Sn nanoparticles on gas diffusion electrodes: Synthesis, characterization and use for continuous CO 2 electroreduction to formate

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works

Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel

Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865 · see citing works

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594 · see citing works

Formic acid as a hydrogen source – recent developments and future trends

Grasemann, M., & Laurenczy, G. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21928j · Cited by 1,229 · see citing works

Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate

Zhang, S., Kang, P., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113885 · Cited by 1,150 · see citing works

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities

Jhong, H. “., Ma, S., & Kenis, P. J. A. (2013) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2013.03.005 · Cited by 824 · see citing works

Electrochemical CO2 reduction: Electrocatalyst, reaction mechanism, and process engineering

Lu, Q., & Jiao, F. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.009 · Cited by 817 · see citing works

The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility

Agarwal, A. S., Zhai, Y., Hill, D., & Sridhar, N. (2011) · ChemSusChem · doi:10.1002/cssc.201100220 · Cited by 573 · see citing works

Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway

Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541 · see citing works

Towards the electrochemical conversion of carbon dioxide into methanol

Albo, J., Álvarez-Guerra, M., Castaño, P., & Irabien, Á. (2015) · Green Chemistry · doi:10.1039/c4gc02453b · Cited by 533 · see citing works

Electrochemical CO₂ Reduction: Recent Advances and Current Trends

Jones, J., Prakash, G. K. S., & Olah, G. A. (2014) · Israel Journal of Chemistry · doi:10.1002/ijch.201400081 · Cited by 425 · see citing works

Towards sustainable fuels and chemicals through the electrochemical reduction of CO 2 : lessons from water electrolysis

Martín, A. J., Larrazábal, G. O., & Pérez‐Ramírez, J. (2015) · Green Chemistry · doi:10.1039/c5gc01893e · Cited by 361 · see citing works

Controlling H + vs CO 2 Reduction Selectivity on Pb Electrodes

Lee, C. H., & Kanan, M. W. (2014) · ACS Catalysis · doi:10.1021/cs5017672 · Cited by 341 · see citing works

Production of methanol from CO2 electroreduction at Cu2O and Cu2O/ZnO-based electrodes in aqueous solution

Albo, J., Sáez, A., Solla‐Gullón, J., Montiel, V., & Irabien, Á. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.04.055 · Cited by 313 · see citing works

Monitoring the Chemical State of Catalysts for CO 2 Electroreduction: An In Operando Study

Dutta, A., Kuzume, A., Rahaman, M., Vesztergom, S., & Broekmann, P. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02322 · Cited by 302 · see citing works

Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol

Albo, J., & Irabien, Á. (2015) · Journal of Catalysis · doi:10.1016/j.jcat.2015.11.014 · Cited by 289 · see citing works

Electrochemical Processing of Carbon Dioxide

Oloman, C. W., & Li, H. (2008) · ChemSusChem · doi:10.1002/cssc.200800015 · Cited by 288 · see citing works

Rational Design of a Hierarchical Tin Dendrite Electrode for Efficient Electrochemical Reduction of CO 2

Won, D. H., Choi, C. H., Chung, J., Chung, M. W., Kim, E., & Woo, S. I. (2015) · ChemSusChem · doi:10.1002/cssc.201500694 · Cited by 268 · see citing works

Rapid Selective Electrocatalytic Reduction of Carbon Dioxide to Formate by an Iridium Pincer Catalyst Immobilized on Carbon Nanotube Electrodes

Kang, P., Zhang, S., Meyer, T. J., & Brookhart, M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201310722 · Cited by 267 · see citing works

Direct formate fuel cells: A review

An, L., & Chen, R. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.04.082 · Cited by 251 · see citing works

Sustainable energy: a review of formic acid electrochemical fuel cells

Rees, N. V., & Compton, R. G. (2011) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-011-1398-4 · Cited by 225 · see citing works

Ionic liquids in the electrochemical valorisation of CO 2

Álvarez-Guerra, M., Albo, J., Alvarez‐Guerra, E., & Irabien, Á. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01486g · Cited by 201 · see citing works

Electrochemical reduction of CO2 to formate in aqueous solution using electro-deposited Sn catalysts

Zhao, C., & Wang, J. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.02.084 · Cited by 187 · see citing works

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes

Kopljar, D., Inan, A., Vindayer, P., Wagner, N., & Klemm, E. (2014) · Journal of Applied Electrochemistry · doi:10.1007/s10800-014-0731-x · Cited by 178 · cited 3× · see citing works

Electrochemical reduction of carbon dioxide III. The role of oxide layer thickness on the performance of Sn electrode in a full electrochemical cell

Wu, J., Risalvato, F. G., Ma, S., & Zhou, X. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta13544f · Cited by 168 · see citing works

Electrochemical CO2 reduction to formic acid on a Pd-based formic acid oxidation catalyst

Kortlever, R., Balemans, C., Kwon, Y., & Koper, M. T. M. (2014) · Catalysis Today · doi:10.1016/j.cattod.2014.08.001 · Cited by 160 · see citing works

Electrocatalytic reduction of CO2 to formate using particulate Sn electrodes: Effect of metal loading and particle size

Castillo, A. D., Álvarez-Guerra, M., Solla‐Gullón, J., Sáez, A., Montiel, V., & Irabien, Á. (2015) · Applied Energy · doi:10.1016/j.apenergy.2015.08.012 · Cited by 137 · see citing works

Alkaline CO2 Electrolysis toward Selective and Continuous HCOO– Production over SnO2 Nanocatalysts

Lee, S., Ocon, J. D., Son, Y.-I., & Lee, J. (2015) · The Journal of Physical Chemistry C · doi:10.1021/jp512436w · Cited by 136 · see citing works

Experimental and theoretical investigations of adsorption of fexofenadine at mild steel/hydrochloric acid interface as corrosion inhibitor

Ahamad, I., Prasad, R., & Quraishi, M. A. (2010) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-010-1041-9 · Cited by 131 · see citing works

Electrochemical reduction of carbon dioxide: IV dependence of the Faradaic efficiency and current density on the microstructure and thickness of tin electrode

Wu, J., Sharma, P. P., Harris, B., & Zhou, X. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.02.014 · Cited by 128 · see citing works

Development of a continuous reactor for the electro-reduction of carbon dioxide to formate – Part 1: Process variables

Li, H., & Oloman, C. W. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-006-9194-z · Cited by 127 · see citing works

Development of rolling tin gas diffusion electrode for carbon dioxide electrochemical reduction to produce formate in aqueous electrolyte

Wang, Q., Dong, H., & Yu, H. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.08.017 · Cited by 126 · see citing works

Sustainable production of formic acid by electrolytic reduction of gaseous carbon dioxide

Lee, S., Ju, H., Machunda, R. L., et al. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta03893b · Cited by 125 · see citing works

Electrochemical membrane reactors for the utilisation of carbon dioxide

Merino‐Garcia, I., Alvarez‐Guerra, E., Albo, J., & Irabien, Á. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.05.032 · Cited by 125 · see citing works

Anodic passivation of tin in slightly alkaline solutions

Kapusta, S. D., & Hackerman, N. (1980) · Electrochimica Acta · doi:10.1016/0013-4686(80)80016-8 · Cited by 117 · see citing works

Electrochemical Reduction of Carbon Dioxide

Wu, J., Risalvato, F. G., Sharma, P. P., Pellechia, P. J., Ke, F., & Zhou, X. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.030309jes · Cited by 106 · see citing works

Enhanced performance of gas diffusion electrode for electrochemical reduction of carbon dioxide to formate by adding polytetrafluoroethylene into catalyst layer

Wang, Q., Dong, H., Yu, H. N., & Yu, H. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.12.118 · Cited by 106 · see citing works

Electrochemical reduction of carbon dioxide to formic acid at a tin cathode in divided and undivided cells: effect of carbon dioxide pressure and other operating parameters

Scialdone, O., Galia, A., Nero, G. L., Proietto, F., Sabatino, S., & Schiavo, B. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.02.079 · Cited by 103 · see citing works

Continuous electrochemical reduction of carbon dioxide into formate using a tin cathode: Comparison with lead cathode

Álvarez-Guerra, M., Castillo, A., & Irabien, Á. (2013) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2013.11.002 · Cited by 102 · see citing works

Effect of solution pH on CO: formate formation rates during electrochemical reduction of aqueous CO2 at Sn cathodes

Bumroongsakulsawat, P., & Kelsall, G. H. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.07.057 · Cited by 102 · see citing works

Electrocatalytic reduction of carbon dioxide on indium coated gas diffusion electrodes—Comparison with indium foil

Bitar, Z., Fécant, A., Trela-Baudot, E., Chardon‐Noblat, S., & Pasquier, D. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.02.041 · Cited by 100 · see citing works

Global warming footprint of the electrochemical reduction of carbon dioxide to formate

Domínguez-Ramos, A., Singh, B., Zhang, X., Hertwich, E. G., & Irabien, Á. (2013) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2013.11.046 · Cited by 99 · see citing works

Effect of cationic and anionic solid polymer electrolyte on direct electrochemical reduction of gaseous CO2 to fuel

Aeshala, L. M., Uppaluri, R. G., & Verma, A. (2013) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2013.09.004 · Cited by 99 · see citing works

Novel hierarchical SnO2 microsphere catalyst coated on gas diffusion electrode for enhancing energy efficiency of CO2 reduction to formate fuel

Fu, Y., Li, Y., Zhang, X., Liu, Y., Qiao, J., Zhang, J., & Wilkinson, D. P. (2016) · Applied Energy · doi:10.1016/j.apenergy.2016.03.115 · Cited by 97 · see citing works

Direct Reduction of Carbon Dioxide to Formate in High‐Gas‐Capacity Ionic Liquids at Post‐Transition‐Metal Electrodes

Watkins, J. D., & Bocarsly, A. B. (2013) · ChemSusChem · doi:10.1002/cssc.201300659 · Cited by 96 · see citing works

Continuous electroreduction of CO 2 to formate using Sn gas diffusion electrodes

Castillo, A., Álvarez-Guerra, M., & Irabien, Á. (2014) · AIChE Journal · doi:10.1002/aic.14544 · Cited by 89 · see citing works

Electrochemical Reduction of Carbon Dioxide

Hudson, M. R. (2016) · CRC Press eBooks · doi:10.1201/b20177 · Cited by 84 · see citing works

Degradation and deactivation of Sn catalyst used for CO2 reduction as function of overpotential

Anawati, Frankel, G. S., Agarwal, A. S., et al. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.04.057 · Cited by 75 · see citing works

Fabrication of a novel tin gas diffusion electrode for electrochemical reduction of carbon dioxide to formic acid

Wang, Q., Dong, H., & Yu, H. (2014) · RSC Advances · doi:10.1039/c4ra10775f · Cited by 68 · see citing works

Porous tin-based film deposited on copper foil for electrochemical reduction of carbon dioxide to formate

Lv, W., Zhou, J., Kong, F., et al. (2015) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2015.11.100 · Cited by 64 · see citing works

Mechanistic insights into the Cu(I) oxide-catalyzed conversion of CO 2 to fuels and chemicals: A DFT approach

Mishra, A. K., & de Leeuw, N. H. (2016) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2016.02.008 · Cited by 48 · see citing works

Electrochemical Reduction of Carbon Dioxide on Cu/CuO Core/Shell Catalysts

Lan, Y., Gai, C., Kenis, P. J. A., & Lu, J. (2014) · ChemElectroChem · doi:10.1002/celc.201402182 · Cited by 44 · see citing works

Synthesis of Pb 2 O electrocatalyst and its application in the electrochemical reduction of CO 2 to HCOOH in various electrolytes

Yadav, V. S. K., & Purkait, M. K. (2015) · RSC Advances · doi:10.1039/c5ra05899f · Cited by 32 · see citing works

Electrochemical reduction of CO 2 to HCOOH on a synthesized Sn electrocatalyst using a Co 3 O 4 anode

Yadav, V. S. K., & Purkait, M. K. (2015) · RSC Advances · doi:10.1039/c5ra12369k · Cited by 25 · see citing works

Reduction synthesis of tin nanoparticles using various precursors and melting behavior

Chee, S., & Lee, J. (2012) · Electronic Materials Letters · doi:10.1007/s13391-012-2086-y · Cited by 23 · see citing works

3‐D Tin‐Carbon Fiber Paper Electrodes for Electrochemically Converting CO 2 to Formate/Formic Acid

Guan, S., Agarwal, A. S., Rode, E. J., Hill, D. M., & Sridhar, N. (2013) · Ceramic transactions /Ceramic transactions · doi:10.1002/9781118751176.ch23 · Cited by 8 · see citing works

Electrochemical CO ₂ Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works

Stable and Highly Efficient Electrochemical Production of Formic Acid from Carbon Dioxide Using Diamond Electrodes

Natsui, K., Iwakawa, H., Ikemiya, N., Nakata, K., & Einaga, Y. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712271 · Cited by 166 · see citing works

Tailoring gas-phase CO ₂ electroreduction selectivity to hydrocarbons at Cu nanoparticles

Merino-Garcia, I., Albo, J., & Irabien, A. (2018) · Nanotechnology · doi:10.1088/1361-6528/aa994e · Cited by 129 · see citing works

Electrochemical conversion of CO2 to HCOOH at tin cathode in a pressurized undivided filter-press cell

Proietto, F., Schiavo, B., Galia, A., & Scialdone, O. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.04.159 · Cited by 67 · see citing works

Catholyte‐Free Electrocatalytic CO₂ Reduction to Formate

Lee, W., Kim, Y. E., Youn, M. H., Jeong, S. K., & Park, K. T. (2018) · Angewandte Chemie · doi:10.1002/ange.201803501 · Cited by 31 · see citing works

Evidence for Isotopic Exchange during Metabolism of Stable-Isotope-Labeled Formate in a Methanogenic Sediment

de Graaf, W., & Cappenberg, T. E. (1996) · Applied and Environmental Microbiology · doi:10.1128/aem.62.9.3535-3537.1996 · Cited by 15 · see citing works

Scanning Tunneling Microscopy Study of Formate Species Synthesized from CO2Hydrogenation and Prepared by Adsorption of Formic Acid over Cu(111)

Fujitani, T., Choi, Y. W., Sano, M., et al. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp9920242 · Cited by 61 · see citing works

Structure of the Formate Ion

Small, P. A., & Wolfenden, J. H. (1936) · Nature · doi:10.1038/137781a0 · Cited by 3 · see citing works

Formate production and utilization by methanogens and by sewage sludge consortia — interference with the concept of interspecies formate transfer

Bleicher, K., & Winter, J. U. (1994) · Applied Microbiology and Biotechnology · doi:10.1007/bf00173998 · Cited by 31 · see citing works

Formate production and utilization by methanogens and by sewage sludge consortia ? interference with the concept of interspecies formate transfer

Bleicher, K., & Winter, J. U. (1994) · Applied Microbiology and Biotechnology · doi:10.1007/s002530050090 · Cited by 3 · see citing works