Cited by 385Atmospheric and Environmental Gas DynamicsScientific Measurement and Uncertainty EvaluationGroundwater and Isotope Geochemistry

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Correction for the 17O interference in δ(13C) measurements when analyzing CO2 with stable isotope mass spectrometry (IUPAC Technical Report)

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Brand, Willi A., Assonov, Sergey S., Coplen, Tyler B.·2010·Pure and Applied Chemistry

DOI 10.1351/pac-rep-09-01-05

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Abstract

Measurements of δ( 13 C) determined on CO 2 with an isotope-ratio mass spectrometer (IRMS) must be corrected for the amount of 17 O in the CO 2 . For data consistency, this must be done using identical methods by different laboratories. This report aims at unifying data treatment for CO 2 IRMS by proposing (i) a unified set of numerical values, and (ii) a unified correction algorithm, based on a simple, linear approximation formula. Because the oxygen of natural CO 2 is derived mostly from the global water pool, it is recommended that a value of 0.528 be employed for the factor λ, which relates differences in 17 O and 18 O abundances. With the currently accepted N ( 13 C)/ N ( 12 C) of 0.011 180(28) in VPDB (Vienna Peedee belemnite) reevaluation of data yields a value of 0.000 393(1) for the oxygen isotope ratio N ( 17 O)/ N ( 16 O) of the evolved CO 2 . The ratio of these quantities, a ratio of isotope ratios, is essential for the 17 O abundance correction: [ N ( 17 O)/ N ( 16 O)]/[ N ( 13 C)/ N ( 12 C)] = 0.035 16(8). The equation [δ( 13 C) ≍ 45 δ VPDB-CO2 + 2 17 R / 13 R ( 45 δ VPDB-CO2 – λ 46 δ VPDB-CO2 )] closely approximates δ( 13 C) values with less than 0.010 ‰ deviation for normal oxygen-bearing materials and no more than 0.026 ‰ in extreme cases. Other materials containing oxygen of non-mass-dependent isotope composition require a more specific data treatment. A similar linear approximation is also suggested for δ( 18 O). The linear approximations are easy to implement in a data spreadsheet, and also help in generating a simplified uncertainty budget.

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Coupling Δ47 and fluid inclusion thermometry on carbonate cements to precisely reconstruct the temperature, salinity and δ18O of paleo-groundwater in sedimentary basins
Mangenot, X., Bonifacie, M., Gasparrini, M., Götz, A., Chaduteau, C., Ader, M., & Rouchon, V. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.10.011 · Cited by 54
“Note that using the 17 O parameters from Brand et al. (2010) would only lead to small differences in 47 values of both of our standards and samples (ie. less than ±0.010‰), well within the analytical uncertainty on Δ47 measurements.”
Influential
A 600-Million-Year Carbonate Clumped-Isotope Record from the Sultanate of Oman
Bergmann, K. D., Al Balushi, S. A. K., Mackey, T. J., Grotzinger, J. P., & Eiler, J. M. (2018) · Journal of Sedimentary Research · doi:10.2110/jsr.2018.51 · Cited by 46
“%) using the correction parameters from Huntington et al. (2009) compared to those from Brand et al. (2010) (Table 4).”
Method
Absolute 13C/12C isotope amount ratio for Vienna PeeDee Belemnite from infrared absorption spectroscopy
Fleisher, A. J., Yi, H., Srivastava, A., B, O. L. P. A., Zobov, N. F., & Hodges, J. T. (2021) · Nature Physics · doi:10.1038/s41567-021-01226-y · Cited by 76
Laboratory-grown coccoliths exhibit no vital effect in clumped isotope (Δ47) composition on a range of geologically relevant temperatures
Katz, A., Bonifacie, M., Hermoso, M., Cartigny, P., & Calmels, D. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.025 · Cited by 44
“…the choice of appropriate parameters accounting for the 17O interferences in d13C determination (e.g., parameters from Santrock et al., 1985 or Brand et al., 2010), and/or the stability/accuracy of the frames constructed to correct raw ∆47 values from the effects of non-linearity and…”
Background
Clumped-isotope palaeothermometry and LA-ICP-MS U–Pb dating of lava-pile hydrothermal calcite veins
MacDonald, J., Faithfull, J., Roberts, N. M. W., Davies, A., Holdsworth, C., Newton, M., Williamson, S., Boyce, A. J., & John, C. M. (2019) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-019-1599-x · Cited by 61
A high yield cellulose extraction system for small whole wood samples and dual measurement of carbon and oxygen stable isotopes
Andreu-Hayles, L., Lévesque, M., Martin‐Benito, D., Huang, W., Harris, R. A., Oelkers, R., Leland, C., Fernández, J. M., Anchukaitis, K., & Helle, G. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2018.09.007 · Cited by 45
“(6)) in a more complex way that also includes an automatic correction of 17O (Brand et al., 2010).”
BackgroundMethod
High-precision measurements of δ(17)O and (17) Oexcess of NBS19 and NBS18.
Barkan, E., Musan, I., & Luz, B. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7378 · Cited by 45
Abundances of isotopologues and calibration of CO 2 greenhouse gas measurements
Tans, P., Crotwell, A., & Thoning, K. (2017) · Atmospheric measurement techniques · doi:10.5194/amt-10-2669-2017 · Cited by 44
“For more detailed descriptions of this relationship see Santrock et al. (1985), Assonov and Brenninkmeijer (2003), Brand et al. (2010) and references therein.”
Background
Stable carbon isotope ratio analysis of anhydrosugars in biomass burning aerosol particles from source samples.
Sang, X.-F., Gensch, I., Laumer, W., Kammer, B., Chan, C., Engling, G., Wahner, A., Wissel, H., & Kiendler-Scharr, A. (2012) · Environmental Science and Technology · doi:10.1021/es204094v · Cited by 44
A stable isotope toolbox for water and inorganic carbon cycle studies
Hillaire-Marcel, C., Kim, S.-T., Landais, A., Ghosh, P., Assonov, S., Lécuyer, C., Blanchard, M., Meijer, H. A. J., & Steen-Larsen, H. C. (2021) · Nature Reviews Earth & Environment · doi:10.1038/s43017-021-00209-0 · Cited by 43
Self-citation
Jena Reference Air Set (JRAS): a multi-point scale anchor for isotope measurements of CO 2 in air
Wendeberg, M., Richter, J. M., Rothe, M., & Brand, W. A. (2013) · Atmospheric measurement techniques · doi:10.5194/amt-6-817-2013 · Cited by 48
“Factors contributing to the uncertainty are the correction for N2O present in the analyzed gas (Sirignano et al., 2004; Ghosh and Brand, 2004), the δ18O value used for digesting the calcite during standardization (Wendeberg et al., 2011) and the 17O correction (Brand et al., 2010).”
BackgroundMethodSelf-citation
Temperature seasonality in the North American continental interior during the Early Eocene Climatic Optimum
Hyland, E., Huntington, K., Sheldon, N., & Reichgelt, T. (2018) · Climate of the Past · doi:10.5194/cp-14-1391-2018 · Cited by 42
“Following recent work (Daëron et al., 2016; Schauer et al., 2016), mass spectrometer data are corrected using the 17O correction values recommended by Brand et al. (2010).”
Method
Revisiting the equable climate problem during the Late Cretaceous greenhouse using paleosol carbonate clumped isotope temperatures from the Campanian of the Western Interior Basin, USA
Burgener, L., Hyland, E., Huntington, K. W., Kelson, J. R., & Sewall, J. O. (2019) · Palaeogeography, Palaeoclimatology, Palaeoecology · doi:10.1016/j.palaeo.2018.12.004 · Cited by 52
Carbon isotope evidence for the substrates and mechanisms of prebiotic synthesis in the early solar system
Chimiak, L. M., Elsila, J. E., Dallas, B., Dworkin, J. P., Aponte, J. C., Sessions, A. L., & Eiler, J. M. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.09.026 · Cited by 47
Travertine deposits constraining transfer zone neotectonics in geothermal areas: An example from the inner Northern Apennines (Bagno Vignoni-Val d’Orcia area, Italy)
Brogi, A., Liotta, D., Capezzuoli, E., Matera, P. F., Kele, S., Soligo, M., Tuccimei, P., Ruggieri, G., Yu, T.-L., Shen, C.-C., et al. (2020) · Geothermics · doi:10.1016/j.geothermics.2019.101763 · Cited by 38
“(2016), IUPAC parameters were used to correct for 17O interference (Brand et al., 2010).”
Method
Determination of the triple oxygen and carbon isotopic composition of CO 2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer
Adnew, G. A., Hofmann, M. E. G., Paul, D., Laskar, A. H., Surma, J., Albrecht, N., Pack, A., Schwieters, J. B., Koren, G., Peters, W., et al. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8478 · Cited by 47
“In this study we used a λ value of 0.528 to calculate the Δ17O of CO2 following Barkan and co‐workers6,7 and the 17O‐correction algorithm by Brand et al.8 Δ17O ¼ ln δ17Oþ 1 − λ ln δ18Oþ 1 (4) Since the discovery of mass‐independent fractionation,9 the Δ17O value has been used to study sources/sinks of atmospheric trac…”
MethodInfluential
Eastern Mediterranean climate change deduced from the Soreq Cave fluid inclusion stable isotopes and carbonate clumped isotopes record of the last 160 ka
Matthews, A., Affek, H. P., Ayalon, A., Vonhof, H., & Bar‐Matthews, M. (2021) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2021.107223 · Cited by 48
Calibration Strategies for FT-IR and Other Isotope Ratio Infrared Spectrometer Instruments for Accurate δ13C and δ18O Measurements of CO2 in Air.
Flores, E., Viallon, J., Moussay, P., Griffith, D., & Wielgosz, R. (2017) · Analytical Chemistry · doi:10.1021/acs.analchem.6b05063 · Cited by 35
Why Measure 17O? Historical Perspective, Triple-Isotope Systematics and Selected Applications
Miller, M. F., & Pack, A. (2021) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2021.86.01 · Cited by 44
Carbonate clumped isotope analysis (Δ 47 ) of 21 carbonate standards determined via gas‐source isotope‐ratio mass spectrometry on four instrumental configurations using carbonate‐based standardization and multiyear data sets
Upadhyay, D., Lucarelli, J., Arnold, A., Flores, R., Bricker, H., Ulrich, R. N., Jesmok, G., Santi, L., Defliese, W., Eagle, R. A., et al. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9143 · Cited by 33
A calibration equation between Δ 48 values of carbonate and temperature
Swart, P. K., Lu, C., Moore, E. W., Smith, M. E., Murray, S. T., & Staudigel, P. T. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9147 · Cited by 43
Reconsidering the uplift history and peneplanation of the northern Lhasa terrane, Tibet
Ingalls, M., Rowley, D. B., Currie, B. S., & Colman, A. S. (2020) · American Journal of Science · doi:10.2475/06.2020.01 · Cited by 38
Reconstructing carbonate alteration histories in orogenic sedimentary basins: Xigaze forearc, southern Tibet
Ingalls, M. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.02.005 · Cited by 30
Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates
Hudson, A. M., Quade, J., Ali, G., Boyle, D., Bassett, S., Huntington, K. W., De los Santos, M. G., Cohen, A. S., Lin, K., & Wang, X. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.06.024 · Cited by 32
“Insufficient data are available to recalculate previously published calibration samples using the Brand et al. (2010) correction at this time.”
MethodResultInfluential
Prehistoric cooking versus accurate palaeotemperature records in shell midden constituents
Müller, P., Staudigel, P., Murray, S., Vernet, R., Barusseau, J., Westphal, H., & Swart, P. (2017) · Scientific Reports · doi:10.1038/s41598-017-03715-8 · Cited by 32
Rapid and precise measurement of carbonate clumped isotopes using laser spectroscopy
Yanay, N., Wang, Z., Dettman, D. L., Quade, J., Huntington, K. W., Schauer, A. J., Nelson, D. D., McManus, J. B., Thirumalai, K., Sakai, S., et al. (2022) · Science Advances · doi:10.1126/sciadv.abq0611 · Cited by 31
Stable and clumped isotope characterization of authigenic carbonates in methane cold seep environments
Thiagarajan, N., Crémière, A., Blättler, C. L., Lepland, A., Kirsimäe, K., Higgins, J. A., Brunstad, H., & Eiler, J. M. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.03.015 · Cited by 41
Reducing contamination parameters for clumped isotope analysis: The effect of lowering Porapak™ Q trap temperature to below –50°C
Davies, A. J., & John, C. M. (2017) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7902 · Cited by 30
Triple oxygen isotope compositions of globally distributed soil carbonates record widespread evaporation of soil waters
Kelson, J. R., Huth, T. E., Passey, B. H., Levin, N. E., Petersen, S., Ballato, P., Beverly, E. J., Breecker, D. O., Hoke, G. D., Hudson, A. M., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.034 · Cited by 43
Clumped isotope thermometry in bivalve shells: A tool for reconstructing seasonal upwelling
Caldarescu, D. E., Sadatzki, H., Andersson, C., Schäfer, P., Fortunato, H., & Meckler, A. N. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.11.019 · Cited by 41
Carbonate clumped isotope values compromised by nitrate-derived NO2 interferent
Fiebig, J., Bernecker, M., Meijer, N., Methner, K., Staudigel, P. T., Davies, A., Bayarjargal, L., Spahr, D., Winkler, B., Hofmann, S., et al. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2024.122382 · Cited by 29
Paleothermometry and distribution of calcite beef in the Vaca Muerta Formation, Neuquén Basin, Argentina
Weger, R. J., Murray, S. T., McNeill, D. F., Swart, P. K., Eberli, G. P., Blanco, L. R., Tenaglia, M., & Sánchez, L. E. R. (2019) · AAPG Bulletin · doi:10.1306/10021817384 · Cited by 39
Calibration of δ17O and 17Oexcess values of three international standards: IAEA‐603, NBS19 and NBS18
Barkan, E., Affek, H., Luz, B., Bergel, S., Voarintsoa, N. R., & Musan, I. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8391 · Cited by 29
Basin scale evolution of zebra textures in fault‐controlled, hydrothermal dolomite bodies: Insights from the Western Canadian Sedimentary Basin
McCormick, C. A., Corlett, H., Clog, M., Boyce, A. J., Tartèse, R., Steele‐MacInnis, M., & Hollis, C. (2023) · Basin Research · doi:10.1111/bre.12789 · Cited by 33
USGS44, a new high‐purity calcium carbonate reference material for δ 13 C measurements
Qi, H., Moossen, H., Meijer, H. A. J., Coplen, T. B., Bijma, A. T., Reid, L. T., Geilmann, H., Richter, J. M., Rothe, M., Brand, W. A., et al. (2020) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9006 · Cited by 34
Self-citation
Spatial pattern of super-greenhouse warmth controlled by elevated specific humidity
van Dijk, J., Fernandez, A., Bernasconi, S., Rugenstein, J. C. C., Passey, S. R., & White, T. (2020) · Nature Geoscience · doi:10.1038/s41561-020-00648-2 · Cited by 27
Equilibrated Gas and Carbonate Standard‐Derived Dual (Δ 47 and Δ 48 ) Clumped Isotope Values
Lucarelli, J. K., Carroll, H. M., Ulrich, R. N., Elliott, B. M., Coplen, T. B., Eagle, R. A., & Tripati, A. (2023) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2022gc010458 · Cited by 27
“All data used the IUPAC parameter set (Brand et al., 2010; Daëron et al., 2016).”
Self-citation
The Tertiary structuration of the Western Subalpine foreland deciphered by calcite-filled faults and veins
Bilau, A., Bienveignant, D., Rolland, Y., Schwartz, S., Godeau, N., Guihou, A., Deschamps, P., Mangenot, X., Brigaud, B., Boschetti, L., et al. (2022) · Earth-Science Reviews · doi:10.1016/j.earscirev.2022.104270 · Cited by 33
Simple spreadsheet templates for the determination of the measurement uncertainty of stable isotope ratio delta values.
Dunn, P., Lu, H., Malinovsky, D., & Goenaga-Infante, H. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7376 · Cited by 26
Development and characterization of a new in-house reference material for stable carbon and oxygen isotopes analyses
Crivellari, S., Viana, P. J., Campos, M. D. C., Kuhnert, H., Lopes, A. B. M., Cruz, F. W., & Chiessi, C. M. (2021) · Journal of Analytical Atomic Spectrometry · doi:10.1039/d1ja00030f · Cited by 29
Internal Water Facilitates Thermal Resetting of Clumped Isotopes in Biogenic Aragonite
Nooitgedacht, C. W., van der Lubbe, J. J. L., Ziegler, M., & Staudigel, P. T. (2021) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc009730 · Cited by 41
Restricted internal oxygen isotope exchange in calcite veins: Constraints from fluid inclusion and clumped isotope-derived temperatures
Nooitgedacht, C. W., van der Lubbe, J. J. L., de Graaf, S., Ziegler, M., Staudigel, P. T., & Reijmer, J. J. G. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.12.008 · Cited by 28
Linear correlations in bamboo coral δ 13 C and δ 18 O sampled by SIMS and micromill: Evaluating paleoceanographic potential and biomineralization mechanisms using δ 11 B and ∆ 47 composition
Saenger, C., Gabitov, R. I., Farmer, J. R., Watkins, J. M., & Stone, R. P. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.02.014 · Cited by 25
Clumped isotope geochemistry of island carbonates in the South China Sea: Implications for early diagenesis and dolomitization
Guo, Y., Deng, W., Liu, X., Kong, K., Yan, W., & Wei, G. (2021) · Marine Geology · doi:10.1016/j.margeo.2021.106513 · Cited by 30
Seawater paleotemperature and paleosalinity evolution in neritic environments of the Mediterranean margin: Insights from isotope analysis of bivalve shells
Briard, J., Pucéat, E., Vennin, E., Daëron, M., Chavagnac, V., Jaillet, R., Merle, D., & de Rafélis, M. (2020) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2019.109582 · Cited by 24
Clumped and stable isotopes of land snail shells on the Chinese Loess Plateau and their climatic implications
Dong, J., Eiler, J. M., An, Z., Wu, N., Liu, W., Li, X., Kitchen, N., & Lu, F. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.119414 · Cited by 26
A Kinetic Difference Between 12C‐ and 13C‐Bound Oxygen Exchange Rates Results in Decoupled δ18O and Δ47 Values of Equilibrating DIC Solutions
Staudigel, P. T., & Swart, P. K. (2018) · Geochemistry Geophysics Geosystems · doi:10.1029/2018gc007500 · Cited by 25
“The Δ47 values for CO2 gas derived from barium carbonate are calculated using the methods outlined by Huntington et al. (2011), using the Brand et al. (2010) revised absolute composition for Pee Dee belemnite R13 (Chang & Li, 1990), R18 (Baertschi, 1976), R17 (Assonov & Brenninkmeijer, 2003), and…”
Method
Analysis of 13 C and 18 O isotope data of CO 2 in CARIBIC aircraft samples as tracers of upper troposphere/lower stratosphere mixing and the global carbon cycle
Assonov, S., Brenninkmeijer, C., Schuck, T., & Taylor, P. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-8575-2010 · Cited by 23
Self-citation
Clumped isotope and Δ17O measurements of carbonates in CM carbonaceous chondrites: New insights into parent body thermal and fluid evolution
Clog, M., Lindgren, P., Modestou, S., McDonald, A., Tait, A., Donnelly, T., Mark, D. F., & Lee, M. (2024) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2024.01.023 · Cited by 26
Mass 47 clumped isotope signatures in modern lacustrine authigenic carbonates in Western China and other regions and implications for paleotemperature and paleoelevation reconstructions
Li, H., Liu, X., Arnold, A., Elliott, B. M., Flores, R., Kelley, A. M., & Tripati, A. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116840 · Cited by 24
Geothermal Fluid Variation Recorded by Banded Ca-Carbonate Veins in a Fault-Related, Fissure Ridge-Type Travertine Depositional System (Iano, southern Tuscany, Italy)
Matera, P. F., Ventruti, G., Zucchi, M., Brogi, A., Capezzuoli, E., Liotta, D., Yu, T., Shen, C., Huntington, K. W., Rinyu, L., et al. (2021) · Geofluids · doi:10.1155/2021/8817487 · Cited by 25
Clumped isotope signatures of methane-derived authigenic carbonate presenting equilibrium values of their formation temperatures
Zhang, N., Lin, M., Snyder, G. T., Kakizaki, Y., Yamada, K., Yoshida, N., & Matsumoto, R. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.02.005 · Cited by 29
Clumped isotope constraints on equilibrium carbonate formation and kinetic isotope effects in freezing soils
Burgener, L., Huntington, K. W., Sletten, R. S., Watkins, J. M., Quade, J., & Hallet, B. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.06.006 · Cited by 28
Amplified seasonality in western Europe in a warmer world
de Winter, N. J., Tindall, J. C., Johnson, A. L. A., Goudsmit, B., Wichern, N., Kaskes, P., Claeys, P., Huygen, F., van Leeuwen, S. M., Metcalfe, B., et al. (2024) · Science Advances · doi:10.1126/sciadv.adl6717 · Cited by 23

Authors: Brand, W. A., Assonov, S. S., & Coplen, T. B.
Affiliations: Max Planck Society (DE)
European Commission (BE)
United States Geological Survey (US)
ORCID: Brand, Willi A.
Assonov, Sergey S.
Coplen, Tyler B.
Venue: Pure and Applied Chemistry
Publisher: Walter de Gruyter GmbH
Published: 2010-05-26
Volume: 82
Issue: 8
Pages: 1719-1733
ISSN: 0033-4545 (ISSN-L)
1365-3075
DOI: 10.1351/pac-rep-09-01-05
OpenAlex: W2129805855
Cited by: 385
References: 27
Citations by year: 2026: 20 · 2025: 27 · 2024: 38 · 2023: 45 · 2022: 48 · 2021: 52 · 2020: 36 · 2019: 36 · 2018: 36 · 2017: 20 · 2016: 6 · 2015: 4 · 2014: 3 · 2013: 5 · 2012: 6
Type: journal article
Language: en
Open access: bronze
doi.org
Locations: Pure and Applied Chemistry (publishedVersion)
Joint Research Centre (European Commission) (submittedVersion)
Topics: Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric and Environmental Gas Dynamics
Physical Sciences › Physics and Astronomy › Instrumentation › Scientific Measurement and Uncertainty Evaluation
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
Keywords: carbon-13 stable isotopes, carbon dioxide, isotope ratio mass spectrometry, oxygen isotope ratios, uncertainty budget

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Correction for the 17O interference in δ(13C) measurements when analyzing CO2 with stable isotope mass spectrometry (IUPAC Technical Report)

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