Improved Photovoltaic Properties of Donor–Acceptor Copolymers by Introducing Quinoxalino[2,3-b′]porphyrin as a Light-Harvesting Unit

Wang, Liwei; Shi, Shaowei; Ma, Di; Chen, Song; Gao, Chen; Wang, Meng; Shi, Keli; Li, Yongfang; Li, Xiaoyu; Wang, Haiqiao

doi:10.1021/ma502050b

Cited by 39Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchPhotodynamic Therapy Research Studies

Improved Photovoltaic Properties of Donor–Acceptor Copolymers by Introducing Quinoxalino[2,3-b′]porphyrin as a Light-Harvesting Unit

Wang, Liwei, Shi, Shaowei, Ma, Di, Chen, Song, Gao, Chen, Wang, Meng, Shi, Keli, Li, Yongfang +2 more·2015·Macromolecules

DOI 10.1021/ma502050b

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Abstract

Donor–acceptor (D–A) copolymerization is an effective approach to construct low bandgap polymers with tunable electronic energy levels for the application as donor materials in polymer solar cells (PSCs). Usually, D–A copolymers possess an intramolecular charge transfer absorption band at long wavelength direction, so that the absorption of the polymers is broadened. However, absorption at short wavelength direction is also important and should be broadened and enhanced to increase the short-circuit current density ( J sc ) of the PSCs. In this study, a series of low bandgap conjugated polymers, P(QP4-BT-DPP1), P(QP1-BT-DPP1), and P(QP1-BT-DPP4), based on two acceptor units quinoxalino[2,3- b ′]porphyrin (QP) and diketopyrrolopyrrole (DPP) connected by oligothiophene donor units, were designed and synthesized by palladium-catalyzed Stille-coupling polymerization. As a complementary light-harvesting unit, QP was first introduced into the D–A conjugated polymers for improving the photovoltaic performance of PSCs. The incorporation of QP broadened and enhanced the absorptions of short wavelength photons as well as kept the well-tuned electronic energy levels and bandgap of the pristine D–A copolymer. Moreover, para-linked QP improved coplanarity and extended π-conjugation along the polymer backbone. As a result, P(QP1-BT-DPP4) with a proper feed ratio (10 mol %) of QP showed an increased J sc of 11.85 mA/cm 2 without sacrificing open-circuit voltage ( V oc ) or fill factor (FF)…

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A36 with a high DPP ratio showed a higher performance (PCE = 5.07%) because of a high Jsc of 11.85 mA cm-2 resulting from its excellent absorption.
“A36 with a high DPP ratio showed a higher performance (PCE ¼ 5.07%) because of a high J sc of 11.85 mA cm 2 which resulted from its excellent absorption.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [43]
The different performances of these polymers are also related to crystallinity, and an increase of the QP ratio leads to a less ordered structure because of the hindrance of the bulky QP unit.
“In addition, the di ff erent performances of these polymers are also related to the crystallinity, and the increase of the ratio of QP leads to a less ordered structure because of the hindrance of the bulky QP unit.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [43]
A36 with just one QP unit shows a sharper diffraction peak as an indicator of a highly crystalline blend film.
“A36 with just one QP unit shows a sharper di ff raction peak as an indicator of a highly crystalline blend  lm.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [43]
A34 with a high ratio of quinoxalino[2,3b]porphyrin showed an inferior performance that can be explained by weak absorption and a large band-gap.
“A34 with a high ratio of quinoxalino[2,3b ]porphyrin (QP) showed an inferior performance that can be explained by the weak absorption and large band-gap. 43”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [43]
They synthesized three polymers A34-A36 by Stille coupling polymerization and used them as donors with PC71BM in BHJ OSCs.
“They synthesized three polymers ( A34 -A36 , Fig. 6) by Stille coupling polymerization and used them as donors with PC71BM in BHJ OSCs.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [43]

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Authors: Wang, L., Shi, S., Ma, D., Chen, S., Gao, C., Wang, M., Shi, K., Li, Y., Li, X., & Wang, H.
Affiliations: Beijing University of Chemical Technology (CN)
China Textile Academy (CN)
Chinese Academy of Sciences (CN)
Corresponding author: Li, Yongfang
Li, Xiaoyu
Wang, Haiqiao
ORCID: Wang, Liwei
Shi, Shaowei
Chen, Song
Gao, Chen
Wang, Meng
Shi, Keli
Li, Yongfang
Li, Xiaoyu
Wang, Haiqiao
Venue: Macromolecules
Publisher: American Chemical Society (ACS)
Published: 2014-12-19
Volume: 48
Issue: 1
Pages: 287-296
ISSN: 0024-9297 (ISSN-L)
1520-5835
DOI: 10.1021/ma502050b
OpenAlex: W1989160385
Cited by: 39
References: 39
Citations by year: 2021: 1 · 2020: 2 · 2019: 3 · 2018: 7 · 2017: 10 · 2016: 9 · 2015: 7
FWCI: 4.60
Type: journal article
Language: en
Open access: closed
Locations: Macromolecules (publishedVersion)
Funders: Ministry of Education of the People's Republic of China (20130010110006)
Natural Science Foundation of Beijing Municipality (2122047)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
Health Sciences › Medicine › Pulmonary and Respiratory Medicine › Photodynamic Therapy Research Studies
Keywords: donor-acceptor polymers, diketopyrrolopyrrole, oligothiophenes, polymer solar cells, short-wavelength absorption, Stille coupling polymerization, power conversion efficiency, short-circuit current density

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Improved Photovoltaic Properties of Donor–Acceptor Copolymers by Introducing Quinoxalino[2,3-b′]porphyrin as a Light-Harvesting Unit

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