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Cited by 400

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Single site catalysts for stereoselective ring-opening polymerization of lactides

Dijkstra, Pieter Jelle, Du, Hongzhi, Feijen, Jan·2011·Polym. Chem.
DOI 10.1039/c0py00204f
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Abstract

Poly(lactide) (PLA) is the most well known biodegradable and biocompatible material among the aliphatic polyesters nowadays explored for biomedical, pharmaceutical and environmental applications. Different poly(lactide)s are distinguished, namely stereoregular PLLA and PDLA, atactic, heterotactic, syndiotactic and stereoblock PLAs. Because the stereochemistry of the monomeric units in the polymer chains plays a decisive role in the mechanical, physical and degradation properties of PLA materials, stereospecific catalysts to prepare different polylactide architectures are a major topic. In this review, after a general introduction on metal catalyzed ring opening polymerization, we mainly focus on single site catalyst systems inducing stereoselective polymerization of lactides.

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Cited by

Metadata

Authors
Dijkstra, P. J., Du, H., & Feijen, J.
Venue
Polym. Chem.
Publisher
Royal Society of Chemistry (RSC)
Published
2011
Volume
2
Issue
3
Pages
520-527
ISSN
  • 1759-9954 (ISSN-L)
  • 1759-9962
DOI
10.1039/c0py00204f
OpenAlex
W2044711120
Cited by
400
References
8
FWCI
10.13
Type
journal article
Language
en
Open access
closed

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