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The Behavior of Mixed Ca–Mn Carbonates in Water and Seawater: Controls of Manganese Concentrations in Marine Porewaters
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High phosphate concentrations in the surface sediment may potentially negatively affect the rate of Mn carbonate formation.
“High phosphate concentrations in the surface sediment may potentially negatively affect the rate of Mn carbonate formation (Mucci, 2004), but there is no evidence for a significant rise in dissolved phosphate in the pore water of Gotland Basin sediments over the past decades (e.g. Carman and Rahm, 1997; Hille et al., 2005; Jilbert et al., 2011).”
From Are recent changes in sediment manganese sequestration in the euxinic basins of the Baltic Sea linked to the expansion of hypoxia? (2015) · cites this paper as Mucci, 2004
The mobility of Mn(II) in the natural environment is controlled by various geochemical processes, including its incorporation into carbonates to form rhombohedral calcite-rhodochrosite solid solutions [(Ca,Mn)CO3] via a dissolution-recrystallization process.
“Its mobility in the natural environment is controlled by various geochemical processes, including its incorporation into carbonates to form rhombohedral calcite-rhodochrosite solid solutions [(Ca,Mn)CO3] via a dissolution–recrystallization process [3–6].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
The synthetic disordered Ca-Mg-rhodochrosite (Mn0.58Ca0.39Mg0.03)CO3 dissolved congruently in water at 25 °C.
“The synthetic disordered Ca-Mg-rhodochrosite (Mn0.58Ca0.39Mg0.03)CO3 dissolved congruently in water at 25 °C”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
A nearly continuous series between CaCO3 and MnCO3 can be prepared in the laboratory.
“and a nearly continuous series between CaCO3 and MnCO3 can be prepared in the laboratory [6, 13].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
The ion activity product (log_IAP) of −10.39 was extrapolated from the congruent dissolution of synthetic disordered Ca-Mg-rhodochrosite (Mn0.58Ca0.39Mg0.03)CO3 in water at 25 °C.
“from which the ion activity product (log_IAP) of − 10.39 was extrapolated [6].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
The disordered calcian rhodochrosite (Mn0.58Ca0.39Mg0.03CO3) precipitated in the laboratory showed a log_IAP value of −10.38 after long-term equilibration.
“The disordered calcian rhodochrosite (Mn0.58Ca0.39Mg0.03CO3) precipitated in the laboratory showed a log_IAP value of -10.38 after long-term equilibration [6].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
The thermodynamic solubility product can be calculated from long-term steady states or extrapolated ion activity products corresponding to the equilibrium constant of mineral dissolution.
“The thermodynamic solubility product could be calculated from the long-term steady states or extrapolated ion activity products (IAPs) of the solutions that corresponded to the equilibrium constant of mineral dissolution [6].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [6]
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Havig, J. R., McCormick, M. L., Hamilton, T. L., & Kump, L. R. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.06.024 · Cited by 72
“…oxygenic phototrophs (including “whiting events”; Thompson et al., 1997), there is presumably a seasonal supply of calcite precipitated by cyanobacteria serving as nucleation sites for precipitation of manganous carbonates as a disordered carbonate phase (Mucci, 2004) throughout the water column.”
BackgroundInfluentialTransient state diagenesis in continental margin muds
Sundby, B. (2006) · Marine Chemistry · doi:10.1016/j.marchem.2005.09.016 · Cited by 69
“carbonates, driven by increased alkalinity production and consequent supersaturation of carbonate phases, could explain these observations (Mucci, 2004).”
ResultLenz, C., Jilbert, T., Conley, D. J., Wolthers, M., & Slomp, C. P. (2015) · Biogeosciences · doi:10.5194/bg-12-4875-2015 · Cited by 61
Biogeochemistry of manganese in ferruginous Lake Matano, Indonesia
Jones, C., Crowe, S. A., Sturm, A., Leslie, K., MacLean, L. C. W., Katsev, S., Henny, C., Fowle, D. A., & Canfield, D. E. (2011) · Biogeosciences · doi:10.5194/bg-8-2977-2011 · Cited by 57
Charge Compensation in Solid Solutions
Schmidt, M., Stumpf, T., Fernandes, M. M., et al. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705827 · Cited by 54
Zhang, B.-L., Wang, C., Robbins, L. J., Zhang, L., Konhauser, K. O., Dong, Z., Li, W.-J., Peng, Z., & Zheng, M. (2020) · Economic Geology · doi:10.5382/econgeo.4729 · Cited by 55
The Speciation and Mobility of Mn and Fe in Estuarine Sediments
Oldham, V. E., Siebecker, M. G., Jones, M. R., et al. (2019) · Aquatic Geochemistry · doi:10.1007/s10498-019-09351-0 · Cited by 53
“For dFeT, diffusion downward occurs and results in the formation of AVS and pyrite, whereas dMnT can either diffuse up and out of the sediment or downward to ultimately co-precipitate with authigenic carbonates or adsorb onto AVS and sediment particles (Mucci 2004).”
BackgroundSelf-citationCa–Mg kutnahorite and struvite production by Idiomarina strains at modern seawater salinities
González‐Muñoz, M. T., Linares, C. D., Martı́nez-Ruiz, F., Morcillo, F., Martín-Ramos, D., & Arias, J. M. (2008) · Chemosphere · doi:10.1016/j.chemosphere.2008.02.010 · Cited by 51
Manganese sulfide formation via concomitant microbial manganese oxide and thiosulfate reduction
Lee, J., Kennedy, D. W., Dohnalkova, A. C., Moore, D. A., Nachimuthu, P., Reed, S. B., & Fredrickson, J. K. (2011) · Environmental Microbiology · doi:10.1111/j.1462-2920.2011.02587.x · Cited by 52
Formation of ordered dolomite in anaerobic photosynthetic biofilms
Daye, M., Higgins, J. A., & Bosak, T. (2019) · Geology · doi:10.1130/g45821.1 · Cited by 52
“This is consistent with 139 the previously noted requirement for Mg(II) in the formation of high-Mn dolomite-type mineral 140 phases in inorganic ternary systems of CaCO3-MnCO3-MgCO3 carbonates (Mucci, 2004).”
ResultRedox conditions and trace metal cycling in coastal sediments from the maritime Antarctic
Monien, P., Lettmann, K., Monien, D., Asendorf, S., Wölfl, A., Lim, C., Thal, J., Schnetger, B., & Brumsack, H. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.06.003 · Cited by 41
Benthic geochemistry of manganese in the Bay of Biscay, and sediment mass accumulation rate
Mouret, A., Anschutz, P., Lécroart, P., Chaillou, G., Hyacinthe, C., Deborde, J., Jorissen, F. J., Deflandre, B., Schmidt, S., & Jouanneau, J. (2008) · Geo-Marine Letters · doi:10.1007/s00367-008-0130-6 · Cited by 41
“…Mn associated with carbonate can represent the main phase under which reactive Mn is ultimately buried in anoxic sediments (Holdren et al. 1975; Grill 1978; Suess 1979; Aller 1980; Pedersen and Price 1982; Thomson et al. 1986; Middelburg et al. 1987; Mucci 1988, 2004; Jakobsen and Postma 1989).”
BackgroundYan, H., Pi, D.-H., Jiang, S., Mao, J., Xu, L., Yang, X., Hao, W., Mänd, K., Li, L., Konhauser, K. O., et al. (2022) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2022.03.030 · Cited by 42
Precipitation and mixing properties of the “disordered” (Mn,Ca)CO3 solid solution
Katsikopoulos, D., González, Á. F., & Rubio, M. P. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.07.001 · Cited by 39
Gao, Z., Zhu, X., Wang, D., Pan, C., Yan, B., & Jin, L. (2021) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2021.104524 · Cited by 38
Reviews and syntheses: Review of proxies for low-oxygen paleoceanographic reconstructions
Hoogakker, B. A. A., Davis, C. V., Wang, Y., Kusch, S., Nilsson-Kerr, K., Hardisty, D. S., Jacobel, A. W., Macaya, D. A. R., Glock, N., Ni, S., et al. (2025) · Biogeosciences · doi:10.5194/bg-22-863-2025 · Cited by 46
Namgung, S., Guo, B., Sasaki, K., Lee, S. S., & Lee, G. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.03.036 · Cited by 34
Chaillou, G., Anschutz, P., Dubrulle-Brunaud, C., et al. (2007) · Aquatic Geochemistry · doi:10.1007/s10498-007-9013-0 · Cited by 33
“In anoxic conditions, sorption of Mn2+ onto CaCO3 surfaces is the most important processes that control the mobility of Mn2+ (Middelburg et al. 1987; Mucci 2004).”
BackgroundHohl, S. V., Becker, H., Jiang, S., Ling, H., Guo, Q., & Struck, U. (2017) · Journal of the Geological Society · doi:10.1144/jgs2016-145 · Cited by 31
“…of E diacaran cap dolostones carbonates, as these may have been deposited under more reducing redox conditions (e.g. ferruginous, manganous, anoxic, suboxic) compared with typical Phanerozoic carbonate rocks, which may result in variable element concentrations (e.g. Thomson et al 1998; Mucci 2004).”
BackgroundHasenfratz, A. P., Martínez‐García, A., Jaccard, S. L., Vance, D., Wälle, M., Greaves, M. J., & Haug, G. H. (2016) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2016.10.004 · Cited by 32
“…from porewater by the formation of Mn-rich 321 carbonates, preferentially forming at the inner surface of foraminifera tests due to the even 322 more reductive microenvironment (Murray, 1991) and the reactive surfaces that promote 323 nucleation (Pedersen and Price, 1982; Mucci, 2004).”
BackgroundEpitaxial Growth of Calcite Crystals on Dolomite and Kutnahorite (104) Surfaces
Pimentel, C., Pina, C. M., & Gnecco, E. (2013) · Crystal Growth & Design · doi:10.1021/cg400315g · Cited by 28
Wang, Y., Hendy, I., Latimer, J., & Bilardello, D. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.04.018 · Cited by 18
Huang, Q., Pi, D.-H., Jiang, S., Liu, D., Yan, H., Mänd, K., Kirsimäe, K., Bishop, B., Robbins, L. J., & Yang, S. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.120992 · Cited by 24
Seawater Pb isotopes extracted from Cenozoic marine sediments
Basak, C., Martin, E. E., & Kamenov, G. D. (2011) · Chemical Geology · doi:10.1016/j.chemgeo.2011.04.007 · Cited by 24
Magen, C., Mucci, A. O., & Sundby, B. (2011) · Aquatic Geochemistry · doi:10.1007/s10498-010-9117-9 · Cited by 22
Self-citationSediment Response to 25 Years of Persistent Hypoxia
Lefort, S., Mucci, A. O., & Sundby, B. (2012) · Aquatic Geochemistry · doi:10.1007/s10498-012-9173-4 · Cited by 22
“…sedimentary sulfide sink for manganese (Thamdrup et al. 1994; Arakaki and Morse 1996; Morse and Luther III 1999), a limited carbonate sink at depth (Mucci 2004) and nearly all the Mn(IV) oxides that accumulate in the oxic sediment layer are reactive (hydroxylamine, ascorbic acid, and total acid…”
BackgroundSelf-citationDissolved Mn2+ promotes microbially-catalyzed protodolomite precipitation in brackish oxidized water
Han, Z., Li, J., Zhao, Y., Chen, Q., Gao, X. P., Hu, K., Guo, N., Wei, X., Meng, R., Zhu, C., et al. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2024.121986 · Cited by 23
Goren, O., Lazar, B., Burg, A., & Gavrieli, I. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.06.032 · Cited by 21
Goto, K. T., Sekine, Y., Ito, T., Suzuki, K., Anbar, A. D., Gordon, G. W., Harigane, Y., Maruoka, T., Shimoda, G., Kashiwabara, T., et al. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120116 · Cited by 19
Ai, J., Siljeström, S. M., Zhong, N., Chen, J., Wang, T., Qiu, N., & George, S. C. (2023) · Precambrian Research · doi:10.1016/j.precamres.2023.107091 · Cited by 21
Zhang, B., Cao, J., Hu, K., Liao, Z., Zhang, Y., & Shi, C. (2022) · Global and Planetary Change · doi:10.1016/j.gloplacha.2022.103950 · Cited by 20
Arsenic fractionation in estuarine sediments: Does coastal eutrophication influence As behavior?
Sá, F., Sanders, C. J., Patchineelam, S. R., et al. (2015) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2015.04.037 · Cited by 19
Katsikopoulos, D., Fernández-González, Á., & Prieto, M. (2009) · Mineralogical Magazine · doi:10.1180/minmag.2009.073.2.269 · Cited by 16
“In natural anaerobic aquatic environments, the precipitation of intermediate MnxCa1 xCO3 compositions is believed to control the concentration of Mn in pore waters (Mucci, 2004).”
BackgroundMethodInfluentialDissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C
Zhu, Y., Nong, P., Mo, N., Zhu, Z., Deng, H., Tang, S., Yang, H., Zhang, L., & Wang, X. (2021) · Geochemical Transactions · doi:10.1186/s12932-021-00075-1 · Cited by 11
“The working principle of the closed-system was described in detail previously [6].”
BackgroundManganese( ii ) promotes prebiotically plausible non-enzymatic RNA ligation reactions
Liu, Z., Jiang, C. Z., Bond, A. D., Tosca, N. J., & Sutherland, J. D. (2024) · Chemical Communications · doi:10.1039/d4cc01086h · Cited by 11
Dissolution and Solubility of the Calcite–Otavite Solid Solutions [(Ca1−xCdx)CO3] at 25 °C
Ma, C., Xu, F., Zhu, Z., Yang, H., Nong, P., Kang, Z., Tang, S., Zhang, L., & Zhu, Y. (2022) · Minerals · doi:10.3390/min12060756 · Cited by 13
Rodríguez-Galán, R. M., & Rubio, M. P. (2018) · Geochemistry Geophysics Geosystems · doi:10.1029/2017gc007261 · Cited by 11
“Manganese-rich calcites formed in marine and nonmarine environments are also very common (Katsikopoulos et al., 2009; Mucci, 2004).”
BackgroundFrom minerals to metabolisms: Evidence for life before oxygen from the geological record
Johnson, J. E. (2019) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2019.01.047 · Cited by 14
Water film-driven Mn (oxy)(hydr)oxide nanocoating growth on rhodochrosite
Luong, N. T., Ilton, E. S., Shchukarev, A., & Boily, J. (2022) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2022.05.019 · Cited by 10
Silicate Weathering and Diagenetic Reaction Balances in Deltaic Muds
Müller, G., Aller, R. C., Sluijs, A., & Middelburg, J. J. (2025) · American Journal of Science · doi:10.2475/001c.134118 · Cited by 11
A Large Review of the Pre Treatment
Gaid, K. (2011) · InTech eBooks · doi:10.5772/19680 · Cited by 9
“Hypoxic concentrations below 16% saturation can increase the concentration of dissolved manganese above that normally found in seawater to concentrations approaching 1500 µg/litre (Mucci,2004).”
BackgroundCook, M. K., & Hendy, I. L. (2024) · Geochemistry Geophysics Geosystems · doi:10.1029/2023gc010885 · Cited by 8
“Additionally, diagenetic Mn‐carbonates readily form on foraminiferal calcite in suboxic, high alkalinity porewaters where Mn 2 + concentrations approach those of Ca 2 + (Mucci, 2004).”
BackgroundCraig, A. T., Shkarupin, A., Amos, R. T., Lindsay, M. B. J., Blowes, D. W., & Ptacek, C. J. (2021) · Applied Geochemistry · doi:10.1016/j.apgeochem.2021.104904 · Cited by 8
Xu, C., Nong, P., Zhu, Z., et al. (2023) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.3c00068 · Cited by 7
Yan, H., Xu, L., Mao, J., Tang, D., Yang, X., Bai, Y., Li, C., Konhauser, K. O., & Robbins, L. J. (2023) · American Mineralogist · doi:10.2138/am-2022-8919 · Cited by 7
Precipitation mechanism of Mn ore deposits in the datangpo formation, Nanhua Basin, South China
Chen, H., Fan, H.-F., Khan, D., Jiang, X., Feng, L., Wen, H.-J., Tian, H., & Zhu, X.-K. (2024) · Global and Planetary Change · doi:10.1016/j.gloplacha.2024.104499 · Cited by 10
Zhu, Y., Yu, X., Pan, S., Nong, P., Kong, Q., Wang, X., Zhang, L., Tan, S., & Zhu, Z. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.120886 · Cited by 7
Živković, I., Bura‐Nakić, E., Knežević, L., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.08.020 · Cited by 7
Hydrogeochemical investigation and fluoride levels in lakes: a comprehensive health risk assessment
Sahoo, M. M., & Swain, J. B. (2025) · Environmental Geochemistry and Health · doi:10.1007/s10653-025-02562-1 · Cited by 7
“15) (Mucci, 2004; Santos et al., 2023), which adds F − to water by encouraging he dissociation of fluorite content (Eq.”
Johnson, J. E., Webb, S. M., Condit, C. B., Beukes, N. J., & Fischer, W. W. (2019) · South African Journal of Geology · doi:10.25131/sajg.122.0034 · Cited by 6
Freeze-induced crystallization: An overlooked pathway for mineral genesis in natural waters
Won, Y., Lee, S., Lee, S., Park, S.-H., Lim, J., Choi, W., & Lee, G. (2025) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2421822122 · Cited by 5
“For instance, the high Ca concentration in natural waters, coupled with the similar solubility products of rhodochrosite and Ca–Mn carbonates [ K sp = 10 −10.33 for kutno-horite, (Mn 0.57 Ca 0.41 Mg 0.02 Fe 0.006 )CO 3 ] ( 58 ), may facilitate Ca– Mn carbonate precipitation.”
InfluentialZhu, Y., Nong, P., Zhu, Z., Pan, S., Liu, H., Deng, H., Tang, S., & Zhang, L. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121614 · Cited by 5
Ali, M. K., Yan, H., Mujahid, M., et al. (2025) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2025.140645 · Cited by 4
Otero, X. L., Ramírez-Pérez, A. M., Abernathy, M. J., Ying, S. C., Queiroz, H. M., Ferreira, T. O., Huerta-Díaz, M. Á., & de Blas, E. (2024) · Marine Geology · doi:10.1016/j.margeo.2024.107250 · Cited by 3
“…fraction (Kiratli and Ergin, 1996), acting as a nucleation site for Mn 2 + (Herndon et al., 2018) and precipitating as a manganoan carbonate (Mucci, 1988, 2004; Lenz et al., 2014a, Lenz et al., 2014b) that is either of kutnohorite or “ pseudokutnohorite ” type (CaMn(CO 3 ) 2 ; Middelburg et…”
Geochemical and Hydrological Controls on Manganese in a Weakly-Stratified Drinking Water Reservoir
Sang, Y., Pietz, O., Christiansen, E., et al. (2024) · ACS ES&T Water · doi:10.1021/acsestwater.4c00355 · Cited by 3
Koshurba, K., & Johnson, J. E. (2024) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.4c00092 · Cited by 2
Dissolution and solubility of the calcium-nickel carbonate solid solutions [(Ca1−xNix)CO3] at 25 °C
Ma, C., Xiaoke, N. O. N. G., Xu, F., Zhu, Z., Nong, P., Luo, F., Tang, S., Zhang, L., Kang, Z., & Zhu, Y. (2024) · Geochemical Transactions · doi:10.1186/s12932-024-00096-6 · Cited by 2
“…be estimated from the long-standing stable state or the extrapolated ion activity product (IAP) of the water solution at the mineral dissolution equilibrium [29], i.e., at dissolution equilibrium, the equilibrium constant ( K sp ) for the (Ca 1 − x Ni x )CO 3 solid solutions can be defined by Eq.”
Metallogenetic Mn-model of the Rhyacian-aged Buritirama Formation, Carajás domain (Amazon Craton)
Salgado, S. S., Caxito, F. D. A., Silva, R. C. F. E., Uhlein, G. J., Nogueira, L. B., Júnior, H. A. N., & Aranda, R. D. O. (2021) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2021.104396 · Cited by 2
Manganese (Sedimentary Carbonates and Sulfides)
Böttcher, M. E. (2011) · Encyclopedia of earth sciences series/Encyclopedia of earth sciences · doi:10.1007/978-1-4020-9212-1_130 · Cited by 2
Nzamba, K. X., Juhkama, H.-R., Moussavou, M., Mayika, K. B., Kreitsmann, T., Lepland, A., Prave, A., & Kirsimäe, K. (2026) · Journal of African Earth Sciences · doi:10.1016/j.jafrearsci.2025.105971 · Cited by 2
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Ladungsausgleich in festen Lösungen
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Pienaar, D., Smith, A. J. B., Blignaut, L., & Viljoen, F. (2025) · South African Journal of Geology · doi:10.25131/sajg.128.0005 · Cited by 1
Estudio de la estructura y reactividad de las superficies de minerales del grupo de la dolomita
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Hydro-geochemical investigation and Fluoride levels in Lakes: A comprehensive health risk assessmentPreprint
Sahoo, M. M., & Swain, J. B. (2025) · Research Square · doi:10.21203/rs.3.rs-6230640/v1 · Cited by 1
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Comment on egusphere-2023-2981
Hoogakker, B. A. A., Davis, C. V., Wang, Y., et al. (2024) · doi:10.5194/egusphere-2023-2981-rc2
Comment on egusphere-2023-2981
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Hoogakker, B. A. A. (2024) · doi:10.5194/egusphere-2023-2981-ac4
Hoogakker, B. A. A. (2024) · doi:10.5194/egusphere-2023-2981-ac3
Hoogakker, B. A. A. (2024) · doi:10.5194/egusphere-2023-2981-ac1
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“Modeling of the saturation state of minerals across water column depth was performed in Phreeqc version 3.6.2 using the Minteq version 4 database, amended with log K sp of kutnahorite [CaMn(CO 3 ) 2 ; log K sp = − 20.77] (Mucci 2004).”
InfluentialDissolution and solubility of (Ca,Pb)SO4 phases in 25 °C aqueous solutions at different pH levels
Zhu, Z., Zhou, X., Tang, S., Luo, F., Xiaoke, N. O. N. G., Zhang, L., Nong, P., & Zhu, Y. (2026) · Chemical Geology · doi:10.1016/j.chemgeo.2026.123340
Hein, M., Kasper, T., Samudra, A. B., et al. (2026) · Boreas · doi:10.1111/bor.70066
Carboxyl-stabilized Mn redox cycling promotes a metastable kutnahorite-to-dolomite pathway
Petrash, D. A., Valero, A., Bialik, O. M., Fang, Y., Hamers, M., Meador, T. B., Bontognali, T. R. R., Böttcher, M. E., & Plümper, O. (2026) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2026.05.034 · Cited by 1
“Although disordered kutnahorite occurs as a metastable phase at near-surface temperatures (Reeder, 1983; Peacor et al., 1987; Mucci, 2004; B ¨ ottcher and Dietzel, 2010), our results clearly show that formation of this phase is kinetically favoured over disordered dolomite under functionalized…”
Chen, X., Zhao, Y., Zhao, H. C., et al. (2026) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2026.143140
Huang, Q., Li, J., Yan, H., Zhang, Y., Ahmet, S., Ding, N., Zhao, L.-N., Yu, S., & Zhou, H. (2026) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2026.107562
Metadata
- Authors
- Mucci, A.
- Affiliations
- McGill University (CA)
- Corresponding author
- Mucci, Alfonso
- ORCID
- Mucci, Alfonso
- Venue
- Aquatic Geochemistry
- Published
- 2004-03
- Volume
- 10
- Issue
- 1-2
- Pages
- 139-169
- ISSN
- 1380-6165 (ISSN-L)
- 1573-1421
- OpenAlex
- W2158510936
- Semantic Scholar
- 6ea7a7f724ed7b085b465a26d9d4f66b86e4a6fe
- Cited by
- 94
- References
- 99
- Citations by year
- 2026: 7 · 2025: 9 · 2024: 17 · 2023: 6 · 2022: 6 · 2021: 6 · 2020: 3 · 2019: 5 · 2018: 2 · 2017: 1 · 2016: 1 · 2015: 5 · 2014: 2 · 2013: 1 · 2012: 5
- FWCI
- 1.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Aquatic Geochemistry (publishedVersion)
- Funders
- Université du Québec à Montréal
- Natural Sciences and Engineering Research Council of Canada
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Keywords
- kutnahorite, rhodochrosite, manganese carbonate, calcite, dissolution kinetics, ion activity product, solubility product, seawater, pore water, marine sediment, phase stability, carbonate mineralogy
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