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End group removal and modification of RAFT polymers

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Willcock, Helen, O'Reilly, Rachel K.·2010·Polym. Chem.

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Abstract

This paper describes both well-established routes and recent advances in the end group modification of polymers synthesised by reversible addition–fragmentation chain transfer (RAFT) polymerisation. The lability of the thiocarbonylthio group, which facilitates the RAFT mechanism, allows for ready post-polymerisation functionalisation of RAFT polymers by a number of techniques. In particular, end group thermolysis, radical induced reduction, hetero-Diels–Alder reactions and reaction with nucleophiles are discussed as are the applications and limitations of each method. The versatility of RAFT as a polymerisation tool for the synthesis of polymers with functional end groups for a range of applications is demonstrated.

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See all 607

Authors: Willcock, H., & O'Reilly, R. K.
Venue: Polym. Chem.
Publisher: Royal Society of Chemistry (RSC)
Published: 2010
Volume: 1
Issue: 2
Pages: 149-157
ISSN: 1759-9954 (ISSN-L)
1759-9962
DOI: 10.1039/b9py00340a
OpenAlex: W2113752987
Cited by: 607
References: 79
FWCI: 11.97
Type: journal article
Language: en
Open access: green

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End group removal and modification of RAFT polymers

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