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Selective O -acyl ring-opening of β-butyrolactone catalyzed by trifluoromethane sulfonic acid: application to the preparation of well-defined block copolymers
Abstract
HOTf catalyzes ring-opening of β-butyrolactone selectively via O -acyl bond cleavage, enabling efficient copolymerization.
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“One of the reasons of this lack can be explained by the divergent reactivity of monomers according to the catalytic mechanism employed, notably in the case of electrophilic or nucleophilic activations [10, 11].”
From A simple and general approach for the synthesis of biodegradable triblock copolymers by organocatalytic ROP from poly(lactide) macroinitiators (2020) · cites this paper as [11]
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Metadata
- Authors
- Couffin, A., Martín-Vaca, B., Bourissou, D., & Navarro, C.
- Affiliations
- University of Toulouse
- Arkema
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 5
- Issue
- 1
- Pages
- 161-168
- ISSN
- 1759-9954
- 1759-9962
- Cited by
- 44
- References
- 83
- Language
- en
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