as a way to reduce CO 2 emissions and as a source of renewable fuels and chemicals, but conversion rates need improvement before the process will be practical. In this article, we show that the rate of CO 2 conversion per unit surface area is about 10 times higher on 5 nm silver nanoparticles than on bulk silver even though measurements on single crystal catalysts show much smaller variations in rate. The enhancement disappears on 1 nm particles. We attribute this effect to a volcano effect associated with changes of the binding energy of key intermediates as the particle size decreases. These results demonstrate that nanoparticle catalysts have unique properties for CO 2 conversion.
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Citations
Cites
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Cited by
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
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Metadata
- Authors
- Salehi-Khojin, A., Jhong, H.-R. M., Rosen, B. A., Zhu, W., Ma, S., Kenis, P. J. A., & Masel, R. I.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-17
- Volume
- 117
- Issue
- 4
- Pages
- 1627-1632
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2110045599
- Cited by
- 435
- References
- 13
- FWCI
- 6.68
- Type
- journal article
- Language
- en
- Open access
- closed
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