The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media
Open accessAbstract
The chemical transformation of carbon dioxide into useful products becomes increasingly important as CO2 levels in the atmosphere continue to rise as a consequence of human activities. In this article we describe the direct hydrogenation of CO2 into formic acid using a homogeneous ruthenium catalyst, in aqueous solution and in dimethyl sulphoxide (DMSO), without any additives. In water, at 40 °C, 0.2 M formic acid can be obtained under 200 bar, however, in DMSO the same catalyst affords 1.9 M formic acid. In both solvents the catalysts can be reused multiple times without a decrease in activity. Worldwide demand for formic acid continues to grow, especially in the context of a renewable energy hydrogen carrier, and its production from CO2 without base, via the direct catalytic carbon dioxide hydrogenation, is considerably more sustainable than the existing routes. The conversion of carbon dioxide into formic acid is attractive for energy storage and chemical production, but the typical use of bases or other additives make isolation of the free acid difficult. Here, the authors report the catalytic conversion of carbon dioxide into formic acid without the need for any additives.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hydrogen-storage materials for mobile applications
Schlapbach, L., & Züttel, A. (2001) · Nature · doi:10.1038/35104634 · Cited by 8,865
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
Aresta, M., & Dibenedetto, A. (2007) · Dalton Transactions · doi:10.1039/b700658f · Cited by 1,452
Opportunities and prospects in the chemical recycling of carbon dioxide to fuels
Centi, G., & Perathoner, S. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.07.075 · Cited by 1,449
Formic acid as a hydrogen source – recent developments and future trends
Grasemann, M., & Laurenczy, G. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21928j · Cited by 1,221
Self-citationHull, J. F., Himeda, Y., Wang, W.-H., Hashiguchi, B., Periana, R., Szalda, D. J., Muckerman, J. T., & Fujita, E. (2012) · Nature Chemistry · doi:10.1038/nchem.1295 · Cited by 936
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Tanaka, R., Yamashita, M., & Nozaki, K. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903574e · Cited by 902
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
Boddien, A., Mellmann, D., Gärtner, F., Jackstell, R., Junge, H., Dyson, P. J., Laurenczy, G., Ludwig, R., & Beller, M. (2011) · Science · doi:10.1126/science.1206613 · Cited by 832
Self-citationCarbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2
Leitner, W. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199522071 · Cited by 797
Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?
Enthaler, S., von Langermann, J., & Schmidt, T. (2010) · Energy & Environmental Science · doi:10.1039/b907569k · Cited by 753
Recent advances in the homogeneous hydrogenation of carbon dioxide
Jessop, P. G., Joó, F., & Tai, C.-C. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.05.019 · Cited by 741
Homogeneous catalytic hydrogenation of supercritical carbon dioxide
Jessop, P. G., Ikariya, T., & Noyori, R. (1994) · Nature · doi:10.1038/368231a0 · Cited by 720
Balaraman, E., Gunanathan, C., Zhang, J., Shimon, L. J. W., & Milstein, D. (2011) · Nature Chemistry · doi:10.1038/nchem.1089 · Cited by 655
Fellay, C., Dyson, P. J., & Laurenczy, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800320 · Cited by 623
Self-citationIn silico screening of carbon-capture materials
Lin, L.-C., Berger, A. H., Martin, R. L., Kim, J., Swisher, J. A., Jariwala, K., Rycroft, C. H., Bhown, A. S., Deem, M. W., Haranczyk, M., et al. (2012) · Nature Materials · doi:10.1038/nmat3336 · Cited by 563
Breakthroughs in Hydrogen Storage—Formic Acid as a Sustainable Storage Material for Hydrogen
Joó, F. (2008) · ChemSusChem · doi:10.1002/cssc.200800133 · Cited by 541
Hydrogen storage: beyond conventional methods
Dalebrook, A. F., Gan, W., Grasemann, M., Moret, S., & Laurenczy, G. (2013) · Chemical Communications · doi:10.1039/c3cc43836h · Cited by 503
Self-citationState‐of‐the‐Art Catalysts for Hydrogenation of Carbon Dioxide
Federsel, C., Jackstell, R., & Beller, M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000533 · Cited by 491
Ab initio carbon capture in open-site metal–organic frameworks
Dzubak, A. L., Lin, L.-C., Kim, J., Swisher, J. A., Poloni, R., Maximoff, S. N., Smit, B., & Gagliardi, L. (2012) · Nature Chemistry · doi:10.1038/nchem.1432 · Cited by 351
Schaub, T., & Paciello, R. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101292 · Cited by 317
Carbon Dioxide Recovery and Utilization
(2003) · Springer eBooks · doi:10.1007/978-94-017-0245-4 · Cited by 257
Selective Formic Acid Decomposition for High‐Pressure Hydrogen Generation: A Mechanistic Study
Fellay, C., Yan, N., Dyson, P. J., & Laurenczy, G. (2009) · Chemistry – A European Journal · doi:10.1002/chem.200801824 · Cited by 235
Self-citationOgo, S., Kabe, R., Hayashi, H., Harada, R., & Fukuzumi, S. (2006) · Dalton Transactions · doi:10.1039/b607993h · Cited by 214
Wesselbaum, S., Hintermair, U., & Leitner, W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203185 · Cited by 198
Barnard, J. H., Wang, C., Berry, N. G., & Xiao, J. (2013) · Chemical Science · doi:10.1039/c2sc21923a · Cited by 185
Dyson, P. J., Laurenczy, G., André Ohlin, C., Vallance, J., & Welton, T. (2003) · Chem. Commun. · doi:10.1039/b308309h · Cited by 178
Self-citationGraf, E., & Leitner, W. (1992) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39920000623 · Cited by 175
Laurenczy, G., Joó, F., & Nádasdi, L. (2000) · Inorganic Chemistry · doi:10.1021/ic000200b · Cited by 166
Self-citationTowards the development of a hydrogen battery
Boddien, A., Federsel, C., Sponholz, P., Mellmann, D., Jackstell, R., Junge, H., Laurenczy, G., & Beller, M. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22043a · Cited by 163
Self-citationA Charge/Discharge Device for Chemical Hydrogen Storage and Generation
Papp, G., Csorba, J., Laurenczy, G., & Joó, F. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201104951 · Cited by 145
Self-citationHayashi, H., Ogo, S., & Fukuzumi, S. (2004) · Chemical Communications · doi:10.1039/b411633j · Cited by 145
High-Pressure Combinatorial Screening of Homogeneous Catalysts: Hydrogenation of Carbon Dioxide
Tai, C.-C., Chang, T., Roller, B., & Jessop, P. G. (2003) · Inorganic Chemistry · doi:10.1021/ic034881x · Cited by 142
Heterogeneous Silica‐Supported Ruthenium Phosphine Catalysts for Selective Formic Acid Decomposition
Gan, W., Dyson, P. J., & Laurenczy, G. (2013) · ChemCatChem · doi:10.1002/cctc.201300246 · Cited by 80
Self-citationMoret, S., Dyson, P. J., & Laurenczy, G. (2013) · Dalton Transactions · doi:10.1039/c3dt00081h · Cited by 76
Self-citationFree formic acid by hydrogenation of carbon dioxide in sodium formate solutions
Zhao, G., & Joó, F. (2011) · Catalysis Communications · doi:10.1016/j.catcom.2011.07.017 · Cited by 67
World looks ahead post-Copenhagen
Tollefson, J. (2009) · Nature · doi:10.1038/462966a · Cited by 43
Homogeneous Hydrogenation of Carbon Dioxide
Jessop, P. G. (2006) · Wiley eBooks · doi:10.1002/9783527619382.ch17 · Cited by 26
Cited by
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
Gao, P., Li, S., Bu, X., Dang, S., Liu, Z., Wang, H., Zhong, L., Qiu, M., Yang, C., Cai, J., et al. (2017) · Nature Chemistry · doi:10.1038/nchem.2794 · Cited by 1,122
Mellmann, D., Sponholz, P., Junge, H., & Beller, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00618j · Cited by 872
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b02649 · Cited by 533
Metadata
- Authors
- Moret, S., Dyson, P. J., & Laurenczy, G.
- Venue
- Nature Communications
- Published
- 2014-06-02
- Volume
- 5
- Issue
- 1
- Pages
- 4017-4017
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2025312240
- Cited by
- 733
- References
- 36
- FWCI
- 24.72
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
