The DOI matches its Crossref record.
Comparison of the Photoelectronic and Photocatalytic Activities of Various Anatase and Rutile Forms of Titania in Pure Liquid Organic Phases and in Aqueous Solutions
Abstract
Various titania samples of industrial origin (Degussa and Tioxide) have been characterized by electrical photoconductance measurements and tested as photocatalysts in various liquid media (either pure organic liquids or aqueous solutions) as a function of their structure (anatase versus rutile). Anatase was constantly found more active than rutile, whatever the reaction chosen (mild oxidation of pure cyclohexane and 2-propanol; total degradation of phenol and nitrophenol isomers in water). In identical conditions, Degussa was found more active, but the intrinsic activity, expressed in moles converted per hour and per square meter of active surface, was found slightly higher for anatase Tioxide. The higher activity of anatase with respect to that of rutile could be explained by the interpretation of the photoconductance measurements, which evidence the higher aptitude of anatase (i) to photoadsorb oxygen, in O 2 - and O - forms; (ii) to photodesorb it; and (iii) to have a lower relative electron−hole recombination rate. The origin of the differences in the photocatalytic behavior of titania leading to mild oxidation in pure liquid organic phase and total oxidative degradation in aqueous medium is also analyzed.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
A review on the visible light active titanium dioxide photocatalysts for environmental applications
Pelaez, M., Nolan, N. T., Pillai, S. C., Seery, M. K., Falaras, P., Kontos, A. G., Dunlop, P. S. M., Hamilton, J. W. J., Byrne, J. A., O'Shea, K., et al. (2012) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2012.05.036 · Cited by 4,047
Review of the anatase to rutile phase transformation
Hanaor, D. A. H., & Sorrell, C. C. (2011) · Journal of Materials Science · doi:10.1007/s10853-010-5113-0 · Cited by 3,394
A surface science perspective on TiO2 photocatalysis
Henderson, M. A. (2011) · Surface Science Reports · doi:10.1016/j.surfrep.2011.01.001 · Cited by 2,038
Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO 2 Using EPR
Hurum, D. C., Agrios, A. G., Gray, K. A., Rajh, T., & Thurnauer, M. C. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp0273934 · Cited by 2,015
Zhang, J., Zhou, P., Liu, J., & Yu, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp02201g · Cited by 1,359
The thermodynamic scale of inorganic crystalline metastability
Sun, W., Dacek, S. T., Ong, S. P., Hautier, G., Jain, A., Richards, W. D., Gamst, A. C., Persson, K. A., & Ceder, G. (2016) · Science Advances · doi:10.1126/sciadv.1600225 · Cited by 961
Recent advances in photocatalysis for environmental applications
Byrne, C., Subramanian, G., & Pillai, S. C. (2018) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2017.07.080 · Cited by 820
Fadeel, B., & Garcia-Bennett, A. E. (2010) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2009.11.008 · Cited by 783
Photocatalysts with internal electric fields
Li, L., Salvador, P. A., & Rohrer, G. S. (2014) · Nanoscale · doi:10.1039/c3nr03998f · Cited by 774
Composite Titanium Dioxide Nanomaterials
Dahl, M., Liu, Y., & Yin, Y. (2014) · Chemical Reviews · doi:10.1021/cr400634p · Cited by 687
Hydrothermal synthesis of nanosized anatase and rutile TiO2 using amorphous phase TiO2
Yin, H., Wada, Y., Kitamura, T., Kambe, S., Murasawa, S., Mori, H., Sakata, T., & Yanagida, S. (2001) · Journal of Materials Chemistry · doi:10.1039/b008974p · Cited by 572
Reaction of O 2 with Subsurface Oxygen Vacancies on TiO 2 Anatase (101)
Setvín, M., Aschauer, U., Scheiber, P., Li, Y.-F., Hou, W., Schmid, M., Selloni, A., & Diebold, U. (2013) · Science · doi:10.1126/science.1239879 · Cited by 565
Chemical oxidation and DNA damage catalysed by inorganic sunscreen ingredients
Dunford, R., Salinaro, A., Cai, L., Serpone, N., Horikoshi, S., Hidaka, H., & Knowland, J. (1997) · FEBS Letters · doi:10.1016/s0014-5793(97)01356-2 · Cited by 540
Testino, A., Bellobono, I. R., Buscaglia, V., Canevali, C., D'Arienzo, M., Polizzi, S., Scotti, R., & Morazzoni, F. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067050+ · Cited by 450
Vu, N., Kaliaguine, S., & Do, T. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201901825 · Cited by 445
Niederberger, M., Bartl, M. H., & Stucky, G. D. (2002) · Chemistry of Materials · doi:10.1021/cm021203k · Cited by 419
Treatment of textile dyehouse wastewater by TiO2 photocatalysis
Pekakis, P. A., Xekoukoulotakis, N. P., & Mantzavinos, D. (2006) · Water Research · doi:10.1016/j.watres.2006.01.019 · Cited by 391
Selective organic transformations on titanium oxide-based photocatalysts
Shiraishi, Y., & Hirai, T. (2008) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2008.05.001 · Cited by 353
Le Bahers, T., Rérat, M., & Sautet, P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp409724c · Cited by 319
Hapeshi, E., Achilleos, A., Vasquez, M. I., Michael, C., Xekoukoulotakis, N. P., Mantzavinos, D., & Kassinos, D. (2010) · Water Research · doi:10.1016/j.watres.2009.11.044 · Cited by 302
HOU, Y., WU, L., WANG, X., DING, Z., LI, Z., & FU, X. (2007) · Journal of Catalysis · doi:10.1016/j.jcat.2007.05.012 · Cited by 285
Lin, J., & Yu, J. C. (1998) · Journal of Photochemistry and Photobiology A: Chemistry · doi:10.1016/s1010-6030(98)00289-5 · Cited by 278
Electron–Hole Recombination Time at TiO2 Single-Crystal Surfaces: Influence of Surface Band Bending
Ozawa, K., Emori, M., Yamamoto, S., Yukawa, R., Yamamoto, S., Hobara, R., Fujikawa, K., Sakama, H., & Matsuda, I. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz500770c · Cited by 277
Commonly used UV filter toxicity on biological functions: review of last decade studies
Gilbert, E., Pirot, F., Bertholle, V., Roussel, L., Falson, F., & Padois, K. (2013) · International Journal of Cosmetic Science · doi:10.1111/ics.12030 · Cited by 150
Metadata
- Authors
- Sclafani, A., & Herrmann, J. M.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 100
- Issue
- 32
- Pages
- 13655-13661
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2080248473
- Cited by
- 589
- References
- 0
- FWCI
- 8.05
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
