The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Insights into the electrocatalytic reduction of CO2on metallic silver surfaces
Abstract
The electrochemical reduction of CO2 could allow for a sustainable process by which renewable energy from wind and solar are used directly in the production of fuels and chemicals. In this work we investigated the potential dependent activity and selectivity of the electrochemical reduction of CO2 on metallic silver surfaces under ambient conditions. Our results deepen our understanding of the surface chemistry and provide insight into the factors important to designing better catalysts for the reaction. The high sensitivity of our experimental methods for identifying and quantifying products of reaction allowed for the observation of six reduction products including CO and hydrogen as major products and formate, methane, methanol, and ethanol as minor products. By quantifying the potential-dependent behavior of all products, we provide insights into kinetics and mechanisms at play, in particular involving the production of hydrocarbons and alcohols on catalysts with weak CO binding energy as well as the formation of a C-C bond required to produce ethanol.
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Cites
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New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
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Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO 2 over Ag and Cu
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Metadata
- Authors
- Hatsukade, T., Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F.
- Venue
- Phys. Chem. Chem. Phys.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 16
- Issue
- 27
- Pages
- 13814-13819
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2012726087
- Cited by
- 578
- References
- 6
- FWCI
- 13.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hatsukade, T., Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2014). Insights into the electrocatalytic reduction of CO2on metallic silver surfaces. Phys. Chem. Chem. Phys. https://doi.org/10.1039/c4cp00692e
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