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Raman Spectroscopy of Graphene Edges
Open accessAbstract
Graphene edges are of particular interest since their orientation determines the electronic properties. Here we present a detailed Raman investigation of graphene flakes with edges oriented at different crystallographic directions. We also develop a real space theory for Raman scattering to analyze the general case of disordered edges. The position, width, and intensity of G and D peaks are studied as a function of the incident light polarization. The D-band is strongest for polarization parallel to the edge and minimum for perpendicular. Raman mapping shows that the D peak is localized in proximity of the edge. For ideal edges, the D peak is zero for zigzag orientation and large for armchair, allowing in principle the use of Raman spectroscopy as a sensitive tool for edge orientation. However, for real samples, the D to G ratio does not always show a significant dependence on edge orientation. Thus, even though edges can appear macroscopically smooth and oriented at well-defined angles, they are not necessarily microscopically ordered.
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Metadata
- Authors
- Casiraghi, C., Hartschuh, A., Qian, H., Piscanec, S., Georgi, C., Fasoli, A., Novoselov, K. S., Basko, D. M., & Ferrari, A. C.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-16
- Volume
- 9
- Issue
- 4
- Pages
- 1433-1441
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2153110626
- Cited by
- 1,056
- References
- 4
- FWCI
- 37.80
- Type
- journal article
- Language
- en
- Open access
- green
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