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Cited by 417

The DOI matches its Crossref record; 178 of the 178 references it cites were found in a registry or an index.

Physico-chemical processes in imidazolium ionic liquids

Dupont, Jairton, Suarez, Paulo A. Z.·2006·Physical Chemistry Chemical Physics
DOI 10.1039/b602046a
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Abstract

Among the various properties exhibited by ionic liquids (ILs)--especially those based on the imidazolium cation-their inherent ionic patterns, very low vapour pressure and pronounced self-organization in the solid, liquid and even in the gas phase are particularly interesting since this allows the use of these fluids as alternative and complementary media to classical organic solvents and water in many applications. Hence, reaction paths that involve charge-separated intermediates or transition states are accelerated--by lowering the activation barrier-in the presence of ILs when compared with those performed in classical organic solvents. It is also possible, for example, to observe, by electrochemical methods, transient species (ionic and radical) that are otherwise undetectible in water or in molecular organic solvents and to investigate the interactions and behaviour of molecular, biological and macromolecular species in solution using physical and chemical methods which require special conditions such as high-vacuum, and which have been traditionally limited to solid state chemistry.

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Metadata

Authors
Dupont, J., & Suarez, P. A. Z.
Venue
Physical Chemistry Chemical Physics
Publisher
Royal Society of Chemistry (RSC)
Published
2006
Volume
8
Issue
21
Pages
2441
ISSN
  • 1463-9076 (ISSN-L)
  • 1463-9084
DOI
10.1039/b602046a
OpenAlex
W2076565225
Cited by
417
References
178
FWCI
20.66
Type
journal article
Language
en
Open access
closed

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