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Radiative forcing of climate by changes in the vertical distribution of ozone
Abstract
We describe a simple method for evaluating the radiative forcing of surface temperature caused by changes in the vertical distribution of ozone. The method employs a parameterization based on one‐dimensional radiative‐convective equilibrium calculations; these calculations predict that the surface temperature should warm in response to both decreases in ozone above 30 km and increases in ozone below 30 km. The parameterization is used to investigate the response of surface temperature to observed changes in the vertical distribution of ozone at northern mid‐latitudes. We show that the observed ozone trends, taken at face value, suggest a cooling of the surface temperature at northern mid‐latitudes during the 1970s equal in magnitude to about half the warming predicted for CO 2 for the same time period. However, the measurement uncertainty of the observed trends is large, with the best estimates for mid‐latitude cooling being −0.05±0.05°C. The surface cooling is caused by ozone decreases in the lower stratosphere, which outweigh the warming effects of ozone increases in the troposphere. The results obtained differ from predictions based on one‐dimensional photochemical model simulations of ozone trends for the 1970s, which suggest a warming of the surface temperature equal to ∼20% of the warming contributed by CO 2 . Also, the ozone decreases observed in the lower stratosphere during the 1970s produce atmospheric cooling by several tenths of a degree in the 12‐ to 20‐km altitude region over the northern mid‐latitudes. This temperature decrease is larger than the cooling due to CO 2 and thus may obscure the expected stratospheric CO 2 greenhouse signature.
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“Numerous studies have reported its potency as a greenhouse gas at these altitudes, due to its ability to absorb IR, UV and visible radiation [146][147][148][149].”
From Investigation of Biofuel as a Potential Renewable Energy Source (2021) · cites this paper as [147]
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Radiative forcing from tropospheric ozone calculated with a unified chemistry-climate model
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Hansen, J. E., Sato, M., & Ruedy, R. A. (1995) · Atmospheric Research · doi:10.1016/0169-8095(94)00077-q · Cited by 147
Response of climate to regional emissions of ozone precursors: sensitivities and warming potentials
Berntsen, T. K., Fuglestvedt, J. S., Joshi, M., Shine, K. P., Stuber, N., Ponater, M., SAUSEN, R., Hauglustaine, D. A., & Li, L. (2005) · Tellus B · doi:10.3402/tellusb.v57i4.16549 · Cited by 145
“It is well-established that changes in upper tropospheric ozone concentrations lead to a larger radiative forcing (e.g. Wang and Sze, 1980; Lacis et al., 1990) than changes nearer the surface; and changes in ozone in the tropics and subtropics have a considerably larger (up to a factor of 2) impact on radiative forcin…”
BackgroundMethodInfluentialRay, E., Moore, F. L., Elkins, J. W., Dutton, G. S., Fahey, D. W., Vömel, H., Oltmans, S. J., & Rosenlof, K. H. (1999) · Journal of Geophysical Research Atmospheres · doi:10.1029/1999jd900323 · Cited by 144
Oceanic Microstructure Measurements by BAKLAN and GRIF
Paka, V. T., Nabatov, V. N., Lozovatsky, I. D., & Dillon, T. M. (1999) · Journal of Atmospheric and Oceanic Technology · doi:10.1175/1520-0426(1999)016 · Cited by 45
Eyring, V., Stevenson, D. S., Lauer, A., Dentener, F. J., Butler, T. M., Collins, W. J., Ellingsen, K., Gauss, M., Hauglustaine, D. A., Isaksen, I. S. A., et al. (2007) · Atmospheric chemistry and physics · doi:10.5194/acp-7-757-2007 · Cited by 141
“The net radiative forcing is most sensitive to NOx emissions at altitudes of about 8–12 km because of longer NOx and O3 lifetimes, and colder temperatures compared to the surface (Lacis et al., 1990; Brasseur et al., 1998). Ship NOx reduces the CH 4 lifetime by 0.13 yr in 2000 and by up to 0.17 yr in 2030, introducing…”
InfluentialInvestigation of Biofuel as a Potential Renewable Energy Source
Khan, M. A. H., Bonifacio, S., Clowes, J., Foulds, A., Holland, R., Matthews, J. C., Percival, C. J., & Shallcross, D. E. (2021) · Atmosphere · doi:10.3390/atmos12101289 · Cited by 140
Historical total ozone radiative forcing derived from CMIP6 simulations
Skeie, R. B., Myhre, G., Hodnebrog, Ø., Cameron-Smith, P. J., Deushi, M., Hegglin, M. I., Horowitz, L. W., Kramer, R. J., Michou, M., Mills, M. J., et al. (2020) · npj Climate and Atmospheric Science · doi:10.1038/s41612-020-00131-0 · Cited by 158
On the evaluation of halocarbon radiative forcing and global warming potentials
Daniel, J. S., Solomon, S., & Albritton, D. L. (1995) · Journal of Geophysical Research Atmospheres · doi:10.1029/94jd02516 · Cited by 149
Apel, E. C., Hornbrook, R. S., Hills, A. J., et al. (2015) · Journal of Geophysical Research Atmospheres · doi:10.1002/2014jd022121 · Cited by 138
Ramaswamy, V., Collins, W. D., Haywood, J., Lean, J. L., Mahowald, N. M., Myhre, G., Naïk, V., Shine, K. P., Soden, B. J., Stenchikov, G. L., et al. (2019) · Meteorological Monographs · doi:10.1175/amsmonographs-d-19-0001.1 · Cited by 148
“%) in solar cycles 22 (1986–96) and cycle 23 (1996–2008) produced decadal solar radiative forcing DFs 5 0.7DTSI/4 5 0.23Wm 22 (Hansen and Lacis 1990).”
BackgroundSources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations
Liu, H., Jacob, D. J., Chan, L. Y., et al. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd002005 · Cited by 136
“[2] Ozone in the troposphere is an important greenhouse gas [Lacis et al., 1990].”
BackgroundPast and future changes in global tropospheric ozone: Impact on radiative forcing
Brasseur, G. P., Kiehl, J. T., Müller, J., Schneider, T. L., Granier, C., Tie, X., & Hauglustaine, D. A. (1998) · Geophysical Research Letters · doi:10.1029/1998gl900013 · Cited by 135
Bönisch, H., Engel, A., Curtius, J., Birner, T., & Hoor, P. M. (2009) · Atmospheric chemistry and physics · doi:10.5194/acp-9-5905-2009 · Cited by 134
“Changes in concentrations of radiatively active species in this region potentially have a strong impact on the radiation balance of the troposphere (e.g., Lacis et al., 1990; Forster and Shine, 1997).”
BackgroundFree tropospheric ozone production following entrainment of urban plumes into deep convection
Pickering, K., Thompson, A. M., Scala, J. R., et al. (1992) · Journal of Geophysical Research Atmospheres · doi:10.1029/92jd01716 · Cited by 134
Summertime free-tropospheric ozone pool over the eastern Mediterranean/Middle East
Zanis, P., Hadjinicolaou, P., Pozzer, A., Tyrlis, E., Dafka, S., Mihalopoulos, N., & Lelieveld, J. (2014) · Atmospheric chemistry and physics · doi:10.5194/acp-14-115-2014 · Cited by 133
“Ozone in the free troposphere has a longer lifetime compared to the boundary layer, which enables transport on regional to hemispheric scales, and it has a proportionally greater influence on climate than ozone near the surface (Lacis et al., 1990).”
BackgroundRemote sensed and in situ constraints on processes affecting tropical tropospheric ozone
Sauvage, B., Martin, R. V., van Donkelaar, A., Liu, X., Chance, K., Jaeglé, L., Palmer, P. I., Wu, S., & Fu, T. (2007) · Atmospheric chemistry and physics · doi:10.5194/acp-7-815-2007 · Cited by 132
“Ozone (O3) in the tropical troposphere is a major component of atmospheric radiative forcing (de Forster et al., 1997; Lacis et al., 1990) and plays a key role in the global oxidizing power of the atmosphere (Logan et al.”
Crawford, J. H., Davis, D. D., Olson, J. R., Chen, G., Liu, S., Gregory, G., Barrick, J. D. W., Sachse, G. W., Sandholm, S. T., Heikes, B. G., et al. (1999) · Journal of Geophysical Research Atmospheres · doi:10.1029/1999jd900106 · Cited by 131
Impact of aircraft and surface emissions of nitrogen oxides on tropospheric ozone and global warming
Johnson, C. E., Henshaw, J., & Mclnnes, G. (1992) · Nature · doi:10.1038/355069a0 · Cited by 129
Tropospheric ozone evolution between 1890 and 1990
Lamarque, J., Hess, P., Emmons, L. K., Buja, L. E., Washington, W. M., & Granier, C. (2005) · Journal of Geophysical Research Atmospheres · doi:10.1029/2004jd005537 · Cited by 127
“[2] The distribution of ozone in the troposphere and lower stratosphere is an important component to the atmospheric radiative forcing [Lacis et al., 1990; Shine and de Forster, 1999].”
BackgroundTropical ozone as an indicator of deep convection
Folkins, I., Braun, C., Thompson, A. M., et al. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd001178 · Cited by 126
Wang, H., Lu, X. H., Jacob, D. J., Cooper, O. R., Chang, K., Li, K., Gao, M. C., Liu, Y., Sheng, B., Wu, K., et al. (2022) · Atmospheric chemistry and physics · doi:10.5194/acp-22-13753-2022 · Cited by 148
“…global scales are largely constrained by the limited coverage of robust long-term ozone measurements for evaluating modeled ozone trends, especially in the free troposphere (Gaudel et al., 2020) where ozone has greater radiative impacts than at the surface (Lacis et al., 1990; Hansen et al., 1997).”
BackgroundInterannual variability in tropical tropospheric ozone and OH: The role of lightning
Murray, L. T., Logan, J. A., & Jacob, D. J. (2013) · Journal of Geophysical Research Atmospheres · doi:10.1002/jgrd.50857 · Cited by 121
“In the cold upper troposphere, ozone has a28 potent greenhouse effect [Lacis et al., 1990; Forster and Shine, 1997].”
BackgroundA guide to global warming potentials (GWPs)
Harvey, L. D. D. (1993) · Energy Policy · doi:10.1016/0301-4215(93)90205-t · Cited by 119
Effects of anthropogenic emissions on tropospheric ozone and its radiative forcing
Berntsen, T. K., Isaksen, I. S. A., Myhre, G., Fuglestvedt, J. S., Stordal, F., Larsen, T. A., Freckleton, R. S., & Shine, K. P. (1997) · Journal of Geophysical Research Atmospheres · doi:10.1029/97jd02226 · Cited by 120
Contributions of Agroecosystems to Global Climate Change
Duxbury, J. M., Harper, L. A., & Mosier, A. R. (1993) · ASA special publication · doi:10.2134/asaspecpub55.c1 · Cited by 116
Fry, M. M., Naïk, V., West, J. J., Schwarzkopf, M. D., Fiore, A. M., Collins, W. J., Dentener, F. J., Shindell, D. T., Atherton, C., Bergmann, D. J., et al. (2012) · Journal of Geophysical Research Atmospheres · doi:10.1029/2011jd017134 · Cited by 114
“EA and SA reductions (except for EA NMVOC) have RF efficiency greater than average, as these regions have greater influences on the UT where RF is the most efficient [Lacis et al., 1990; Wang et al., 1993; Forster and Shine, 1997; West et al., 2009a].”
BackgroundQuantifying the contributions of individual NOx sources to the trend in ozone radiative forcing
Dahlmann, K., Grewe, V., Ponater, M., & Matthes, S. (2011) · Atmospheric Environment · doi:10.1016/j.atmosenv.2011.02.071 · Cited by 123
“Due to the dependency of the greenhouse effect on the temperature of the absorber the radiative efficiency is larger for ozone changes near the tropopause (Lacis et al., 1990).”
BackgroundClimate forcing due to tropospheric and stratospheric ozone
Kiehl, J. T., Schneider, T. L., Portmann, R. W., & Solomon, S. (1999) · Journal of Geophysical Research Atmospheres · doi:10.1029/1999jd900991 · Cited by 113
Impact of aircraft NO x emissions on the atmosphere – tradeoffs to reduce the impact
Gauss, M., Isaksen, I. S. A., Lee, D. S., & Søvde, O. A. (2006) · Atmospheric chemistry and physics · doi:10.5194/acp-6-1529-2006 · Cited by 113
“These factors, combined25 with the relatively large radiative forcing caused by ozone increases occurring in the UTLS (Wang and Sze, 1980; Lacis et al., 1990; Hansen et al., 1997), make aircraft NOx emissions disproportionately important to the total O3 radiative forcing from all ACPD 5,…”
BackgroundRotman, D., Atherton, C. S., Bergmann, D. J., Cameron-Smith, P. J., Chuang, C. C., Connell, P. S., Dignon, J., Franz, A., Grant, K. E., Kinnison, D. E., et al. (2004) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd003155 · Cited by 110
“natural and anthropogenic perturbations on ozone in the tropopause region is important because ozone in this region exerts a disproportionately greater influence on radiative forcing than ozone in other atmospheric regions [Lacis et al., 1990; IPCC, 2001].”
BackgroundInfluentialChemistry-albedo feedbacks offset up to a third of forestation’s CO 2 removal benefits
Weber, J., King, J., Abraham, N. L., Grosvenor, D. P., Smith, C., Shin, Y. M., Lawrence, P., Roe, S., Beerling, D. J., & Martin, M. V. (2024) · Science · doi:10.1126/science.adg6196 · Cited by 122
Lamarque, J., Brasseur, G. P., Hess, P., & Müller, J. (1996) · Journal of Geophysical Research Atmospheres · doi:10.1029/96jd02160 · Cited by 108
Sudo, K., Takahashi, M., & Akimoto, H. (2003) · Geophysical Research Letters · doi:10.1029/2003gl018526 · Cited by 107
“Since O3 changes in the tropopause region cause the largest radiative effect (particularly on surface temperatures) [Lacis et al., 1990], climate change impacts on STE can play a crucial role in future radiative forcing from O3.”
Background
Metadata
- Authors
- Lacis, A. A., Wuebbles, D. J., & Logan, J. A.
- Affiliations
- Goddard Institute for Space Studies (US)
- National Center for Supercomputing Applications (BG)
- Harvard University (US)
- Venue
- Journal of Geophysical Research Atmospheres
- Publisher
- American Geophysical Union (AGU)
- Published
- 1990-06-20
- Volume
- 95
- Issue
- D7
- Pages
- 9971-9981
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2057192297
- Cited by
- 556
- References
- 51
- Citations by year
- 2026: 9 · 2025: 15 · 2024: 39 · 2023: 10 · 2022: 33 · 2021: 11 · 2020: 13 · 2019: 9 · 2018: 17 · 2017: 16 · 2016: 19 · 2015: 14 · 2014: 13 · 2013: 17 · 2012: 16
- FWCI
- 10.31
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
- Physical Sciences › Environmental Science › Global and Planetary Change › Climate variability and models
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
- Keywords
- radiative forcing, vertical ozone distribution, surface temperature, stratospheric ozone depletion, radiative-convective equilibrium, surface cooling, northern mid-latitudes, ozone trends
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