Correction for the 17O interference in δ(13C) measurements when analyzing CO2 with stable isotope mass spectrometry (IUPAC Technical Report)

Brand, Willi A.; Assonov, Sergey S.; Coplen, Tyler B.

doi:10.1351/pac-rep-09-01-05

Cited by 385Atmospheric and Environmental Gas DynamicsScientific Measurement and Uncertainty EvaluationGroundwater and Isotope Geochemistry

Correction for the 17O interference in δ(13C) measurements when analyzing CO2 with stable isotope mass spectrometry (IUPAC Technical Report)

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Brand, Willi A., Assonov, Sergey S., Coplen, Tyler B.·2010·Pure and Applied Chemistry

DOI 10.1351/pac-rep-09-01-05

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Abstract

Measurements of δ( 13 C) determined on CO 2 with an isotope-ratio mass spectrometer (IRMS) must be corrected for the amount of 17 O in the CO 2 . For data consistency, this must be done using identical methods by different laboratories. This report aims at unifying data treatment for CO 2 IRMS by proposing (i) a unified set of numerical values, and (ii) a unified correction algorithm, based on a simple, linear approximation formula. Because the oxygen of natural CO 2 is derived mostly from the global water pool, it is recommended that a value of 0.528 be employed for the factor λ, which relates differences in 17 O and 18 O abundances. With the currently accepted N ( 13 C)/ N ( 12 C) of 0.011 180(28) in VPDB (Vienna Peedee belemnite) reevaluation of data yields a value of 0.000 393(1) for the oxygen isotope ratio N ( 17 O)/ N ( 16 O) of the evolved CO 2 . The ratio of these quantities, a ratio of isotope ratios, is essential for the 17 O abundance correction: [ N ( 17 O)/ N ( 16 O)]/[ N ( 13 C)/ N ( 12 C)] = 0.035 16(8). The equation [δ( 13 C) ≍ 45 δ VPDB-CO2 + 2 17 R / 13 R ( 45 δ VPDB-CO2 – λ 46 δ VPDB-CO2 )] closely approximates δ( 13 C) values with less than 0.010 ‰ deviation for normal oxygen-bearing materials and no more than 0.026 ‰ in extreme cases. Other materials containing oxygen of non-mass-dependent isotope composition require a more specific data treatment. A similar linear approximation is also suggested for δ( 18 O). The linear approximations are easy to implement in a data spreadsheet, and also help in generating a simplified uncertainty budget.

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Raw Δ47 values were calculated using the 17O calibration parameters reported in ref. 53, which have been shown to improve interlaboratory data consistency.
“Due to the possible large uncertainties related to Assonov 17 O calibration parameters (50-53), we calculated raw Δ 47 values using the 17 O calibration parameters reported in ref. 53, which have been shown to improve interlaboratory data consistency (54).”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [53]
The interlaboratory bias correction of the dolomite temperature calibration based on a single standard may not be optimal, but it is still better for Δ47 temperature calculations than direct use of the original calibration in ref. 50.
“The preceding interlaboratory bias correction of the temperature calibration for dolomites based on a single standard may not be optimal, but it is still better for Δ 47 temperature calculations than direct use of the original calibration in ref. 50, which was not given in the Brand parametric framework nor calibrated to the ETH standard values reported in ref. 53.”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [53]
The Summary and Practical Implementation section (pp. 1729–1730) describes a framework for correcting and calibrating CO₂ isotope measurements. It does not address dolomite Δ47 temperature calibrations or compare a single-standard interlaboratory correction with direct use of an original calibration. Searches for those terms found no passage that evaluates the claimed comparison. (LLM, conf=0.75)
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Research works printed but not linked: 27

H. Craig. Geochim. Cosmochim. Acta 12, 133 (1957).
J. Santrock, S. A. Studley, J. M. Hayes. Anal. Chem. 57, 1444 (1985).
C. E. Allison, R. J. Francey, H. A. J. Meijer. In Reference and Intercomparison Materials for Stable Isotopes of Light Elements, IAEA-TECDOC-825, pp. 155-162, International Atomic Energy Agency, Vienna (1995).
M. F. Miller, I. A. Franchi, A. S. Sexton, C. T. Pillinger. Rapid Commun. Mass Spectrom. 13, 1211 (1999).
H. A. J. Meijer, W. J. Li. Isot. Environ. Health Stud. 34, 349 (1998).
S. S. Assonov, C. A. M. Brenninkmeijer. Rapid Commun. Mass Spectrom. 15, 2426 (2001).
E. Barkan, B. Luz. Rapid Commun. Mass Spectrom. 19, 3737 (2005).
B. Luz, E. Barkan. Geochim. Cosmochim. Acta 69, 1099 (2005).
J. Kaiser. Geochim. Cosmochim. Acta 72, 1312 (2009).
S. S. Assonov, C. A. M. Brenninkmeijer. Rapid Commun. Mass Spectrom. 19, 627 (2005).
Y. Matsuhisa, J. R. Goldsmith, R. N. Clayton. Geochim. Cosmochim. Acta 42, 173 (1978).
E. D. Young, A. Galy, H. Nagahara. Geochim. Cosmochim. Acta 66, 1095 (2002).
A. Landais, E. Barkan, B. Luz. Geophys. Res. Lett. 35, L02709 (2008).
M. F. Miller. Geochim. Cosmochim. Acta 66, 1881 (2002).
M. F. Miller, I. A. Franchi, M. H. Thiemens, T. L. Jackson, A. Brack, G. Kurat, C. T. Pillinger. Proc. Natl. Acad. Sci. USA 99, 10988 (2002).
S. S. Assonov, C. A. M. Brenninkmeijer. Rapid Commun. Mass Spectrom. 17, 1007 (2003).
S. S. Assonov, C. A. M. Brenninkmeijer. Rapid Commun. Mass Spectrom. 17, 1017 (2003).
W. Li, B. Ni, D. Jin, Q. Zhang. Kexue Tongbao (Chin. Sci. Bull., Engl. transl.) 33, 1610 (1988).
T.-L. Chang, W. Li. Chin. Sci. Bull. 35, 290 (1990).
K. J. R. Rosman, P. D. P. Taylor. Pure Appl. Chem. 70, 217 (1998).
R. M. Verkouteren, J. N. Lee. Fresenius' J. Anal. Chem. 370, 803 (2001). <http://www.nist.gov/widps-co2>.
R. Gonfiantini, W. Stichler, K. Rozanski. In Reference and Intercomparison Materials for Stable Isotopes of Light Elements, IAEA-TECDOC-825, pp. 13-29, International Atomic Energy Agency, Vienna (1995).
P. Baertschi. Earth Planet. Sci. Lett. 31, 341 (1976).
T. B. Coplen, C. Kendall, J. Hopple. Nature 302, 236 (1983). This paper recommends the use of +30.91 ‰ for VPDB relative to VSMOW. However, NBS 19 was measured and reported as -2.19 ‰ relative to PDB. Correction of this value to -2.2 ‰ leads to the revised value of +30.92 ‰ relative to VPDB (see also ref. [25]).
R. A. Werner, W. A. Brand. Rapid Comm. Mass Spectrom. 15, 501 (2001).
M. H. Thiemens, T. L. Jackson, C. A. M. Brenninkmeijer. Geophys. Res. Lett. 22, 255 (1995).
W. A. Brand, L. Huang, H. Mukai, A. Chivulescu, J. M. Richter, M. Rothe. Rapid Commun. Mass Spectrom. 23, 915 (2009).

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Levitt, N. P., Eiler, J. M., Romanek, C. S., Beard, B. L., Xu, H., & Johnson, C. M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007089 · Cited by 48 · see citing works
Constraints on the vital effect in coccolithophore and dinoflagellate calcite by oxygen isotopic modification of seawater
Hermoso, M., Horner, T. J., Minoletti, F., & Rickaby, R. E. M. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.05.002 · Cited by 51 · see citing works
“Carbon isotope composition 13 The co-addition of 17O in the medium also has an effect on the determination of the 45CO2/44CO2 and 46CO2/44CO2, and hence on δ13CDIC and δ13Cc (Santrock et al., 1985; Brand et al., 2010).”
Coupling Δ47 and fluid inclusion thermometry on carbonate cements to precisely reconstruct the temperature, salinity and δ18O of paleo-groundwater in sedimentary basins
Mangenot, X., Bonifacie, M., Gasparrini, M., Götz, A., Chaduteau, C., Ader, M., & Rouchon, V. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.10.011 · Cited by 51 · see citing works
“Note that using the 17 O parameters from Brand et al. (2010) would only lead to small differences in 47 values of both of our standards and samples (ie. less than ±0.010‰), well within the analytical uncertainty on Δ47 measurements.”
Influential
A 600-Million-Year Carbonate Clumped-Isotope Record from the Sultanate of Oman
Bergmann, K. D., Al Balushi, S. A. K., Mackey, T. J., Grotzinger, J. P., & Eiler, J. M. (2018) · Journal of Sedimentary Research · doi:10.2110/jsr.2018.51 · Cited by 46 · see citing works
“%) using the correction parameters from Huntington et al. (2009) compared to those from Brand et al. (2010) (Table 4).”
Method
Absolute 13C/12C Isotope Amount Ratio for Vienna Pee Dee Belemnite from Infrared Absorption Spectroscopy
Fleisher, A., Yi, H.-M., Srivastava, A., Polyansky, O., Zobov, N., & Hodges, J. (2021) · Nature Physics · doi:10.1038/s41567-021-01226-y · Cited by 46 · see citing works
Laboratory-grown coccoliths exhibit no vital effect in clumped isotope (Δ47) composition on a range of geologically relevant temperatures
Katz, A., Bonifacie, M., Hermoso, M., Cartigny, P., & Calmels, D. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.025 · Cited by 44 · see citing works
“…the choice of appropriate parameters accounting for the 17O interferences in d13C determination (e.g., parameters from Santrock et al., 1985 or Brand et al., 2010), and/or the stability/accuracy of the frames constructed to correct raw ∆47 values from the effects of non-linearity and…”
Background
Clumped-isotope palaeothermometry and LA-ICP-MS U–Pb dating of lava-pile hydrothermal calcite veins
MacDonald, J., Faithfull, J., Roberts, N. M. W., Davies, A., Holdsworth, C., Newton, M., Williamson, S., Boyce, A. J., & John, C. M. (2019) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-019-1599-x · Cited by 61 · see citing works
A high yield cellulose extraction system for small whole wood samples and dual measurement of carbon and oxygen stable isotopes
Andreu-Hayles, L., Lévesque, M., Martin‐Benito, D., Huang, W., Harris, R. A., Oelkers, R., Leland, C., Fernández, J. M., Anchukaitis, K., & Helle, G. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2018.09.007 · Cited by 45 · see citing works
“(6)) in a more complex way that also includes an automatic correction of 17O (Brand et al., 2010).”
BackgroundMethod
High-precision measurements of δ(17)O and (17) Oexcess of NBS19 and NBS18.
Barkan, E., Musan, I., & Luz, B. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7378 · Cited by 45 · see citing works
Abundances of isotopologues and calibration of CO 2 greenhouse gas measurements
Tans, P., Crotwell, A., & Thoning, K. (2017) · Atmospheric measurement techniques · doi:10.5194/amt-10-2669-2017 · Cited by 44 · see citing works
“For more detailed descriptions of this relationship see Santrock et al. (1985), Assonov and Brenninkmeijer (2003), Brand et al. (2010) and references therein.”
Background
Stable carbon isotope ratio analysis of anhydrosugars in biomass burning aerosol particles from source samples.
Sang, X.-F., Gensch, I., Laumer, W., Kammer, B., Chan, C., Engling, G., Wahner, A., Wissel, H., & Kiendler-Scharr, A. (2012) · Environmental Science and Technology · doi:10.1021/es204094v · Cited by 44 · see citing works
A stable isotope toolbox for water and inorganic carbon cycle studies
Hillaire-Marcel, C., Kim, S.-T., Landais, A., Ghosh, P., Assonov, S., Lécuyer, C., Blanchard, M., Meijer, H. A. J., & Steen-Larsen, H. C. (2021) · Nature Reviews Earth & Environment · doi:10.1038/s43017-021-00209-0 · Cited by 43 · see citing works
Self-citation
Jena Reference Air Set (JRAS): a multi-point scale anchor for isotope measurements of CO 2 in air
Wendeberg, M., Richter, J., Rothe, M., & Brand, W. (2012) · Atmospheric measurement techniques · doi:10.5194/amt-6-817-2013 · Cited by 43 · see citing works
“Factors contributing to the uncertainty are the correction for N2O present in the analyzed gas (Sirignano et al., 2004; Ghosh and Brand, 2004), the δ18O value used for digesting the calcite during standardization (Wendeberg et al., 2011) and the 17O correction (Brand et al., 2010).”
BackgroundMethodSelf-citation
Temperature seasonality in the North American continental interior during the Early Eocene Climatic Optimum
Hyland, E., Huntington, K., Sheldon, N., & Reichgelt, T. (2018) · Climate of the Past · doi:10.5194/cp-14-1391-2018 · Cited by 42 · see citing works
“Following recent work (Daëron et al., 2016; Schauer et al., 2016), mass spectrometer data are corrected using the 17O correction values recommended by Brand et al. (2010).”
Method
Revisiting the equable climate problem during the Late Cretaceous greenhouse using paleosol carbonate clumped isotope temperatures from the Campanian of the Western Interior Basin, USA
Burgener, L., Hyland, E., Huntington, K. W., Kelson, J. R., & Sewall, J. O. (2019) · Palaeogeography, Palaeoclimatology, Palaeoecology · doi:10.1016/j.palaeo.2018.12.004 · Cited by 52 · see citing works
Carbon isotope evidence for the substrates and mechanisms of prebiotic synthesis in the early solar system
Chimiak, L., Elsila, J., Dallas, B., Dworkin, J., Aponte, J., Sessions, A., & Eiler, J. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.09.026 · Cited by 39 · see citing works
Travertine deposits constraining transfer zone neotectonics in geothermal areas: An example from the inner Northern Apennines (Bagno Vignoni-Val d’Orcia area, Italy)
Brogi, A., Liotta, D., Capezzuoli, E., Matera, P. F., Kele, S., Soligo, M., Tuccimei, P., Ruggieri, G., Yu, T.-L., Shen, C.-C., et al. (2020) · Geothermics · doi:10.1016/j.geothermics.2019.101763 · Cited by 38 · see citing works
“(2016), IUPAC parameters were used to correct for 17O interference (Brand et al., 2010).”
Method
Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer
Adnew, G., Hofmann, M., Paul, D., Laskar, A., Surma, J., Albrecht, N., Pack, A., Schwieters, J., Koren, G., Peters, W., et al. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8478 · Cited by 38
“In this study we used a λ value of 0.528 to calculate the Δ17O of CO2 following Barkan and co‐workers6,7 and the 17O‐correction algorithm by Brand et al.8 Δ17O ¼ ln δ17Oþ 1 − λ ln δ18Oþ 1 (4) Since the discovery of mass‐independent fractionation,9 the Δ17O value has been used to study sources/sinks of atmospheric trac…”
MethodInfluential
Eastern Mediterranean climate change deduced from the Soreq Cave fluid inclusion stable isotopes and carbonate clumped isotopes record of the last 160 ka
Matthews, A., Affek, H., Ayalon, A., Vonhof, H., & Bar-Matthews, M. (2021) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2021.107223 · Cited by 36 · see citing works
Calibration Strategies for FT-IR and Other Isotope Ratio Infrared Spectrometer Instruments for Accurate δ13C and δ18O Measurements of CO2 in Air.
Flores, E., Viallon, J., Moussay, P., Griffith, D., & Wielgosz, R. (2017) · Analytical Chemistry · doi:10.1021/acs.analchem.6b05063 · Cited by 35
Why Measure 17O? Historical Perspective, Triple-Isotope Systematics and Selected Applications
Miller, M. F., & Pack, A. (2021) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2021.86.01 · Cited by 35 · see citing works
Carbonate clumped isotope analysis (Δ 47 ) of 21 carbonate standards determined via gas‐source isotope‐ratio mass spectrometry on four instrumental configurations using carbonate‐based standardization and multiyear data sets
Upadhyay, D., Lucarelli, J., Arnold, A., Flores, R., Bricker, H., Ulrich, R. N., Jesmok, G., Santi, L., Defliese, W., Eagle, R. A., et al. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9143 · Cited by 33 · see citing works
A calibration equation between Δ 48 values of carbonate and temperature
Swart, P. K., Lu, C., Moore, E. W., Smith, M. E., Murray, S. T., & Staudigel, P. T. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9147 · Cited by 40 · see citing works
Reconsidering the uplift history and peneplanation of the northern Lhasa terrane, Tibet
Ingalls, M., Rowley, D. B., Currie, B. S., & Colman, A. S. (2020) · American Journal of Science · doi:10.2475/06.2020.01 · Cited by 38 · see citing works
Reconstructing carbonate alteration histories in orogenic sedimentary basins: Xigaze forearc, southern Tibet
Ingalls, M. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.02.005 · Cited by 30 · see citing works
Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates
Hudson, A. M., Quade, J., Ali, G., Boyle, D., Bassett, S., Huntington, K. W., De los Santos, M. G., Cohen, A. S., Lin, K., & Wang, X. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.06.024 · Cited by 32 · see citing works
“Insufficient data are available to recalculate previously published calibration samples using the Brand et al. (2010) correction at this time.”
MethodResultInfluential
Prehistoric cooking versus accurate palaeotemperature records in shell midden constituents
Müller, P., Staudigel, P., Murray, S., Vernet, R., Barusseau, J., Westphal, H., & Swart, P. (2017) · Scientific Reports · doi:10.1038/s41598-017-03715-8 · Cited by 32 · see citing works
Rapid and precise measurement of carbonate clumped isotopes using laser spectroscopy
Yanay, N., Wang, Z., Dettman, D. L., Quade, J., Huntington, K. W., Schauer, A. J., Nelson, D. D., McManus, J. B., Thirumalai, K., Sakai, S., et al. (2022) · Science Advances · doi:10.1126/sciadv.abq0611 · Cited by 31 · see citing works
Stable and clumped isotope characterization of authigenic carbonates in methane cold seep environments
Thiagarajan, N., Crémière, A., Blättler, C., Lepland, A., Kirsimäe, K., Higgins, J., Brunstad, H., & Eiler, J. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.03.015 · Cited by 31 · see citing works
Reducing contamination parameters for clumped isotope analysis: The effect of lowering Porapak™ Q trap temperature to below –50°C
Davies, A. J., & John, C. M. (2017) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7902 · Cited by 30 · see citing works
Triple oxygen isotope compositions of globally distributed soil carbonates record widespread evaporation of soil waters
Kelson, J., Huth, T., Passey, B., Levin, N., Petersen, S., Ballato, P., Beverly, E., Breecker, D., Hoke, G., Hudson, A., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.034 · Cited by 30 · see citing works
Clumped isotope thermometry in bivalve shells: A tool for reconstructing seasonal upwelling
Caldarescu, D. E., Sadatzki, H., Andersson, C., Schäfer, P., Fortunato, H., & Meckler, A. N. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.11.019 · Cited by 41 · see citing works
Carbonate clumped isotope values compromised by nitrate-derived NO2 interferent
Fiebig, J., Bernecker, M., Meijer, N., Methner, K., Staudigel, P. T., Davies, A., Bayarjargal, L., Spahr, D., Winkler, B., Hofmann, S., et al. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2024.122382 · Cited by 29 · see citing works
Paleothermometry and distribution of calcite beef in the Vaca Muerta Formation, Neuquén Basin, Argentina
Weger, R. J., Murray, S., McNeill, D., Swart, P., Eberli, G., Rodriguez-Blanco, L., Tenaglia, M., & Rueda, L. E. (2019) · American Association of Petroleum Geologists Bulletin · doi:10.1306/10021817384 · Cited by 29 · see citing works
Calibration of δ17O and 17Oexcess values of three international standards: IAEA‐603, NBS19 and NBS18
Barkan, E., Affek, H., Luz, B., Bergel, S., Voarintsoa, N. R., & Musan, I. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8391 · Cited by 29 · see citing works
Basin scale evolution of zebra textures in fault‐controlled, hydrothermal dolomite bodies: Insights from the Western Canadian Sedimentary Basin
McCormick, C. A., Corlett, H., Clog, M., Boyce, A. J., Tartèse, R., Steele‐MacInnis, M., & Hollis, C. (2023) · Basin Research · doi:10.1111/bre.12789 · Cited by 33 · see citing works
USGS44, a new high‐purity calcium carbonate reference material for δ 13C measurements
Qi, H., Moossen, H., Meijer, H., Coplen, T., Aerts-Bijma, A., Reid, L. T., Geilmann, H., Richter, J. M., Rothe, M., Brand, W., et al. (2020) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9006 · Cited by 28 · see citing works
Self-citation
Spatial pattern of super-greenhouse warmth controlled by elevated specific humidity
van Dijk, J., Fernandez, A., Bernasconi, S., Rugenstein, J. C. C., Passey, S. R., & White, T. (2020) · Nature Geoscience · doi:10.1038/s41561-020-00648-2 · Cited by 27 · see citing works
Equilibrated Gas and Carbonate Standard‐Derived Dual (Δ 47 and Δ 48 ) Clumped Isotope Values
Lucarelli, J. K., Carroll, H. M., Ulrich, R. N., Elliott, B. M., Coplen, T. B., Eagle, R. A., & Tripati, A. (2023) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2022gc010458 · Cited by 27 · see citing works
“All data used the IUPAC parameter set (Brand et al., 2010; Daëron et al., 2016).”
Self-citation
The Tertiary structuration of the Western Subalpine foreland deciphered by calcite-filled faults and veins
Bilau, A., Bienveignant, D., Rolland, Y., Schwartz, S., Godeau, N., Guihou, A., Deschamps, P., Mangenot, X., Brigaud, B., Boschetti, L., et al. (2022) · Earth-Science Reviews · doi:10.1016/j.earscirev.2022.104270 · Cited by 31 · see citing works
Simple spreadsheet templates for the determination of the measurement uncertainty of stable isotope ratio delta values.
Dunn, P., Lu, H., Malinovsky, D., & Goenaga-Infante, H. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7376 · Cited by 26 · see citing works
Development and characterization of a new in-house reference material for stable carbon and oxygen isotopes analyses
Crivellari, S., Viana, P. J., Campos, M. D. C., Kuhnert, H., Lopes, A. B. M., da Cruz, F. D., & Chiessi, C. (2021) · Journal of Analytical Atomic Spectrometry · doi:10.1039/d1ja00030f · Cited by 25
Internal Water Facilitates Thermal Resetting of Clumped Isotopes in Biogenic Aragonite
Nooitgedacht, C. W., van der Lubbe, J. J. L., Ziegler, M., & Staudigel, P. T. (2021) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc009730 · Cited by 41 · see citing works
Restricted internal oxygen isotope exchange in calcite veins: Constraints from fluid inclusion and clumped isotope-derived temperatures
Nooitgedacht, C. W., van der Lubbe, J. J. L., de Graaf, S., Ziegler, M., Staudigel, P. T., & Reijmer, J. J. G. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.12.008 · Cited by 27 · see citing works
Linear correlations in bamboo coral δ 13 C and δ 18 O sampled by SIMS and micromill: Evaluating paleoceanographic potential and biomineralization mechanisms using δ 11 B and ∆ 47 composition
Saenger, C., Gabitov, R. I., Farmer, J. R., Watkins, J. M., & Stone, R. P. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.02.014 · Cited by 25 · see citing works
Clumped isotope geochemistry of island carbonates in the South China Sea: Implications for early diagenesis and dolomitization
Guo, Y., Deng, W., Liu, X., Kong, K., Yan, W., & Wei, G. (2021) · Marine Geology · doi:10.1016/j.margeo.2021.106513 · Cited by 30 · see citing works
Seawater paleotemperature and paleosalinity evolution in neritic environments of the Mediterranean margin: Insights from isotope analysis of bivalve shells
Briard, J., Pucéat, E., Vennin, E., Daëron, M., Chavagnac, V., Jaillet, R., Merle, D., & de Rafélis, M. (2020) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2019.109582 · Cited by 24 · see citing works
Clumped and stable isotopes of land snail shells on the Chinese Loess Plateau and their climatic implications
Dong, J., Eiler, J. M., An, Z., Wu, N., Liu, W., Li, X., Kitchen, N., & Lu, F. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.119414 · Cited by 26 · see citing works
A Kinetic Difference Between 12C‐ and 13C‐Bound Oxygen Exchange Rates Results in Decoupled δ18O and Δ47 Values of Equilibrating DIC Solutions
Staudigel, P. T., & Swart, P. K. (2018) · Geochemistry Geophysics Geosystems · doi:10.1029/2018gc007500 · Cited by 25 · see citing works
“The Δ47 values for CO2 gas derived from barium carbonate are calculated using the methods outlined by Huntington et al. (2011), using the Brand et al. (2010) revised absolute composition for Pee Dee belemnite R13 (Chang & Li, 1990), R18 (Baertschi, 1976), R17 (Assonov & Brenninkmeijer, 2003), and…”
Method
Analysis of 13 C and 18 O isotope data of CO 2 in CARIBIC aircraft samples as tracers of upper troposphere/lower stratosphere mixing and the global carbon cycle
Assonov, S., Brenninkmeijer, C., Schuck, T., & Taylor, P. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-8575-2010 · Cited by 23 · see citing works
Self-citation
Clumped isotope and Δ17O measurements of carbonates in CM carbonaceous chondrites: New insights into parent body thermal and fluid evolution
Clog, M., Lindgren, P., Modestou, S., McDonald, A., Tait, A., Donnelly, T., Mark, D. F., & Lee, M. (2024) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2024.01.023 · Cited by 26 · see citing works
Mass 47 clumped isotope signatures in modern lacustrine authigenic carbonates in Western China and other regions and implications for paleotemperature and paleoelevation reconstructions
Li, H., Liu, X., Arnold, A., Elliott, B. M., Flores, R., Kelley, A. M., & Tripati, A. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116840 · Cited by 23 · see citing works
Geothermal Fluid Variation Recorded by Banded Ca-Carbonate Veins in a Fault-Related, Fissure Ridge-Type Travertine Depositional System (Iano, southern Tuscany, Italy)
Matera, P. F., Ventruti, G., Zucchi, M., Brogi, A., Capezzuoli, E., Liotta, D., Yu, T., Shen, C., Huntington, K. W., Rinyu, L., et al. (2021) · Geofluids · doi:10.1155/2021/8817487 · Cited by 25 · see citing works
Clumped isotope signatures of methane-derived authigenic carbonate presenting equilibrium values of their formation temperatures
Zhang, N., Lin, M., Snyder, G., Kakizaki, Y., Yamada, K., Yoshida, N., & Matsumoto, R. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.02.005 · Cited by 22 · see citing works
Clumped isotope constraints on equilibrium carbonate formation and kinetic isotope effects in freezing soils
Burgener, L., Huntington, K. W., Sletten, R. S., Watkins, J. M., Quade, J., & Hallet, B. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.06.006 · Cited by 28 · see citing works
Amplified seasonality in western Europe in a warmer world
de Winter, N. D., Tindall, J., Johnson, A. L. A., Goudsmit-Harzevoort, B., Wichern, N., Kaskes, P., Claeys, P., Huygen, F., van Leeuwen, S. V., Metcalfe, B., et al. (2024) · Science Advances · doi:10.1126/sciadv.adl6717 · Cited by 21 · see citing works

Authors: Brand, W. A., Assonov, S. S., & Coplen, T. B.
Affiliations: Max Planck Society (DE)
European Commission (BE)
United States Geological Survey (US)
ORCID: Brand, Willi A.
Assonov, Sergey S.
Coplen, Tyler B.
Venue: Pure and Applied Chemistry
Publisher: Walter de Gruyter GmbH
Published: 2010-05-26
Volume: 82
Issue: 8
Pages: 1719-1733
ISSN: 0033-4545 (ISSN-L)
1365-3075
DOI: 10.1351/pac-rep-09-01-05
OpenAlex: W2129805855
Cited by: 385
References: 27
Citations by year: 2026: 20 · 2025: 27 · 2024: 38 · 2023: 45 · 2022: 48 · 2021: 52 · 2020: 36 · 2019: 36 · 2018: 36 · 2017: 20 · 2016: 6 · 2015: 4 · 2014: 3 · 2013: 5 · 2012: 6
Type: journal article
Language: en
Open access: bronze
doi.org
Locations: Pure and Applied Chemistry (publishedVersion)
Joint Research Centre (European Commission) (submittedVersion)
Topics: Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric and Environmental Gas Dynamics
Social Sciences › Decision Sciences › Statistics, Probability and Uncertainty › Scientific Measurement and Uncertainty Evaluation
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
Keywords: carbon-13 stable isotopes, carbon dioxide, isotope ratio mass spectrometry, oxygen isotope ratios, uncertainty budget

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Correction for the 17O interference in δ(13C) measurements when analyzing CO2 with stable isotope mass spectrometry (IUPAC Technical Report)

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